两种具有电双稳态的全有机络合物

首次发现两种在室温下即具有电双稳态的全有机（有机-有机）络合物，分别称为MCA＋TCNQ和BBDN＋TCNQ。它们可在真空中制备成薄膜，在数伏电压的作用下，从高电阻至低电阻的跃迁时间小于100ns，因此可作为一次写入的存储器材料。根据我国目前最小刻线宽度的水平，可望在1．6cm2的SiO2平面上做出64Mb的存储器。     

Effects Of Ozone On The Production Of Biodegradable Dissolved Organic Carbon (BDOC) During Water Treatment

This article deals with the oxidation effect of ozone on the increasing fraction of biodegradable organic matter with the “ozotest” method, a laboratory technique which simulates the effect of ozonation and allows a complete oxidation assessment. Ozone treatment was performed on river water samples and sand filter effluent samples. Ozone consumption, reduction of UV absorbance and BDOC formation were monitored with applied ozone doses from 0 to 10 mg/L and with contact times from 0 to 60 min. The BDOC formation was optimum at an applied ozone dose of 0.25-0.5 mg O₃ per mg DOC (contact time = 5 min) corresponding to apparition of traces of residual ozone and maximum UV reduction. Maximum ozone consumption, UV reduction and BDOC formation occurred simultaneously during the first two minutes of treatment. Concerning BDOC formation, applied ozone dose showed a greater effectiveness than contact time. For the same quantity of consumed ozone, a short contact time associated with a high ozone dose was preferable to a long contact time and a low ozone dose.     

A new class of corrosion inhibitors for waterborne coatings: 4-methyl-γ-oxo-benzene-butanoic acid complexes

Amine and transition metal based complexes with 4-methyl-γ-oxo-benzene-butanoic acid represent a new class of corrosion inhibitors specifically designed for long-term corrosion protection in waterborne coatings. Today, corrosion protection in waterborne technology is typically achieved using traditional anticorrosive pigments initially developed for use in solventborne coatings. Regulations concerning heavy metals and limitations regarding the compatibility and performance of such materials in waterborne coatings have created a need for novel approaches. Mechanistic aspects are discussed for the 4-methyl-γ-oxo-benzene-butanoic complexes based on electrochemical solution experiments (electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV)) and investigations performed on coated substrates. Exposure results underline the high efficiency of such complexes for both long-term corrosion protection and weld seam rust control in waterborne coatings.     

The Chemistry of Water Treatment Processes Involving Ozone,Hydrogen Peroxide and Ultraviolet Radiation

Advanced oxidation processes are defined as those which involve the generation of hydroxyl radicals in sufficient quantity to affect water purification. The theoretical and (practical yield of OH from O₃ at high pH, 0₃/H₂0₂, O₃/UV and H₂O₂/UV systems is reviewed. New data is presented which illustrates the importance of direct photolysis in the O₃/UV process, the effect of the H₂0₂:0₃ ratio in the O₃/H₂O₂ process, and the impact of the low extinction coefficient of H₂O₂ in the H₂0₂/UV process.     

Interactions Between Ozone,Halogens and Organic Compounds

During drinking-water treatment, ozone used as a preoxidant and chlorine required for final disinfection, lead to competing chemical reactions, in the case of raw water containing both organic compounds and inorganic salts (such as bromides and ammonia).

The study of the interactions between those reactants has been made according to the following main topics :

As for THM formation, experiments conducted on simple organic compounds or on natural fulvic acids show important decreases in THM or TCAA formation after ozonation. It may be noticed, however, that the ozonation of surface waters may induce the formation of haloform precursors, usually with a low level of reactivity.

In water supplies containing bromide ions, oxidation of the latter through hypobromous acid may take place during the ozonation stage. Failing preozonation treatment, hypobromous acid is generated very rapidly during chlorination, thus inducing the formation of chloro- brominated organic compounds.

During the ozonation of fulvic acid solutions, the presence of small amounts of bicarbonate was found to improve precursor removal significantly.

It can be concluded that the partial analogy of the action of ozone or chlorine on aromatic structures, whether simple or complex (such as humic and fulvic acids), seems to indicate that the consequence of preozonation is the destruction, at least in part, of the most reactive sites for THM production, thus leading to a decrease of the volatile organochlorinated compounds formed during the post-chlorination. However, some ozonation products of natural waters are THM precursors, though of low reactivity. Then, in the presence of bromide ions, the formation of volatile organobrominated compounds may be observed during ozonation.     

Oxidation Of Iron And Manganese By Ozone

The oxidation of iron and manganese by ozone was studied in the laboratory. Model waters both with and without organic matter were used. Results showed iron to be very rapidly oxidized to an insoluble form in the absence of organic matter. However, in the presence of organic matter the iron was protected from oxidation by ozone and precipitation. The degree to which this occurred depended on the nature of the organic matter and the chemical environment at the time of mixing the iron stock and the dissolved organic matter.

Experiments with manganese allowed the determination of second order rate constants for the reaction of ozone with manganese at various pH values. The oxidation of manganese in the presence of organic matter occurred in competition with oxidation of the organic matter. As a result, high ozone doses were required to achieve the same degree of removal of manganese. An increase in bicarbonate alkalinity from 50 mg/L to 200 mg/L did not result in an acceleration of the manganese oxidation in the absence of organic matter. However, in the presence of organic matter, higher levels of bicarbonate created conditions that resulted in more complete oxidation of the manganese following total consumption of the dosed ozone.     

Characterization of humified substances in organic fertilizers by means of analytical electrofocusing (EF): A first approach

The objectives of the study were to test the electrofocusing technique to determine its suitability as a method for the characterization of organic fertilizers from a qualitative point of view and identification of the organic matrix in an unknown fertilizer; no laboratory methods for this purpose are presently available.Analytical electrofocusing (EF) is shown to fulfill these objectives and may be easily adopted as a routine manual procedure. A solution of sodium hydroxide was chosen as the extractant because it allows comparisons between various types of humified materials and permits the evolution of organic matter to be followed during maturation of the fertilizer itself. The organic fertilizers considered included many nitrogen-rich waste materials, mostly of animal origin. They are divided into different groups according to origin and EF profiles.     

Retrofitting of pedestrian overpass by Truss-Z modular systems using graph-theory approach

Installing pedestrian ramps is a common improvement towards a barrier-free environment. This paper introduces a graph-theoretical method of retrofitting of a single-branch Truss-Z (TZ) ramp in a constrained environment. The results produced by this exhaustive search method are usually ideal and better than those produced previously with meta-heuristic methods.A large case study of linking two sections of the Hongo Campus of Tokyo University using an overpass in an extremely constrained environment is presented. TZ modules with 1:12 (8.3%) slope are used, which is allowable in most countries for ramps for self-powered wheelchairs.The results presented here are highly satisfactory both in terms of structural optimization and aesthetics.Visualizations of the TZ ramp system, composed of 124 units, are presented.     

Dynamic shading of a building envelope based on rotating polarized film system controlled by one-dimensional cellular automata in regular tessellations (triangular,square and hexagonal)

The original prototype of the cellular automaton (CA) shading system (CASS) for building facades was based on rectangular array of cells and used liquid crystal technology. This paper introduces polarized film shading system (PFSS) – an alternative approach based on opto-mechanical modules whose opacity is a function of the rotation of polarized film elements. PFSS in regular tessellations: triangular, square and hexagonal are discussed. Simulations for each type of tessellation are presented and visualized. Visual attractiveness of emergent CA patterns manifested by “particles” and “solitons” is discussed.     

有机物料及其配施在潮土中的残留特点

试验采用尼龙布袋埋袋法研究了5种单一物料(玉米秸、稻秸、苜蓿、鸡粪、猪粪)和2种混合物料(玉米秸-猪粪-鸡粪、苜蓿-猪粪-鸡粪)在潮土中的腐解状况,以了解土壤中有机质的积累规律,探讨有机肥料对土壤的培肥效果。研究结果表明,玉米秸、稻秸、苜蓿、鸡粪、猪粪等是增加土壤有机质的较好物料;对C/N比较高的物料,当增加N素(添加猪粪、鸡粪这些氮含量较高的物料)、调节C/N比值时,可以促进混合物料有机碳的分解和向腐殖质的转化。