大型MOX燃料快堆钠空泡反应性微扰理论研究

钠空泡反应性效应是钠冷快堆核设计和安全分析的重要内容。本文基于多群节块扩散法,采用微扰理论推导出钠空泡反应性的计算方法,对1 000 MWe钠冷快堆MOX燃料堆芯的总钠空泡反应性、空间分布、物理分项进行了计算。结果表明,钠空泡反应性主要来源于中子泄漏的增加和能谱的硬化,两者一正一负,且空间分布规律相反,导致钠空泡反应性具有强烈的空间依赖性;对于所计算的MOX燃料堆芯钠空泡反应性高达3 $左右。计算和分析结果阐明了钠空泡反应性的产生机理和分布规律,可为低钠空泡的设计提供参考。     

高温气冷堆舱室抗商用飞机撞击的耦合数值分析

本文建立了大型商用飞机撞击典型高温气冷堆核电站反应堆舱室的非线性有限元模型,计算中混凝土舱室直接采用工程用钢筋混凝土的损伤塑性本构模型,飞机结构采用Johnson-Cook本构模型。对飞机高速撞击高温气冷堆核电站反应堆舱室非线性撞击过程进行模拟计算,得出正面和侧面撞击条件下的撞击载荷曲线、撞击位移云图、反应堆舱室混凝土破坏情况等结果。评估表明,反应堆舱室结构在撞击条件下的整体损伤微小,可为保护内部关键设备提供重要的屏障功能。     

基于决策树的堆芯物理参数预测研究

反应堆堆芯核设计涉及大量方案的搜索与详细计算,缩短方案搜索时间有利于提高核设计效率。数据挖掘技术通过对大量数据进行学习与模式识别,可实现核设计方案物理参数的快速预测,更快地筛选出可行的备选堆芯方案。本文基于数据挖掘的决策树4种算法：C4.5、RepTree、Random Forest及Random Tree,在计算时以燃料富集度、含可燃毒物燃料棒数量及含量作为自变量,以寿期内k_eff不均匀系数偏差（KUCD）、径向功率不均匀系数偏差（RPNCD）、径向中子通量不均匀系数偏差（RFNCD）、堆芯寿期（CL）作为目标函数,构成目标函数符合度（CPF）,利用大量已知核设计参数的组件及堆芯设计方案作为数据挖掘训练集,构建数据挖掘模型,并用于对未知核设计参数的组件方案集合（测试集）进行CPF快速预测。结果表明,4种算法利用训练集构建数据挖掘模型的时间在0.6 s以内,各算法的交叉验证精度均在0.7以上,其中C4.5算法对CPF预测精度最高;对测试集方案的核设计参数预测中,单个方案的预测时间均在0.9 s以内,而Random Forest算法对CPF等于4的预测效果最好。     

应用于钠冷快堆的超临界二氧化碳动力转换系统研究

超临界二氧化碳（SCO₂）布雷顿循环由于高效、紧凑和可避免钠水反应等特性而成为钠冷快堆的理想动力转换系统。本文以1 200 MWe大型池式钠冷快堆为系统热源,钠回路温度及热负荷为循环系统运行边界,对比研究了不同SCO₂布雷顿循环系统性能和关键设备性能的变化规律。研究发现,级间冷却再压缩循环与钠冷快堆热源特性匹配性最佳,且循环效率最高（40.7%）。进而研究了不同运行参数对级间冷却再压缩循环效率的影响规律,给出了循环系统效率对各关键影响因素的敏感度,发现循环系统效率对冷端参数的敏感度最强,其次为分流比和透平入口参数,对主压缩机级间压比的敏感度最弱。     

Interaction of two in-line bubbles of equal size rising in viscous liquid

The interaction of bubbles is the key to understand gas–liquid bubbling flow. Two-dimensional axis-symmetry computational fluid dynamics simulations on the interactive bubbles were performed with VOF method,which was validated by experimental work. It is testified that several different bubble interactive behaviors could be acquired under different conditions. Firstly, for large bubbles(d: 4, 6, 8, 10 mm), the trailing bubble rising velocity and aspect ratio have negative correlations with liquid viscosity and surface tension. The influences of viscosity and surface tension on leading bubble are negligible. Secondly, for smaller bubbles(d: 1, 2 mm), the results are complicated. The two bubbles tend to move together due to the attractive force by the wake and the potential repulsive force. Especially for high viscous or high surface tension liquid, the bubble pairs undergo several times acceleration and deceleration. In addition, bubble deformation plays an important role during bubble interaction which cannot be neglected.     

Upgrading Siberian (Russia) crude oil by hydrodesulfurization in a slurry reactor: A kinetic study

Hydrodesulfurization (HDS) of sour crude oil is an effective way to address the corrosion problems in refineries, and is an economic way to process sour crude oil in an existing refinery built for sweet oil. In the current study, the HDS of Siberian crude oil was carried out in a slurry reactor. The Co–Mo, Ni–Mo, and Ni–W catalysts supported on γ-Al₂O₃ were compared at the temperature of 340 °C and the pressure of 4.5 MPa. The HDS activity follows the order of Co–Mo > Ni–Mo > Ni–W at a high concentration of H₂S, and the difference between Co–Mo and Ni–Mo becomes insignificant at a low concentration of H₂S. The influence of reaction temperature 320–360 °C and reaction pressure 3–5.5 MPa was investigated, and both play a positive role in the HDS reaction. A kinetic model over Ni–Mo/Al₂O₃ in the slurry reactor was established. The activation energy is estimated as 60.34 kJ·mol⁻¹; the orders of sulfur components and hydrogen partial pressure are 1.43 and 1.30, respectively. The kinetic parameters are compared with those in a trickle-bed reactor, implying that the mass transfer is greatly enhanced in the slurry reactor. The back mixing effect is present in the slurry reactor and can be reduced by a multi-stage design, which would lead to higher reactor efficiency in industrial application.     

Liquid-solid mass transfer in a rotating packed bed reactor with structured foam packing

A rotating packed bed (RPB) reactor has substantially potential for the process intensification of heterogeneous catalytic reactions. However, the scarce knowledge of the liquid–solid mass transfer in the RPB reactor is a barrier for its design and scale-up. In this work, the liquid–solid mass transfer in a RPB reactor installed with structured foam packing was experimentally studied using copper dissolution by potassium dichromate. Effects of rotational speed, liquid and gas volumetric flow rate on the liquid–solid mass transfer coefficient (k_LS) have been investigated. The correlation for predicting k_LS was proposed, and the deviation between the experimental and predicted values was within ± 12%. The liquid–solid volumetric mass transfer coefficient (k_LSa_LS) ranged from 0.04–0.14 1⁻¹, which was approximately 5 times larger than that in the packed bed reactor. This work lays the foundation for modeling of the RPB reactor packed with structured foam packing for heterogeneous catalytic reaction.     

Bubble size fractal dimension,gas holdup,and mass transfer in a bubble column with dual internals

As the scale of residual oil treatment increases and cleaner production improves in China, slurry bubble column reactors face many challenges and opportunities for residual oil hydrogenation technology. The internals development is critical to adapt the long-term stable operation. In this paper, the volumetric mass transfer coefficient, gas holdup and bubble size in a gas–liquid up-flow column are studied with two kinds of internals. The gas holdup and volumetric mass transfer coefficient increase by 120% and 42% when the fractal dimension of bubbles increases from 0.56 to 2.56, respectively. The enhanced mass transfer processing may improve the coke suppression ability in the slurry reactor for residual oil treatment. The results can be useful for the exploration of reacting conditions, scale-up strategies, and oil adaptability. This work is valuable for the design of reactor systems and technological processes.     

A study of A2/O process in El-Berka WWTP by replacing the anaerobic selector with UASB and adopting a hybrid system in the oxic zone

ABSTRACT

A multistage system comprising an upflow anaerobic sludge blanket (UASB) followed by anoxic unit and then oxic activated sludge (AS) with biofilm is studied in El-Berka WWTP, Egypt. Different organic loading wastewaters of chemical oxygen demand (COD) less than 500 mg/L till 3000 mg/L are tested during the study. The hydraulic retention time (HRT) varies for each loading from 7.5 to 10 to 15 h. The UASB reactor accomplishes the removal efficiency of 50%–70% of influent COD. The overall system performs the removal efficiency of 95% of influent COD and NH₄-N. Also, the results are verified by a modified mathematical model.     

新型格栅支撑有序堆积床内流动传热数值研究

颗粒堆积床作为反应器和分离器等的重要组成广泛应用于实际化学工业生产中。基于传统的有序堆积结构,提出了一种新型格栅支撑有序堆积结构,通过采用新型格栅支撑结构可以快速构建有序颗粒堆积床,其中包括格栅支撑简单立方、格栅支撑体心立方、格栅支撑疏松面心立方和格栅支撑密实面心立方颗粒堆积结构。对4种颗粒堆积单元通道内的流动换热进行模拟研究后发现,不同堆积形式的格栅支撑颗粒堆积床流动换热性能不同;在相同的面心立方堆积形式下,使用不同的格栅支撑结构,其流动传热也有明显差异;与传统有序堆积结构相比,在换热相差不多的情况下,格栅支撑有序堆积结构的压降减小,所以其综合换热效率有明显提升。