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Calculation methods for comparing the performance of pure and mixed working fluids in heat pump applications 总被引:2,自引:0,他引:2
Three methods for comparing cycle performance of working fluids, pure as well as non-azeotropic mixtures, are investigated for two applications and for two mixture pairs, HCFC22-CFC114 and HCFC22-HCFC142b, and their pure components. The methods differ in the way of calculating the heat exchange processes. They assume, respectively, equal minimum approach temperatures, equal mean temperature differences and equal heat transfer areas. Changes of coefficient of performance (COP) with composition are explained for all methods. It is shown that transport properties must be taken into account when making rigorous comparisons between working fluids. To predict the relations between fluids with high accuracy, one must use the method with equal heat transfer areas. By the method with equal mean temperature differences, the COP can be estimated with the same accuracy for mixtures as for pure fluids, and can be used for rough estimations of the COP level with different fluids. The method of equal minimum approach temperatures should be avoided for non-azeotropic mixtures. 相似文献
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A. T. Sousa P. S. Fialho C. A. Nieto de Castro R. Tufeu B. Le Neindre 《International Journal of Thermophysics》1996,17(3):551-560
The density of HCFC 141b has been measured at several temperatures between 260 and 320 K, Mid pressures up to 20 MPa, with a mechanical oscillator densimeter. The densimeter was calibrated with 2,2,4-trimethylpentane, whose density was obtained from a correlating cyuation with 0.3% uncertainty. The density data obtained for HCFC 14H) hits a reproducibility of 0.05% and an uncertainty of 0.3%. The data obtained were fitted to a Tait-type equation. which reproduced the experimental densities within 0.11 % and were compared with the data obtained in other works.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A. 相似文献
55.
The influence of different alkali halides (LiF, LiCl. LiBr, NaF, NaCl, NaBr, KF, KCl and KBr) on α-chymotrypsin-catalysed plastein synthesis has been studied in aqueous medium at different substrate concentrations. The results showed an enhancing effect on the plastein synthesis enzyme action by the presence of salts, proportional to salt concentration, which was decreased when the substrate concentration was increased. Additionally, these facts allowed the ions to be classified as a function of their activation power (F? > Cl? > Br?: K+ > Na+ > Li+), which was in agreement with the interpretation of the Hofmeister lyotropic series. The influence of the several phenomena produced by the presence of salts in the plastein reaction, such as, salt-substrate interactions and water activity, as well as the presence of deactivated enzyme was also analysed. The obtained results showed that the substrate concentration is the most important factor, and the activating effect of salts could be simultaneously involved with both a structural change on the substrate conformation and a reduction of water activity into the reaction media, enhancing the catalytic capability of the α-chymotrypsin towards a peptide synthesis action. 相似文献
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M. Zahedifar P. Rezaeian S. Harooni 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2007,264(2):378-382
A new general order Thermoluminescence (TL) model for exponential distribution of activation energies has been presented. In the proposed model an effective kinetic-order has been introduced as an additional adjustable parameter. This makes it possible to take the re-trapping into account and would give a better estimate of the activation energy compared with the first order kinetics model. The proposed model has been applied to the basaltic rocks from central zone of Iran. The obtained results show that the proposed model gives a better fit to the experimental peaks compared to the first order model. 相似文献
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Wan Fokkink Rob van Glabbeek Paulien de Wind 《Electronic Notes in Theoretical Computer Science》2006,156(1):97
We present congruence formats for η- and rooted η-bisimulation equivalence. These formats are derived using a method for decomposing modal formulas in process algebra. To decide whether a process algebra term satisfies a modal formula, one can check whether its subterms satisfy formulas that are obtained by decomposing the original formula. The decomposition uses the structural operational semantics that underlies the process algebra. 相似文献
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Kenneth W. Young Kevin J. Whittle 《Journal of the science of food and agriculture》1985,36(5):383-392
Hunter L, a and b values are used to order fish mince colour according to species or processing parameters. Mince colour difference (ΔE) or statistical examination of L, a and b values are used to establish a 3-dimensional plot to illustrate colour differences between samples. 相似文献