原子荧光光谱法测定搪瓷容器中微量溶出锑的研究

采用氢化物发生-原子荧光光谱法,用L-半胱氨酸预还原锑,对搪瓷容器中微量溶出锑进行了分析,讨论并确定了实验的最佳测定条件.结果表明,锑的检出限为0.235μg/L,回收率为89.0%～104.2%,相对标准偏差为0.8%.该法准确、快速、简便.     

Controlled destruction of residual crosslinker in a silicone elastomer for drug delivery

In drug delivery systems that use silicone elastomers as a diffusion matrix for the active drug, it is common to crosslink the material by the hydrosilylation reaction. In this platinum‐catalyzed reaction, vinyl groups on a polymer add to the methyl siloxane hydride (MHS) groups on a low molecular mass crosslinker. With an excess of crosslinker, a fast curing is achieved and a fully crosslinked material is formed. Unreacted MHS groups were shown to remain in the elastomer after curing because of the excess crosslinker. In this work, a simple procedure was developed to eliminate the unreacted MHS groups from the final product. We found that storage of the product at +40°C and 75% relative humidity for a few weeks will effectively destroy the residual MHS groups in the elastomer. The effects of varying levels of humidity, oxygen, and temperature on this postcuring procedure were studied. The amount of MHS groups was measured with NMR and IR spectroscopy. We also found that the hardness of the material increased by approximately 25% as a consequence of this postcuring treatment. This increase is probably due to a secondary crosslinking reaction between MHS and silanol groups. Heat treatment at higher temperatures led to an even further increase in the hardness and compression modulus. Because no MHS groups remained in the elastomer when this heat treatment was started, it is apparent that another secondary crosslinking reaction is occurring, probably silanol condensation. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2254–2264, 2002     

Effect of the metal oxide loading on the activity of silica supported MoO3 and V2O5 catalysts in the selective partial oxidation of methane

Precipitated silica catalysts loaded with either MoO₃ (0.2–4.0 wt%) or V₂O₅ (0.2–5.3 wt%) have been studied in the selective partial oxidation of methane to formaldehyde with molecular oxygen at 520 °C. The functionality of the SiO₂ surface towards the formation of HCHO is significantly promoted by V₂O₅, while it is depressed by the MoO₃.     

汽车尾气用催化剂载体研究现状及展望

汽车尾气催化净化器中，催化剂载体是实现高效尾气净化的一个关键因素。本文综述了对尾气净化催化剂载体的要求和研究现状。并提出导电型复合陶瓷是今后尾气净化载体材料研究和发展的一个新型方向。     

《铁碳合金相图》的教学探究

本文对Fe-Fe3C相图和它的教学设计进行了全面分析,特别用简而易懂的5单7双3线9点方法对铁碳合金相图进行了详细的分析,使得原本枯燥难懂的理论变得形象生动。     

Highly stable novel inorganic hydrides from aqueous electrolysis and plasma electrolysis

After 10⁴ h of continuous aqueous electrolysis with K₂CO₃ as the electrolyte, highly stable novel inorganic hydride compounds such as KH KHCO₃ and KH were isolated and identified by time of flight secondary ion mass spectroscopy (ToF-SIMS). The existence of novel hydride ions was determined using X-ray photoelectron spectroscopy (XPS) and solid state magic-angle spinning proton nuclear magnetic resonance spectroscopy (¹H MAS NMR). A novel hydride ion formed by plasma electrolysis of a K₂CO₃, Rb₂CO₃, or Cs₂CO₃ electrolyte was also observed by high resolution visible spectroscopy at 407.0 nm corresponding to its predicted binding energy of 3.05 eV.     

金属—橡胶硫化粘接复合体剥离破坏行为的研究

本文分析了对橡胶分子链特性、部分交联弹性聚合物材料的粘弹行为及金属──橡胶硫化粘接体剥离过程中聚合物分子链的应力分布状况和剥离破坏模型，认为粘着一滑动（Stick—slip）模型剥离破坏并非是橡胶类材料的固有特征，而是由于金属──橡胶硫化粘接过程中的分子取向交联和部分交联弹性材料多个凯尔文（Kelvin）模型粘弹行为的综合结果．同时指出单从剥离试验的结果难以表征金属——橡胶硫化粘接复合作的粘接效果．     

Adsorption of mercaptopropionic acid onto Au(1 1 1): Part II. Effect on copper electrodeposition

Copper deposition in the presence of an organic additive (3-mercaptopropionic acid, MPA) was studied by cyclic voltammetry and in situ scanning tunneling microscopy (STM) and the results are compared to those for additive-free solutions. It is shown that underpotential deposition (upd) of copper onto a fully MPA-covered electrode produces a defect-rich substrate, but the defects are blocked by the dense organic film for bulk deposition, resulting in a low number of nuclei. A grain-refining effect of MPA, however, was found, when Cu deposition was initiated shortly after addition of MPA to the solution, i.e., for a low-coverage MPA adlayer.     

全启发式教学法在“金属切削机床与刀具”课程中的应用

针对当代大学生的特点,阐述了来自于建构主义的全启发式教学方法的理论,对“金属切削机床与刀具”课程内容进行问题分解,采用以启发诱导、共同协作为核心的全启发式教学方法,对该课程的教学环节进行了合理的设计。     

一个国际产、学、研结合的范例--美国伍斯特工学院金属研究所

简要介绍美国伍斯特工学院金属研究所(MPI)在产学研结合方面的成功经验.美国伍斯特工学院是美国历史上第3所工科院校,以重视与企业合作进行工程教育而闻名.MPI是大学研究所与企业的联合体,有包括福特汽车公司、北美压铸协会等131个大大小小的企业及工业协会参加这一联合体.致力于进行针对企业存在的技术问题的基础与应用研究,开发和示范最先进的金属加工技术,为工业合伙人培训雇员等.会员自愿入会,交纳会费,由会员代表组成指导委员会,汇集和整理企业提出的技术需求,每年从中提炼出两个共性的问题,交由MPI进行研究.同时,MPI也同联合体成员共同承担美国政府资助的研究项目,这类项目多数由企业部分出资.研究工作以MPI与企业密切结合的方式开展.联合体每年举办两次会议,由MPI向企业汇报研究结果,交换信息.联合体也以伍斯特工学院为依托,开展企业的人员培训工作.