全文获取类型
收费全文 | 124741篇 |
免费 | 11156篇 |
国内免费 | 7323篇 |
专业分类
电工技术 | 14984篇 |
技术理论 | 18篇 |
综合类 | 7617篇 |
化学工业 | 12994篇 |
金属工艺 | 3467篇 |
机械仪表 | 4404篇 |
建筑科学 | 11197篇 |
矿业工程 | 2184篇 |
能源动力 | 25972篇 |
轻工业 | 2592篇 |
水利工程 | 1651篇 |
石油天然气 | 2483篇 |
武器工业 | 797篇 |
无线电 | 7694篇 |
一般工业技术 | 10900篇 |
冶金工业 | 4487篇 |
原子能技术 | 1575篇 |
自动化技术 | 28204篇 |
出版年
2024年 | 509篇 |
2023年 | 2918篇 |
2022年 | 4261篇 |
2021年 | 4774篇 |
2020年 | 5093篇 |
2019年 | 4907篇 |
2018年 | 4114篇 |
2017年 | 4742篇 |
2016年 | 4567篇 |
2015年 | 4366篇 |
2014年 | 8244篇 |
2013年 | 9092篇 |
2012年 | 7956篇 |
2011年 | 9316篇 |
2010年 | 7138篇 |
2009年 | 7631篇 |
2008年 | 7001篇 |
2007年 | 7280篇 |
2006年 | 5756篇 |
2005年 | 4653篇 |
2004年 | 3870篇 |
2003年 | 3472篇 |
2002年 | 3097篇 |
2001年 | 2548篇 |
2000年 | 2346篇 |
1999年 | 1983篇 |
1998年 | 1689篇 |
1997年 | 1424篇 |
1996年 | 1281篇 |
1995年 | 1039篇 |
1994年 | 925篇 |
1993年 | 816篇 |
1992年 | 627篇 |
1991年 | 579篇 |
1990年 | 470篇 |
1989年 | 368篇 |
1988年 | 310篇 |
1987年 | 257篇 |
1986年 | 208篇 |
1985年 | 272篇 |
1984年 | 267篇 |
1983年 | 217篇 |
1982年 | 213篇 |
1981年 | 127篇 |
1980年 | 115篇 |
1979年 | 110篇 |
1978年 | 76篇 |
1977年 | 77篇 |
1976年 | 22篇 |
1975年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
71.
Xueru Chen Yin Zhang Dashui Yuan Wu Huang Jing Ding Hui Wan Wei-Lin Dai Guofeng Guan 《材料科学技术学报》2021,71(12):211-220
Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations. 相似文献
72.
《Ceramics International》2022,48(11):15056-15063
Hydrogen (H2) sensors based on metal oxide semiconductors (MOS) are promising for many applications such as a rocket propellant, industrial gas and the safety of storage. However, poor selectivity at low analyte concentrations, and independent response on high humidity limit the practical applications. Herein, we designed rGO-wrapped SnO2–Pd porous hollow spheres composite (SnO2–Pd@rGO) for high performance H2 sensor. The porous hollow structure was from the carbon sphere template. The rGO wrapping was via self-assembly of GO on SnO2-based spheres with subsequent thermal reduction in H2 ambient. This sensor exhibited excellently selective H2 sensing performances at 390 °C, linear response over a broad concentration range (0.1–1000 ppm) with recovery time of only 3 s, a high response of ~8 to 0.1 ppm H2 in a minute, and acceptable stability under high humidity conditions (e. g. 80%). The calculated detection limit of 16.5 ppb opened up the possibility of trace H2 monitoring. Furthermore, this sensor demonstrated certain response to H2 at the minimum concentration of 50 ppm at 130 °C. These performances mainly benefited from the special hollow porous structure with abundant heterojunctions, the catalysis of the doped-PdOx, the relative hydrophobic surface from rGO, and the deoxygenation after H2 reduction. 相似文献
73.
In this paper, we present an aero‐structural model of a tethered swept wing for airborne wind energy generation. The carbon composite wing has neither fuselage nor actuated aerodynamic control surfaces and is controlled entirely from the ground using three separate tethers. The computational model is efficient enough to be used for weight optimisation at the initial design stage. The main load‐bearing wing component is a nontypical “D”‐shaped wing‐box, which is represented as a slender carbon composite shell and further idealised as a stack of two‐dimensional cross section models arranged along an anisotropic one‐dimensional beam model. This reduced 2+1D finite element model is then combined with a nonlinear vortex step method that determines the aerodynamic load. A bridle model is utilised to calculate the individual forces as a function of the aerodynamic load in the bridle lines that connect the main tether to the wing. The entire computational model is used to explore the influence of the bride on the D‐box structure. Considering a reference D‐box design along with a reference aerodynamic load case, the structural response is analysed for typical bridle configurations. Subsequently, an optimisation of the internal geometry and laminate fibre orientations is carried out using the structural computation models, for a fixed aerodynamic and bridle configuration. Aiming at a minimal weight of the wing structure, we find that for the typical load case of the system, an overall weight savings of approximately 20% can be achieved compared with the initial reference design. 相似文献
74.
Wassim Bahr 《国际自然能源杂志》2018,39(8):802-812
This paper assesses building integrated photovoltaic (BIPV) installation parameters based on the profit generated by a photovoltaic system. It takes into consideration a home building case study and it investigates its monthly energy demand based on a specific location and a typical occupancy. The capability of a photovoltaic (PV) system to generate more profit occurs when solar intensity is maximum while the electric energy price is at its highest rate. The paper traces a framework that encompasses different aspects such as energy demand, energy price, and solar intensity. This framework identifies profit alternatives according to different installation parameters. A tool that predicts a PV installation hourly electric energy production is developed. The profit generated is simulated for home buildings located in Beirut (Lebanon) and Xihua (China), both at 33.8° latitude north. The paper highlights a new approach for BIPV installations, taking into account weather conditions, energy demand, and electric energy utility rates. 相似文献
75.
《International Journal of Hydrogen Energy》2019,44(11):5189-5202
Independent hydrogen production from petrochemical wastewater containing mono-ethylene glycol (MEG) via anaerobic sequencing batch reactor (ASBR) was extensively assessed under psychrophilic conditions (15–25 °C). A lab-scale ASBR was operated at pH of 5.50, and different organic loading rates (OLR) of 1.00, 1.67, 2.67, and 4.00 gCOD/L/d. The hydrogen yield (HY) progressed from 134.32 ± 10.79 to 189.09 ± 22.35 mL/gMEGinitial at increasing OLR from 1.00 to 4.00 gCOD/L/d. The maximum hydrogen content of 47.44 ± 3.60% was achieved at OLR of 4.0 gCOD/L/d, while methane content remained low (17.76 ± 1.27% at OLR of 1.0 gCOD/L/d). Kinetic studies using four different mathematical models were conducted to describe the ASBR performance. Furthermore, two batch-mode experiments were performed to optimize the nitrogen supplementation as a nutrient (C/N ratio), and assess the impact of salinity (as gNaCl/L) on hydrogen production. HY substantially dropped from 62.77 ± 4.09 to 6.02 ± 0.39 mL/gMEGinitial when C/N ratio was increased from 28.5 to 114.0. Besides, the results revealed that salinity up to 10.0 gNaCl/L has a relatively low inhibitory impact on hydrogen production. Eventually, the cost/benefit analysis showed that environmental and energy recovery revenues from ASBR were optimized at OLR of 4.0 gCOD/L/d (payback period of 7.13 yrs). 相似文献
76.
Zhongkai Zhao Yohanes A. Situmorang Ping An Nichaboon Chaihad Jing Wang Xiaogang Hao Guangwen Xu Abuliti Abudula Guoqing Guan 《化学工程与技术》2020,43(4):625-640
In the future, hydrogen will be an important energy carrier and industrial raw material. Catalytic steam reforming of bio-oils is a promising and economically viable technology for hydrogen production. However, during the reforming process, the catalysts are rapidly deactivated due to coke formation and sintering. Thus, maintaining the activity and stability of catalysts is the key issue in this process. Optimized operation conditions could extend the catalyst lifetime by affecting the coke morphology or promoting coke gasification. This article summarizes the recent developments in the field of catalytic steam reforming of bio-oils, focusing on the operation conditions, the properties of the catalysts, and the effects of the catalyst supports. The expected insights into the catalytic steam reforming of bio-oils will provide further guidance for hydrogen production from bio-oils. 相似文献
77.
A hybrid sorbent material for removal of hydrogen sulfide from air was developed. The material is based on activated carbon and iron compounds obtained from waste iron(II) sulfate(VI) heptahydrate. The iron salt is deposited on the carbonaceous support and subjected to oxidation (Fe2+ to Fe3+) using atmospheric oxygen under alkaline conditions. An effect of H2O2 addition to the process on the composition of the resultant material was also examined. X-ray diffraction (XRD) analyses confirmed easy conversion of waste FeSO4·7H2O to iron oxides Fe3O4 and FeOOH. The activated carbon supporting iron oxides revealed a higher efficiency in H2S elimination from air compared to the commercial activated carbon, without any modification. 相似文献
78.
Somnath Karmakar 《Polycyclic Aromatic Compounds》2019,39(2):159-171
Eigensolutions of {X( = C,B,N),Y( = C,B,N)}-cyclacene graphs with next nearest neighbor (nnn) interactions have been obtained in analytical forms by adapting n-fold rotational symmetry followed by two-fold rotational symmetry (or a plane of symmetry). Expressions of eigensolution indicate the subspectral relationship among such cyclacenes with an even number of hexagonal rings e.g., eigenvalues of {X,Y}-di-cyclacene are found in the eigenspectra of all such even cyclacenes. Total π-electron energies and highest occupied molecular orbital and lowest unoccupied molecular orbital (HOMO–LUMO) gaps are calculated using the analytical expressions obtained and are found to vary negligibly with the variation of nnn interactions in such cyclacenes. Total π-electron energy is found to increase due to increase in restriction intensity of nnn interactions, whereas the HOMO–LUMO gap of polyacenecs having the even number of hexagonal rings and with one electron at each site (atom) decreases with increase in the restriction intensity since such systems contain degenerate half-filled HOMO (bonding or nonbonding) that are much more vulnerable for perturbations imposed through nnn interactions. 相似文献
79.
针对异构计算节点组成的大规模多状态计算系统的容错性能分析问题,提出了一种计算系统容错性能的评估方法。该方法采用自定义的两级容错性能形式化描述框架进行系统描述,通过构造多值决策图(Multi-value Decision Diagram,MDD)模型对系统进行容错性能建模,并基于构造的模型高效地计算出部件故障的条件下计算系统在特定性能水平上运行的概率,减少了计算的冗余性。实验结果表明,该方法在模型的大小和构建时间上均优于传统方法。该方法的提出将对系统操作员或程序设计者具有重要意义,使其确保系统适合预期应用。 相似文献
80.
Output feedback controller for polytopic systems exploiting the direct searching of the design space
This paper deals with the problem of designing a robust static output feedback controller for polytopic systems. The current research that tackled this problem is mainly based on LMI method, which is conservative by nature. In this paper, a novel approach is proposed, which considers the design space of the controller parameters and iteratively partitions the space to small simplexes. Then, by assessing the stability in each simplex, the solution space for design parameters is directly determined. It has been theoretically proved that, if there exists a feasible solution in the design space, the algorithm can find it. To validate the result of the proposed approach, comparative simulation examples are given to illustrate the performance of the design methodology as compared to those of previous approaches. 相似文献