原子吸收光谱法快速测定松香皂中几种金属元素

提出了用原子吸收光谱法快速测定松香皂中几种金属元素的方法。考察了元素干扰情况及灰化温度。该方法快速、简便、准确 ,RSD为 0 .95 %～ 2 .2 1% ,回收率为 95 .6 %～ 10 8.7%。     

膜催化反应器的分析与模拟

分析了膜反应器的出现、发展和最新研究。论述了几种膜反应器中气体的传递机理,定量分析了膜反应器中控制传递与反应的模型方程式以及计算机模拟和实验研究结果。最后评价了两类膜反应器的操作特性,以⊿n<0、⊿n=0和⊿n>0三类不同的催化反应作为模型反应与传统的PFR 和 MFR 的操作特性作了对比。     

Elastic–plastic response of structural foams subjected to localized static loads

Structural foams are increasingly used in engineering applications where high strength and low weight are important. They are used also as energy absorbers. Sandwich structures are a typical area for application of structural foams (as core materials). In a sandwich structure, the core transfers the transverse forces as shear stresses and supports the face sheets against buckling and wrinkling. The structural foams are notoriously sensitive to failure by the application of localized surface loads. Thus, the proper design requires an understanding of the mechanical response of the foam materials to localized external loads.In this paper, the elastic–plastic behavior of closed-cell cellular foams subjected to point and line loads is investigated both experimentally and numerically. Two types of Divinicell foam (H60 and H100) are studied. A finite element modeling procedure is developed using the ABAQUS package. Both plane and axisymmetric formulations for local indentations by rigid bodies are considered. The plastic behavior is described using the *CRUSHABLE FOAM HARDENING material model. This model is calibrated using experimental curves from uniaxial compression tests. Geometrical non-linearity is also taken into account. Both indentation and unloading phases are modeled. Static indentation tests of foam panels and beams are performed using spherical and cylindrical indentors, respectively. A comparison of indentation response obtained from the numerical analysis and from the tests is carried out. A good agreement between the modeling and the experimental data is achieved. In perspective view, the present investigation can contribute towards the development of a damage tolerance methodology for rigid foams.     

Plasma etching of high-k and metal gate materials

Etching characteristics of high-k dielectric materials (HfO₂) and metal electrode materials (Pt, TaN) have been studied in high-density chlorine-containing plasmas at pressures around 10 mTorr. The etching of HfO₂ was performed in BCl₃ without rf biasing, giving an etch rate of about 5 nm/min with a high selectivity of >10 over Si and SiO₂. The etching of Pt and TaN was performed in Ar/O₂ with high rf biasing and in Ar/Cl₂ with low rf biasing, respectively, giving a Pt etch rate of about several tens nm/min and a TaN etch rate of about 200 nm/min with a high selectivity of >8 over HfO₂ and SiO₂. The etched profiles were outwardly tapered for Pt, owing to the redeposition of etch or sputter products on feature sidewalls, while the TaN profiles were almost anisotropic, probably owing to the ion-enhanced etching that occurred.     

Preparation of a sensor substrate using functionalized mesoporous silica on a gold film for surface plasmon resonance (SPR) spectroscopy

The use of surface plasmon resonance (SPR) spectroscopy has been applied to a wide variety of fields such as biosensors and surface analysis instruments. In general, a SPR substrate is prepared using self-assembled monolayer (SAM) method of organic molecules as receptor for the target on a layer of gold or silver. However, mesoporous inorganic materials such as SBA-15 have benefits as sensor substrate for SPR. Mesoporous silica has a large surface area which receptor molecule can be attached and has a rigid body which has an excellent stability in the extreme condition compared to organic sensing layer. We prepared an organic modified mesoporous silica and successfully immobilized it on a gold surface, in an attempt to use as a substrate for SPR spectroscopy. For the comparison of sensitivity of prepared substrate, Pt²⁺ detection was selected as a model system. Substrate prepared in this study exhibited the capability of selective sensing for Pt²⁺ ions.     

多孔材料孔径及孔径分布的测定方法

孔径及其分布显著影响着多孔体的透过性、渗透速率、过滤性等一系列性能。本文介绍多孔材料孔径及其分布的常用测定方法，包括断面直接观测法、气泡法、透过法、压汞法、气体吸附法、液．液法、悬浮液过滤法、X射线小角度散射法等，并对几种测量方法进行了比较。     

Al-Ti纤维增强Mg合金复合材料的制备及其微观组织

本文采用粉末冶金工艺制备出了一种新的Al-Ti纤维增强Mg合金复合材料,经光学显微镜、扫描电子显微镜和X射线衍射分析,表明Al-Ti纤维在Mg合金基体中分布均匀,制备过程中没有被损伤.纤维/基体界面上有不连续的颗粒状Mg17Al12析出,此析出相直径小于1.5μm,且数量很少.     

Physical Modelling of Transport Phenomena in a Delta‐shaped,Four‐strand Tundish with Flow Modifiers

Experiments were conducted in a full‐scale physical model of a delta‐shaped, four‐strand tundish to study the effect of flow modifiers on tundish performance. Two different types of flow modifiers were studied; an existing flow‐modifier and a turbulence‐inhibitor. Their effects were quantified by measuring residence times of fluid in the tundish and residual ratios of inclusions. Although the Turbulence‐Inhibitor appeared to be more effective in guiding flows than the flow‐modifier, the latter gave the longer average residence times and smaller residence time differences between the inner and outer nozzles, which resulted in a higher residual ratio of inclusions.     

Fracture and microstructure of open cell aluminum foam

SEM and EDS measurements were used to scrutinize the microstructure of Duocel open cell 6101 aluminum foam in relation to its fracture properties. In-situ SEM tensile tests on the open cell aluminum foam were performed to investigate the different fracture modes of struts and Aramis/Digital Image Correlation software was used to map the strain in individual struts. Observations during tensile tests showed that the microstructure of the struts has a great influence on the fracture behaviour of the foam. In particular AlFeSi-precipitates, which are due to the casting of the 6101 aluminum alloy, and the morphology of the foam alters the fracture mode of the struts in the foam from transgranular to intergranular. Less energy is needed for intergranular fracture of struts and the strain to failure of the foam is decreased due to weak individual struts.     

Damage Tolerant Magnesium Metal Matrix Composites: Influence of Reinforcement and Processing

A growing impetus to enhance our understanding of the behavior of magnesium-based alloys for use in weight critical applications resulted as a consequence of the low density of magnesium. In an attempt to enhance the applicability of magnesium for a wide spectrum of performance-critical applications, the addition of reinforcement to the alloy was considered as an economically affordable and potentially viable scientific alternative. In this paper are reported the results of a study aimed at understanding the influence of saffil alumina short fiber reinforcement on microstructural development of a squeeze-cast magnesium alloy. Preliminary results confirm promise of the reinforced alloy, which retains hardness, strength, and stiffness better at elevated temperatures compared to the unreinforced counterpart. However, impact strength and toughness of the reinforced alloy are inferior. The importance of the matrix alloy in governing the overall mechanical response of the composite microstructure is discussed based on fractographic observations. The importance of volume fraction of the reinforcing phase on properties of the composite microstructure is highlighted.