Differences in the structure of copper active sites for decomposition and selective reduction of nitric oxide with hydrocarbons and ammonia

Cu ion co-ordination-location in zeolites of MFI, erionite, mordenite matrices has been determined and the activity of the individual Cu sites compared for NO decomposition and its selective reduction by hydrocarbons or ammonia. It appears that Cu ions in the vicinity of one framework Al (site II), able to form stable Cu⁺-dinitrosyl complexes, and abundant in MFI structure, are responsible for high activity in NO decomposition. The Cu ions neighbouring two framework Al atoms (site I), and forming mostly mononitrosyl complexes, which dominate in erionite structure, provide a high activity in selective reduction of NO.     

Red emission from Eu3+: PVA polymer film

Bright red luminescent Eu³⁺ doped polyvinyl alcohol (PVA) films were made by solution casting technique. The emission performance of these films was studied from the measurement of excitation, emission, and lifetimes. On irradiation with an UV source, the doped films emitted bright red light. Such luminescent polymer films are expected to find potential applications as new optical materials. Emission process in the system was explained by an energy level scheme. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3273–3276, 2006     

ⅡB族同核准分子Hg2226.2nm漫射带研究

本文报导在高纯Ｈｇ蒸气石英放电管中首次观测到峰值位于２２６．２ｎｍ左右属于Ｈｇ２准分子ＧＯ＾＋ｕ→ＸＯ＾＋ｇ束缚→自由跃迁的漫射带辐射，实验测量了漫射带强度随放电电流、气体温度和密度的变化关系，获得漫射带最大信号输出的工作参量。     

基于智能垃圾桶的垃圾分类动态收运路径优化问题研究

针对城市生活垃圾分类收运过程中存在的环境二次污染和垃圾产生量不确定性等问题,提出了一种基于智能垃圾桶的动态收运车辆路径优化方法。建立以最小化碳排放成本、燃油消耗成本、固定成本和车辆延迟到达惩罚成本为目标的动态车辆路径优化模型。采用滚动时域的方式将动态问题转换为一系列静态问题,并设计两阶段算法进行求解。首先采用粒子群算法对收运车辆路径进行规划,而后在每个时域末,综合考虑待清运垃圾桶的位置和垃圾量、垃圾收运车辆的位置和装载量以动态调整现有车辆路径。研究结果表明,相较于传统的静态收运方案,动态垃圾收运方案能够在降低车辆运输成本和碳排放成本的同时,显著降低由于清运不及时造成的环境二次污染的风险。     

海绵城市建设的技术装备应用综述

结合某区域海绵城市建设,从源头减排、过程控制、系统治理3个方面重点介绍了透水铺装、CSO调蓄池、一体化水处理设备等项目各阶段涉及的主要技术装备。同时,归纳总结了各阶段其他技术装备的特点及适用条件,指出海绵城市建设技术装备体系将向预制化、集成化和运程简易化方向发展。     

小浪底细砂岩单轴压缩声发射特征研究

采用岩石伺服试验机和声发射仪,对小浪底三叠系细砂岩进行单轴压缩声发射试验。基于试验结果,将试样变形过程划分为压密、弹性、塑性和破坏四个阶段,分析了不同阶段试样声发射幅值、峰值频率、振铃计数和能量的变化特征,在此基础上对比分析了试样声发射ｂ值以及累计振铃计数的演化规律,得出了岩石的破坏时间前兆特征。研究结果表明:压密和弹性阶段试样声发射幅值、振铃计数和能量处于较低水平、峰值频率频带数量依次增多;塑性阶段试样幅值增大、振铃计数与能量上升且整体处于较高水平、峰值频率数值增大且呈现多频带化,临近破坏阶段试样产生大量100ｄＢ的高幅值信号,振铃计数与能量持续急增,峰值频率降低,频带减少;声发射ｂ值的变化规律可以间接反映岩体内部微裂隙萌生、扩展的演化特征。     

基于径向基的瓦斯涌出量灰色预测模型

为了进一步预防煤层瓦斯突出,实现准确、快速预测煤矿瓦斯涌出量的大小,首先采用1-AGO对样本数据进行处理,建立灰色(GM)预测模型,再利用径向基(RBF)神经网络对灰色预测模型结果进行预测,以作为其最终的预测值;采用阜新煤矿某工作面瓦斯涌出量的历史数据进行建模,实验结果表明,GM-RBF组合模型在预测精度及训练误差方面均优于单一的GM模型和RBF神经网络预测模型;算法计算简便,减弱了数据的随机性及模型误差,煤矿瓦斯涌出量的预测平均误差减小到1.57%。     

An improved bacterial foraging algorithm for combined static/dynamic environmental economic dispatch

Economic dispatch is carried out at the energy control center to find out the optimal output of thermal generating units such that power balance criterion is met, unit operating limits are satisfied and the fuel cost is minimized. With growing environmental awareness and strict government regulations throughout the world, it has become essential to optimize not only the total fuel cost but also the harmful emissions, both, under static as well as dynamic conditions. The static environment economic dispatch finds the optimal output of generating units for a fixed load demand at a given time, while the dynamic environmental economic dispatch schedules the output of online generators with changing power demands over a certain time period (normally one day) so as to minimize these two conflicting objectives, simultaneously. In this paper, the price penalty factor approach is employed for simultaneous minimization of cost and emission. The generator ramp rate constraints, non-convex and discontinuous nature of cost function and the large number of generators in practical power plants, make this problem very difficult to solve. Here, a fuzzy ranking approach is employed to identify the solution which offers the best compromise between cost and emission objectives.     

The adsorption characteristics of two Mo sites on a sulfided MoO3/γ-Al2O3 surface

The surface structure of the oxidized and ammonia dissolved MoO₃/-Al₂O₃ samples and the adsorption characteristics of the sulfided samples were investigated by Laser Raman Spectroscopy (LRS) and Low Temperature Infrared Spectroscopy (LTIR) techniques.It was verified that there were two kinds of coordinated unsaturated Mo sites (denoted as Mo_A(CUS) and Mo_B(CUS)) on the surface and the precursors of Mo_A(CUS) and Mo_B(CUS) were Mo(O) and Mo(T), respectively. It was also concluded that Mo_A(CUS) sites could adsorb NO and CO, while Mo_B(CUS) could adsorb CO only. The surface concentration of Mo_A(CUS) might be far smaller than that of Mo_B(CUS).     

An enhanced,acoustic emission-based,single-fiber-composite test

In the single-fiber-composite (SFC) test, a fiber imbedded in a matrix is loaded in tension, resulting in a fragmentation of the fiber. In the conventional version of this test, the final fiber fragmentation length distribution is used with a micro-mechanical model to determine the average fiber/matrix interfacial shear stress. In the enhanced version of this test, one also determines the applied stress at each fiber fracture, and from this, one can evaluate the strength of the fiber at short gage lengths. In our measurement system, we utilize an acoustic emission (AE) technique to detect the fiber fractures and to locate the fiber breaks and so determine both the fiber failure stresses as well as the fiber fragmentation lengths while the test is in progress. Critical to the success of this test is a broadband AE system that utilizes point-like AE sensors, procedures for evaluatingin situ, the wavespeed of the first wave arrival and signal processing techniques for determining the arrival time of this signal as precisely as possible for a broad range of wave shapes. Here we describe the application of such an enhanced SFC test procedure to investigate the failure of a Nicalon fiber in an epoxy matrix.