采用循环伏安法研究微孔型多孔炭电极的电容特性

以酚醛树脂为原料,KOH为活化剂,制备出3种不同孔径分布的微孔型多孔炭(孔径≤2 nm)。在低温氮气吸附法测定BET比表面积和孔结构的基础上,采用循环伏安法考察了这3种微孔型多孔炭作电极的双电层电容器(EDLC)的电容特性。实验结果表明,微孔型多孔炭作电极的EDLC的电容特性是:在低扫描速率下,其循环伏安曲线达到电容平台后在高电压(±1.0 V)附近出现峰电容;延长在电解液中的浸渍时间,电极的比电容增大,高电位附近的峰电容减小。3种不同孔径分布的微孔型多孔炭作电极的EDLC的循环伏安特性受浸渍时间影响的程度也不同。     

高技术产品用无源元件与中国钽工业发展

世界高技术产品市场总体看呈增长趋势，预计2020年销售额将比2000年翻一番。以高技术产品为主要应用领域的电阻、电容、电感等无源元件，也将随着高技术产业的发展呈现出良好的市场前景，但是钽电容器市场近几年表现出骤涨急落的发展态势。由于钽电容器产能过剩，且面临着被替代的威协，因此价格将无法返回到2000年以前的水平，并呈现整体持续走低的趋势。中国的钽工业发展应注重提高企业自身的综合竞争力，加强企业间的沟通、交流与合作，维护我国钽工业的整体利益，增强环保意识，做好国外转移到我国的初级产品和低端产品生产的环保工作。     

电解电容器铝箔纯交流腐蚀工艺影响因素的研究

对电解电容器铝箔交流腐蚀体系中各影响因素的研究结果表明，在电流密度为０．５Ａ／ｃｍ２，温度为４７±２℃；控制腐蚀液中Ａｌ（３＋）含量及适量添加表面保护剂和辅助添加剂的条件下，可获得最大比电容。通过循环伏安曲线测试，探讨了各因素影响腐蚀的机理及相互关系。     

电感电容损耗电阻的讨论

通过对电容电感阻抗的测量，发现实验值偏离理论值。定性地分析了误差的来源，得出的结论是电感电容内部的损耗电阻随着频率的变化而变化，变化方向相反而并非相同。     

Evaluation of a palladinized Nafion™ for direct methanol fuel cell application

Palladinized Nafion™ was prepared via ion-exchange and chemical reduction method. Palladium precursors and solvent systems determined the efficiency of the incorporation and distribution of nanoparticles. The tortuous thin Pd film was formed on the surface of membrane when Na⁺-Nafion™ and water were used. Pd nanoparticles enhanced the water uptake of Nafion™ and reduced its methanol uptake. And dispersed Pd nanoparticles in Nafion™ disturbed the proton conduction and methanol permeation simultaneously in Nafion™ cluster. In order to reduce methanol permeation of Nafion™ and keep its high conductivity, it was more efficient for Pd nanoparticles to distribute near the surface of membrane. Palladinized Nafion™ improved the performance of DMFC single cell operation by reducing the methanol permeation.     

Electrical double layer characteristics of nanoporous carbon derived from titanium carbide

Electrochemical parameters of the nanoporous carbide-derived carbon|organic electrolyte have been studied by cyclic voltammetry and electrochemical impedance spectroscopy. The gas adsorption measurements have been used for evaluating the specific surface area, pore size distribution and porosity as the essential parameters influencing the double layer performance of carbon. The region of ideal polarizability, values of series and parallel resistance, capacitance and other important electrical double layer parameters were established. It was shown that specific capacitance of typical nanoporous carbon derived from titanium carbide is in the range of 70-90 F cm⁻³ or 100-130 F g⁻¹ and it depends on the synthesis conditions. The influence of the electrolyte solvent to the capacitance was insignificant, although acetonitrile was advantageous with respect of smaller viscosity.     

A hybrid intelligent system for medical data classification

In this paper, a hybrid intelligent system that consists of the Fuzzy Min–Max neural network, the Classification and Regression Tree, and the Random Forest model is proposed, and its efficacy as a decision support tool for medical data classification is examined. The hybrid intelligent system aims to exploit the advantages of the constituent models and, at the same time, alleviate their limitations. It is able to learn incrementally from data samples (owing to Fuzzy Min–Max neural network), explain its predicted outputs (owing to the Classification and Regression Tree), and achieve high classification performances (owing to Random Forest). To evaluate the effectiveness of the hybrid intelligent system, three benchmark medical data sets, viz., Breast Cancer Wisconsin, Pima Indians Diabetes, and Liver Disorders from the UCI Repository of Machine Learning, are used for evaluation. A number of useful performance metrics in medical applications which include accuracy, sensitivity, specificity, as well as the area under the Receiver Operating Characteristic curve are computed. The results are analyzed and compared with those from other methods published in the literature. The experimental outcomes positively demonstrate that the hybrid intelligent system is effective in undertaking medical data classification tasks. More importantly, the hybrid intelligent system not only is able to produce good results but also to elucidate its knowledge base with a decision tree. As a result, domain users (i.e., medical practitioners) are able to comprehend the prediction given by the hybrid intelligent system; hence accepting its role as a useful medical decision support tool.     

混杂系统的一致输入输出对状态稳定性

混杂系统的输入输出对状态稳定性是混杂控制系统领域极富挑战性的课题之一. 为了观测混杂系统的状态,本文提出了一类混杂系统的一致输入输出对状态稳定的充分条件,分析了混杂系统的一致输入输出对状态稳定性、光滑Lyapunov函数存在性和状态模估计器存在性三者之间的关系. 借助状态模估计器将混杂系统化为受扰动系统,获得了受扰动系统一致输入输出对状态稳定性的结果,并进一步证明了混杂系统的一致输入输出对状态稳定性.     

A hybrid hub-and-spoke postal logistics network with realistic restrictions: A case study of Korea Post

Postal logistics has a complex transportation network for efficient mail delivery. Therefore, a postal logistics network consists of various functional sites with a hybrid hub-and-spoke structure. More specifically, there are multiple Delivery & Pickup Stations (D&PSs), multiple Mail Processing Centers (MPCs), and one Exchange Center (EC). In this paper, we develop two mathematical models with realistic restrictions for Korea Post for the current postal logistics network by simultaneously considering locations and allocations. We propose an Integer Linear Programming (ILP) model for transportation network organization and vehicle operation and a Mixed Integer Linear Programming (MILP) model that considers potential ECs for decision making while simultaneously regarding the EC location, transportation network organization, and vehicle operation. We use modified real data from Korea Post. Additionally, we consider several scenarios for supporting EC decision makers. The proposed models and scenarios are very useful in decision making for postal logistics network designers and operators.     

铝电解电容器用新型宽温高压工作电解液

采用异癸二酸铵为主溶质,乙二醇和γ-丁内酯为复合溶剂,制备新型宽温(-40~105℃)、高压(400 V)铝电解电容器工作电解液,并检测了该电解液和用该电解液生产的电解电容器的性能。测试结果表明,该工作电解液25℃时电导率达到1.6 mS/cm,闪火电压为480 V,-40℃下未见晶体析出;CD 110/400 V铝电解电容器试样的漏电流≤10μA,损耗0.03,容量变化率只有-3%。经过105℃高温贮存250 h后各项电气性能不仅优于国家标准,而且能达到严格的企业标准。