Quantification of trace amounts of impurities in high purity cobalt by high resolution inductively coupled plasma mass spectrometry

An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au, and Pb) in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects because of the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the deter- mination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 μg?g?1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.     

Employing fractals and FEM for detailed variation analysis of non-rigid assemblies

Many studies on non-rigid assemblies, or assemblies of non-rigid components, suggest that the component variation affects the assembly dimensional quality. However, little is known about how the variation of surface micro-geometry of assembly components influences the assembly dimensional quality. In this paper, a new method based on the fractal geometry and finite element method (FEM) is proposed to study such an influence. In the new method, a special fractal function, named the Weierstrass–Mandelbrot (W–M) function, is used to extract and represent the characteristics of surface micro-geometry of assembly components. FEM is applied to analyze the deformation of non-rigid assemblies by integrating the variation of component micro-geometry. The sensitivity matrix between the component variation and assembly variation is obtained by using the existing influence coefficients method. It is found that contributions of the surface micro-geometry of assembly components to the final variation of non-rigid assemblies could be substantial under certain conditions. The proposed method is illustrated through a case study on an assembly of two flat sheet metal components under different fixture-releasing conditions.     

Elastic-plastic analytical solution for centric crack loaded by two pairs of point shear forces in finite plate

1 Introduction A great number of cracks exist in metal materials. Their existence and interaction often lead to high stress concentration and become the source of weakening and failure of metal materials[1- 4]. The elastic-plastic analysis for a cracked p…     

玻璃包覆纯铜微丝的制备与表征

采用熔融纺丝法制备了玻璃包覆纯铜微丝,对微丝进行了组织观察以及尺寸和缺陷表征,提出了不同冷却条件下的纯铜芯丝凝固过程模型,讨论了制备过程中存在的问题并提出了相应的解决方案.结果表明:在空气中自然冷却凝固的纯铜芯丝内部组织为细等轴晶,加冷却水快速冷却凝固制备的纯铜芯丝内部的晶粒沿着微丝长度方向呈竹节状整齐排列;当微丝外径为45μm、芯丝直径为25 μm时,外径尺寸波动在6%以内,芯丝直径误差小于4%;当原料质量存在问题或制备过程中拉丝速度、冷却速度等工艺参数匹配不合理时,易导致芯丝表面存在凹坑和凹槽等缺陷.     

镁基复合材料微区力学状态的有限元分析

弹性变形范围内,在采用三维有限元模型分析了颗粒增强Mg基复合材料(PRMMCs)中,颗粒的分布形态对材料微区力学状态的影响。结果表明,在保持颗粒长径比(2:1)和颗粒间距(d)不变的情况下,随着θ的变化,不存在颗粒断裂的危险,材料的主要失效方式为界面脱离和基体开裂。增强体相对夹角θ=15o时的结果优于其它情况,这更有利于充分发挥材料的性能。     

A1-Li合金的拉伸断裂过程研究

以2090 Ce合金为研究对象，对不同时效时间的室温拉伸断口进行了半定量分析，探讨了拉伸性能对断裂特征的响应关系，重点分析合金分层裂纹的形成过程。研究表明：2090 Ce合金的断裂方式以韧窝、分层开裂和沿亚晶界开裂3种为主，随时效时间的延长，韧窝、分层开裂逐渐减少，沿亚晶界开裂比例逐渐加大：分层开裂程度与时效程度有密切关系：分层开裂过程与试样内部受力状态、晶界状态有密切关系。分层最先发生在试样中心，随后在二分之一、四分之一……处反复发生，最终将试样分割成一系列平行的薄板。时效后期由于亚晶界的弱化，使裂纹倾向沿亚晶界扩展，从而抑制分层开裂的发生，同时导致合金强度，尤其是塑性的下降。     

液膜法分离富集,测定水中微量锶

用乳状液膜体系对锶进行分离富集，该体系包括协同流动载体（ＰＭＢＰ，ＴＢＰ），表面活性剂（ＳＰＡＮ８０）增强剂（丙三醇）溶剂（正己烷）和内相（１．２ｍｏｌ／Ｌ的盐酸溶液），实验表明，在适宜的条件下，锶的富集效率可达９９．５％以上，而在此条件下许多共存离子，如Ｆｅ＾３＋，Ａｌ＾３＋，Ｃａ＾２＋，Ｍｇ＾２＋，Ｂａ＾２＋，Ｃｒ＾３＋，ＣＯ＾２＋，Ｎｉ＾２＋，Ｚｒ＾４＋，Ｃｕ＾２＋，Ｚｎ＾２＋，Ｐｂ＾２＋和     

金属热塑性成型数值模拟中的时空耦合算法

提出一种应用于金属热塑性成型数值模拟中的时空耦合算法。将热力交织的非稳定非均质问题在时间和空间上分解开来,变成瞬间的稳定、均质问题和热力承转反馈的递推过程,并且能够进行各种关联成型行为的穿插计算,为成型模拟提供了更大的发展空间。     

铝/空心微珠复合材料弹性性能的预测研究

根据复合材料的基本原理建立了复合材料弹性模量的本构方程，在这基础上利用有限元的方法预测了空心微珠增强铝基复合材料的弹性模量，并在模拟中考察了空心微珠体积百分比（Vf）、空心微珠壁厚与空心微珠半径的比值（t／R）两个参数对弹性模量的影响。通过将有限元模拟结果与理论计算结果相比较，发现结果具有较好的一致性。由于有限元模型和公式是理想模型，其结果比实验值要高，为此，通过考虑空心微珠增强铝基复合材料的主要缺陷，从而使模拟值更接近于实验值。     

建立企业管理信息系统的思想、方法及其开发途径

本文以系统工程的思想和方法为指导,就企业如何建立管理信息系统,尤其是对认真做好各项前期准备工作等方面的问题,作了较全面、深入的论述。