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排序方式: 共有6281条查询结果,搜索用时 15 毫秒
31.
徐宝成 《石油化工安全环保技术》2006,22(1):31-34
有机过氧化物是烯烃聚合工业中重要的引发剂。针对烯烃聚合工业用有机过氧化物自分解温度低、易发生反应失控引发火灾爆炸等情况,简要叙述了有机过氧化物的结构、分类、化学性质以及反应特性,重点对其储存、使用、管理等过程中的危险性进行了分析。提出过氧化物储存、运输、使用、报废等方面的风险消减与事故预防措施。 相似文献
32.
Franz Schauer 《Solar Energy Materials & Solar Cells》2005,87(1-4):235
Basic suppositions and microphysical origin of the occurrence of the space-charge-limited currents (SCLC) are presented in general and for the temperature-modulated space-charge-limited currents (TM-SCLC) in particular. The criteria are given for the spectroscopical method TM-SCLC to be used for localized electron states elucidation in organic semiconducting materials for organic solar cells optimization and modelling. The “visibility “of the localized states by SCLC method, i.e. the power of the SCLC method to distinguish the localized states, is tested by the modelling, varying the temperature, energy position of localized states and their concentration. Generally, it was determined that the SCLC measurements results are more reliable with the increased energy of the states, with their increased concentration and with decreased temperature. The correlation (or its absence) between the measured current and activation energy on applied voltage, expressed by the dependence of preexponential factor of conductivity on activation energy (Meyer–Neldel rule), gives the possibility to determine the energy range where the reconstruction of density of localized states function is reliable. 相似文献
33.
Wenying Wei Zhen Wang Yanhua Yin Jinyu Han Wen Xu 《Korean Journal of Chemical Engineering》2008,25(3):562-567
Composition Group Vector Space (CGVS) method for estimating melting and boiling point T
m
, T
b
of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T
m
, T
b
have been established and the numerical values of relative parameters have been presented. The average percentage deviations
of T
m
, T
b
estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability
to predict the above properties, compared to conventional group methods. 相似文献
34.
Shi-Woo Rhee 《Korean Journal of Chemical Engineering》1995,12(1):1-11
Aluminum has been used widely as a conducting material in the fabrication of integrated circuits, and chemical vapor deposition
process for Al has been actively investigated for the application in ultra large scale integration. In this review, various
precursors, mainly alkyl aluminum and alane compounds, and reaction mechanisms of these precursors in Al CVI) are described.
Epitaxial growth and selectivity of the deposition are also discussed. In addition to thermal reactions, plasma and photochemical
reactions are also briefly described. 相似文献
35.
H. Vestweber J. Oberski A. Greiner W. Heitz R. F. Mahrt H. Bssler 《Advanced functional materials》1993,2(4):197-204
The electroluminescent behaviour of films of poly(phenylphenylenevinylene) (PPPV), of PPPV blended with polystyrene (PS) and of PS doped with oligo(phenylenevinylene) sandwiched between indium–tin oxide (ITO) and Al contacts has been investigated. Polymer blending increases the relative quantum efficiency by up to two orders of magnitude. Studying the cell performance under application of rectangular voltage pulses as a function of temperature indicates that (i) hole injection at the ITO contact occurs by tunnelling, (ii) tunnel injection of electrons at the cathode is promoted by a space charge field across an interfacial Al2O3 layers and (iii) leakage of holes through the cathodic barrier is the main loss mechanism for holes. 相似文献
36.
The electrochemical properties of an electrochemical double-layer capacitor electrode based on an ultra-long (500 μm), aligned, carbon nanotube array (ACNTA) in Et4NPF6/propylene carbonate electrolyte are examined. The specific capacitance of the ACNTA electrode in an organic electrolyte is 24.5 F g−1, which is larger than that obtained in an aqueous electrolyte. The results of ac impedance measurements show that the ACNTA electrode gives a high power density and an excellent rate capability in an organic electrolyte. It is shown that the ACNTA electrode has a lower equivalent series resistance and a better rate capability than activated carbon electrode. This is due to the fact that ACNTA possesses a larger pore size and a more a regular pore structure. Both these features are conformed by scanning electron microscopic and nitrogen gas adsorption studies. 相似文献
37.
采用Bowman和Cole提出的有机磷分级体系,分3个灌水量对外源活性有机磷β-甘油磷酸钠在黄棕壤中的淋溶和转化特征进行了研究。结果表明,大于50mm的灌水量可以使β-甘油磷酸钠发生淋溶。施入黄棕壤中的β-甘油磷酸钠在24h内可以转化为速效磷和中活性有机磷,灌水量愈大,速效磷和中活性有机磷积累的土层也愈深。中稳性有机磷和高稳性有机磷含量没有明显变化。 相似文献
38.
P. Lutsyk J. Misiewicz A. Podhorodecki Ya. Vertsimakha 《Solar Energy Materials & Solar Cells》2007,91(1):47-53
The optical and photovoltaic properties of dichlorotin phthalocyanine (SnCl2Pc) films and SnCl2Pc/pentacene (Pn) heterostructures (HS) have been studied. Weak bands at 1.35, 1.52 and 2.05 eV have been found in absorption and modulated photoreflectance spectra of SnCl2Pc films. These bands can be caused by the formation of charge transfer states. The low concentration of recombination centers of charge carriers has been formed on a free surface of SnCl2Pc films. This concentration essentially decreases at air evacuation before vacuum deposition of a Pn layer. Therefore, interface with an insignificant recombination rate of charge carriers is formed for SnCl2Pc/Pn HS. 相似文献
39.
有机薄膜电致发光现象及其广阔的应用前景,激发了人们的研究兴趣。本文介绍了器件结构的研究现状。 相似文献
40.
W. Fischer 《Progress in Organic Coatings》1993,22(1-4):181-193
Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests. 相似文献