用金属卟啉络合物引发合成高分子量聚醚

介绍了用四苯基卟啉铝络合物催化体系合成高分子量聚醚的方法。该聚合过程显示出一种持续特性。产物具有均一的链长和极窄的分子量分布，且数均分子量Ｍｎ可通过改变单体与引发剂的摩尔比来控制。     

Transitions from solid to liquid in isotactic polystyrene studied by thermal analysis and X-ray scattering

A three-phase model, comprising mobile amorphous fraction (MAF), rigid amorphous fraction (RAF) and crystalline fraction (C), has been applied to interpret the thermal transitions and structure of cold-crystallized isotactic polystyrene (iPS) from below the glass transition temperature, T_g, to above the melting point. Quenched amorphous iPS films were isothermally crystallized at different temperatures for 12 h. The fraction of crystalline phase, ?_c, was measured by differential scanning calorimetry (DSC), wide angle X-ray scattering and Fourier Transform infrared spectroscopy. The fraction of the mobile amorphous phase, ?_MAF, was obtained from the heat capacity increment at the glass transition temperature. In the three-phase model, the fraction of the rigid amorphous phase, ?_RAF, was found from 1−?_MAF−?_c. Specific heat capacity measurements by standard DSC confirm that the experimental baseline heat capacity conforms to a three-phase model for temperatures ranging from below T_g, up to the relaxation of RAF. The relaxation of RAF appears as a sigmoidal change in heat capacity accompanied by excess enthalpy, in which solid-like RAF is converted to an identical amount of liquid-like MAF.At temperatures above the relaxation of RAF, either one or two major crystal melting endotherms are observed in standard DSC, dependent upon crystallization temperature. However, using quasi-isothermal temperature modulated DSC, we always observed two reversing melting endotherms. The effects of annealing on iPS structure during the quasi-isothermal measurement were assessed using small angle X-ray scattering (SAXS). Combining the DSC and SAXS results, a model for the melting of iPS lamellae at low heating rates is presented.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

Dynamic buffering performance of the honeycomb paperboard filled with polyurethane

A new kind of composite buffering material was made by filling the voids of honeycomb paperboard with polyurethane. Drop tests were performed to evaluate the dynamic energy absorption capacity of the material. Based on the tests results, we analyzed the mechanical behaviors of the material under different conditions and obtained the inherent influencing laws of some factors on the material＇s dynamic buffering performance. It was shown that the dynamic buffering performance varied directly with impact velocity, and inversely with the void diameter, thickness and buffeting area of the composite material.     

第二代农民工市民化与中国共产党执政能力建设

第二代农民工市民化利益要求的实现有助于从阶级基础、群众基础、执政理念、执政资源和执政环境等方面加强党的执政能力建设。在第二代农民工市民化背景下,党应该强化执政为民的理念,构建利益相关制度,强化第二代农民工的工人阶级意识和主人翁意识,鼓励他们积极参与政治生活,有组织、有秩序地进行利益表达,使他们充分享受到城市经济社会发展成果,同时提高党自身的执政能力。     

析架空输电线路上倍容导线的选择

架空输电线路项目扩容改造,当采用倍容导线时,需在技术和经济上对倍容导线进行比较分析。文章对这种导线的种类、特性情况作了介绍,通过在220kV线路上对倍容导线的选择分析,为同类案例的处理提供了借鉴和参考。     

高精度冷轧不锈钢管生产

介绍了用ＬＤ型冷轧管机生产高精度冷轧不锈钢管的经验和质量保证措施。     

High temperature corrosion mechanisms and effect of alloying elements for materials used in waste incineration environment

Corrosion products on two typical materials, SA213-T12 steel and alloy 625 exposed to the actual combustion gas, were analyzed in addition to laboratory tests for penetration of corrosive matter. It has been clarified that corrosion products of oxides containing a little chlorides and sulphides show lamellar structures and that at the alloy-scale interface, chlorination, sulphidation, and oxidation occur under a low P_O2-high P_Cl2 condition. The formation of scale structures and the effect of corrosion-resistant alloying elements can be explained according to the stability tendencies of metals, chlorides, and oxides in the M-Cl-O equilibrium diagrams. The severity of corrosion environments at the interface is influenced by the penetration extent of corrosive matters through deposits and scales, and the protective effects of oxide films derived from alloying elements play an important role in preventing the corrosion. On the other hand, it has been shown that thermal fluctuation characterized in this kind of environment makes the lamellar scale structures and sometimes breaks and peels off the scale, and thus accelerates the corrosion. On the basis of the above mentioned knowledge, a new corrosion model is presented.     

高钒高速钢碳化钒形态的数值化分析

针对碳化钒的不同形态,设计出定量分析软件,并利用形状因子K,实现了高钒高速钢不同碳化物形态数值化处理,当K介于0.785～1.000之间碳化钒形态为团球状;K≤0.223,碳化钒呈开花状.高钒高速钢当碳含量达到4.2%时,K为0.86和当量直径D为0.78μm,碳化物呈团球状均匀分布.     

Effects of electrical discharge surface modification of superalloy Haynes 230 with aluminum and molybdenum on oxidation behavior

The effects of the electrical discharge alloying (EDA) process on improving the high temperature oxidation resistance of the Ni-based superalloy Haynes 230 have been investigated. The 85 at.% Al and 15 at.% Mo composite electrode provided the surface alloying materials. An Al-rich layer is produced on the surface of the EDA specimen alloyed with positive electrode polarity, whereas, many discontinuous piled layers are attached to the surface of the EDA superalloy when negative electrode polarity is selected. The oxidation resistance of the specimen alloyed with positive electrode polarity is better than that of the unalloyed superalloy, and the effective temperature of oxidation resistance of the alloyed layer can be achieved to 1100 °C. Conversely, the oxidation resistance of the other EDA specimen alloyed with negative electrode polarity is even worse than that of the unalloyed superalloy.