全文获取类型
收费全文 | 23826篇 |
免费 | 2847篇 |
国内免费 | 1058篇 |
专业分类
电工技术 | 273篇 |
技术理论 | 2篇 |
综合类 | 1130篇 |
化学工业 | 6844篇 |
金属工艺 | 1420篇 |
机械仪表 | 762篇 |
建筑科学 | 1453篇 |
矿业工程 | 502篇 |
能源动力 | 1634篇 |
轻工业 | 2084篇 |
水利工程 | 216篇 |
石油天然气 | 1401篇 |
武器工业 | 327篇 |
无线电 | 3427篇 |
一般工业技术 | 4999篇 |
冶金工业 | 591篇 |
原子能技术 | 164篇 |
自动化技术 | 502篇 |
出版年
2024年 | 124篇 |
2023年 | 777篇 |
2022年 | 691篇 |
2021年 | 1010篇 |
2020年 | 1077篇 |
2019年 | 1002篇 |
2018年 | 862篇 |
2017年 | 975篇 |
2016年 | 930篇 |
2015年 | 932篇 |
2014年 | 1533篇 |
2013年 | 1542篇 |
2012年 | 1573篇 |
2011年 | 1763篇 |
2010年 | 1251篇 |
2009年 | 1368篇 |
2008年 | 1175篇 |
2007年 | 1388篇 |
2006年 | 1300篇 |
2005年 | 1089篇 |
2004年 | 883篇 |
2003年 | 842篇 |
2002年 | 585篇 |
2001年 | 542篇 |
2000年 | 481篇 |
1999年 | 379篇 |
1998年 | 285篇 |
1997年 | 248篇 |
1996年 | 233篇 |
1995年 | 184篇 |
1994年 | 160篇 |
1993年 | 117篇 |
1992年 | 86篇 |
1991年 | 72篇 |
1990年 | 42篇 |
1989年 | 41篇 |
1988年 | 21篇 |
1987年 | 26篇 |
1986年 | 18篇 |
1985年 | 33篇 |
1984年 | 15篇 |
1983年 | 16篇 |
1982年 | 14篇 |
1981年 | 5篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1964年 | 2篇 |
1951年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
研究了DHDECMP-TBP/煤油萃取HNO3后形成和防止形成第二有机相的各影响因素。以Gd代表稀土,探讨了DHDECMP-TBP/煤油萃取稀土时DHDECMP浓度、TBP浓度、水相HNO3浓度和温度对有机相萃取负载量的影响。结果表明:0.60mol/LDHDECMP-1.40mol/LTBP/煤油能有效避免第二有机相的形成,又能满足工艺负载量的要求。 相似文献
62.
复垦土地是重要的后备土地资源,但通常土壤结构差、有机质和养分含量低;增施有机肥是快速提升地力的关键途径,但会造成温室气体如氧化亚氮(N2O)的大量排放.接种具有N2O还原功能的植物根际促生菌(PGPR)不仅能够减少温室气体排放,还能促进作物生长.本研究以一株具有N2O还原功能的PGPR反硝化无色杆菌(Achromobacter denitrificans) YSQ030为供试菌株,明确接种YSQ030对施用有机肥的复垦土壤N2O排放和氮循环关键功能基因的影响.通过设置施用有机无机复混肥和羊粪有机肥的土壤微宇宙试验,利用气相色谱仪分析接种YSQ030后土壤N2O排放通量,进一步计算累积排放量;在试验结束后分析土壤pH、EC(电导率)、硝态氮和铵态氮含量,并利用实时荧光定量PRC分析土壤硝化功能基因(AOA amoA和AOB amoA)和反硝化功能基因(nirS、nirK、nosZ Ⅰ 和nosZ Ⅱ)的丰度.结果显示,施用有机无机复混肥和羊粪有机肥的土壤中接种YSQ030明显减少复垦土壤N2O排放,N2O排放量最大减少分别达90.4%和30.6%.施用有机无机复混肥处理的N2O排放量远高于施用羊粪有机肥处理,这可能是由于施用有机无机复混肥的土壤与施用羊粪有机肥的土壤相比,土壤中编码反硝化细菌N2O还原酶基因nosZ Ⅰ 和非典型反硝化细菌N2O还原酶基因nosZ Ⅱ 基因丰度较低.施用有机无机复混肥均显著降低土壤硝化和反硝化功能基因丰度,而施用羊粪有机肥对土壤硝化和反硝化功能基因丰度大多没有明显影响.本研究表明,接种YSQ030能够减少施用有机肥土壤的N2O排放,将为复垦土壤地力提升和N2O减排提供科学依据,也将为研发新型微生物肥料或生物有机肥提供核心菌种资源. 相似文献
63.
Christian Friebe Martin D. Hager Andreas Winter Ulrich S. Schubert 《Advanced materials (Deerfield Beach, Fla.)》2012,24(3):332-345
Electropolymerization represents a suitable and well‐established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal‐functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research. 相似文献
64.
65.
Eiji Kamio Tomoki Yasui Yu Iida Jian Ping Gong Hideto Matsuyama 《Advanced materials (Deerfield Beach, Fla.)》2017,29(47)
Highly robust ion gels, termed double‐network (DN) ion gels, composed of inorganic/organic interpenetrating networks and a large amount of ionic liquids (ILs), are fabricated. The DN ion gels with an 80 wt% IL content show extraordinarily high mechanical strength: more than 28 MPa of compressive fracture stress. In the DN ion gel preparation, a brittle inorganic network of physically bonded silica nanoparticles and a ductile organic network of polydimethylacrylamide (PDMAAm) are formed in the IL. Because of the different reaction mechanisms of the inorganic/organic networks, the DN ion gels can be formed by an easy and free‐shapeable one‐pot synthesis. They can be prepared in a controllable manner by manipulating the formation order of the inorganic and organic networks via not only multistep but also single‐step processes. When silica particles form a network prior to the PDMAAm network formation, DN ion gels can be prepared. The brittle silica particle network in the DN ion gel, serving as sacrificial bonds, easily ruptures under loading to dissipate energy, while the ductile PDMAAm network maintains the shape of the material by the rubber elasticity. Given the reversible physical bonding between the silica particles, the DN ion gels exhibit a significant degree of self‐recovery by annealing. 相似文献
66.
Ning-Wei Lai Zhi-Chao Zheng Dan Hua Jiang Zhang Huan-Huan Chen Xin Ye Zeng-Rong Huang Jiuxin Guo Lin-Tong Yang Li-Song Chen 《International journal of molecular sciences》2022,23(10)
Low pH-induced alterations in gene expression profiles and organic acids (OA) and free amino acid (FAA) abundances were investigated in sweet orange [Citrus sinensis (L.) Osbeck cv. Xuegan] leaves. We identified 503 downregulated and 349 upregulated genes in low pH-treated leaves. Further analysis indicated that low pH impaired light reaction and carbon fixation in photosynthetic organisms, thereby lowering photosynthesis in leaves. Low pH reduced carbon and carbohydrate metabolisms, OA biosynthesis and ATP production in leaves. Low pH downregulated the biosynthesis of nitrogen compounds, proteins, and FAAs in leaves, which might be conducive to maintaining energy homeostasis during ATP deprivation. Low pH-treated leaves displayed some adaptive responses to phosphate starvation, including phosphate recycling, lipid remodeling, and phosphate transport, thus enhancing leaf acid-tolerance. Low pH upregulated the expression of some reactive oxygen species (ROS) and aldehyde detoxifying enzyme (peroxidase and superoxidase) genes and the concentrations of some antioxidants (L-tryptophan, L-proline, nicotinic acid, pantothenic acid, and pyroglutamic acid), but it impaired the pentose phosphate pathway and VE and secondary metabolite biosynthesis and downregulated the expression of some ROS and aldehyde detoxifying enzyme (ascorbate peroxidase, aldo-keto reductase, and 2-alkenal reductase) genes and the concentrations of some antioxidants (pyridoxine and γ-aminobutyric acid), thus disturbing the balance between production and detoxification of ROS and aldehydes and causing oxidative damage to leaves. 相似文献
67.
68.
69.
Dong‐Hui Yang Lingjun Kong Ming Zhong Jian Zhu Xian‐He Bu 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(3)
The development of cost‐effective and flexible electrodes is demanding in the field of energy storage. Herein, flexible FexOy/nitrogen‐doped carbon films (FexOy/NC‐MOG) are prepared by facile electrospinning of Fe‐based metal–organic gels (MOGs) followed by high‐temperature carbonization. This approach allows the even mixing of fragile coordination polymers with polyacrylonitrile into flexible films while reserving the structural characteristics of coordination polymers. After thermal treatment, FexOy/NC‐MOG films possess uniformly distributed FexOy nanoparticles and larger accessible surface areas than traditional FexOy‐NC films without MOG. Taking advantage of the unique structure, FexOy/NC‐MOG exhibits a superior rate performance (449.8 mA h g?1 at 5000 mA g–1) and long cycle life (629.3 mA h g–1 after 500 cycles at 1000 mA g–1) when used as additive‐free anodes in lithium‐ion batteries. 相似文献
70.