AlxZn1-xO合金MSM光电探测器的研究

在Si衬底上磁控溅射制备AlxZn1-xO(AZO)合金薄膜,在其上真空蒸发Ni/Au叉指电极获得金属-半导体-金属(MSM)结构光电探测器.采用UV-Vis-Nir分光光度计测量AZO系列薄膜的光吸收特性,观察到AZO 合金薄膜的光学吸收带边随Al含量增加明显蓝移.测试AZO探测器的电流电压特性、时间特性和响应光谱发...     

Creep phenomena in lead-free solders

A critical review of data on microstructure and creep process activation energy values for a number of lead-free solder alloys like Sn-Ag; Sn-Bi; Sn-In was conducted. The review revealed a scatter in experimental data, which could not be explained by the dislocation creep mechanism only, even after the published data was corrected for Young’s modulus temperature dependence. An analysis of the data implies that possible origin of such a scatter is nucleation, accumulation and further growth of such internal defects as pores and microcracks during creep. It is shown that these processes may affect the measured steady-state creep rates, and may be one of the major reasons for the observed scatter in experimental data, and, therefore, must be taken into consideration in lead-free solder alloys’ creep studies.     

Single‐Phase Filamentary Cellular Breakdown Via Laser‐Induced Solute Segregation

Nanosecond melting and quenching of materials offers a pathway to novel structures with unusual properties. Impurity‐rich silicon processed using nanosecond‐pulsed‐laser‐melting is known to produce nanoscale features in a process referred to as “cellular breakdown” due to destabilization of the planar liquid/solid interface. Here, atom probe tomography combined with electron microscopy is applied to show that the morphology of cellular breakdown in these materials is significantly more complex than previously documented. Breakdown into a complex, branching filamentary structure topped by a few nm of a cell‐like layer is observed. Single‐phase diamond cubic silicon highly supersaturated with at least 10% atomic Co and no detectable silicides is reported within these filaments. In addition, the unprecedented spatio‐chemical accuracy of the atom probe allows to investigate nanosecond formation dynamics of this complex material. Previously reported properties of these materials can now be reconsidered in light of their true composition, and this class of inhomogeneous metastable alloys in silicon can be explored with confidence.     

H2 In Situ Inducing Strategy on Pt Surface Segregation Over Low Pt Doped PtNi5 Nanoalloy with Superhigh Alkaline HER Activity

Surface segregation constitutes an efficient approach to enhance the alkaline hydrogen evolution reaction (HER) activity of bimetallic Pt_xNi_y nanoalloys. Herein, a new strategy is proposed by utilizing the small gas molecule of H₂ as the structure directing agent (SDA) to in situ induce Pt surface segregations over a series of PtNi₅-n samples with extremely low Pt doping (Pt/Ni = 0.2). Impressively, the sample of PtNi₅-0.3 synthesized under 0.3 MPa H₂ delivers an extremely low overpotential of 26.8 mV (−10 mA cm⁻²) and Tafel slope of 19.2 mV dec⁻¹, which is superior to most of the previously reported Pt_xNi_y electrocatalysts. This is substantially related to the strong H₂ in situ inducing effect to generate Pt-rich@Ni-rich core-shell nanostructure of PtNi₅-0.3 with an ultrahigh Pt surface content of 46%. The specific mechanistic effects of H₂ during the PtNi₅-n synthesis process are well illustrated based on the combined experimental and theoretical studies. The density functional theory mechanism simulations further unravel that the evolved active site of PtNi₅-n can efficiently reduce the reaction Gibbs free energies; especially for the scenario of PtNi₅-0.3, the downward-shifted d band center of the Pt active site significantly reduces the Pt H bond strength, eventually resulting in the lowest absolute value of ΔG_H.     

Nanoporous PtRu Alloy Enhanced Nonenzymatic Immunosensor for Ultrasensitive Detection of Microcystin‐LR

A novel nonenzymatic immunosensor for sensitive detection of Microcystin‐LR (MC‐LR) is constructed using a graphene platform combined with mesoporous PtRu alloy as a label for signal amplification. Primary antibody‐Microcystin‐LR (Ab₁) is immobilized onto the surface of a graphene sheet (GS) through an amidation reaction between the carboxylic acid groups attached to the GS and the available amine groups of Ab₁. Mesoporous PtRu alloy, prepared by corrosion PtRuAl alloys, is employed as a label to immobilize secondary antibody (Ab₂). The resulting nanoparticles, PtRu‐Ab₂, are used as labels for the immunosensor to detect MC‐LR. Under optimal conditions, the immunosensor exhibits a wide linear response to MC‐LR that ranges from 0.01 to 28 ng·mL^?1, with a low detection limit of 9.63 pg·mL^?1 MC‐LR. The proposed immunsensor shows good reproducibility, selectivity, and stability. The assayed results of polluted water with the sandwich‐type sensor are acceptable. Importantly, this methodology may provide a promising ultrasensitive assay strategy for other environmental pollutants.     

Cobalt Assisted Synthesis of IrCu Hollow Octahedral Nanocages as Highly Active Electrocatalysts toward Oxygen Evolution Reaction

Development of oxygen evolution reaction (OER) catalysts with reduced precious metal content while enhancing catalytic performance has been of pivotal importance in cost‐effective design of acid polymer electrolyte membrane water electrolyzers. Hollow multimetallic nanostructures with well‐defined facets are ideally suited for saving the usage of expensive precious metals as well as boosting catalytic performances; however, Ir‐based hollow nanocatalysts have rarely been reported. Here, a very simple synthetic scheme is reported for the preparation of hollow octahedral nanocages of Co‐doped IrCu alloy with readily tunable morphology and size. The Co‐doped IrCu octahedral nanocages show excellent electrocatalytic activity and long‐term durability for OER in acidic media. Notably, their OER activity represents one of the best performances among Ir‐based acidic OER catalysts.     

AZ31B镁合金/不锈钢异种合金双光束激光熔钎焊接特性

以镁基焊丝为填充材料,采用双光束激光熔钎焊的方法对AZ31B镁合金/不锈钢的焊接特性进行了研究。分析了不同工艺参数对焊缝成形、接头力学性能和断裂行为的影响。结果表明,采用双光束进行填丝熔钎焊能够获得较满意的外观成形,无明显缺陷,焊接工艺范围较宽。接头拉伸均断裂于熔化焊的镁侧焊缝及热影响区(HAZ),最大剪切强度为193 MPa,达到镁合金母材强度的71%。组织分析发现焊缝和HAZ的晶粒粗大,成为接头的薄弱部位,是接头失效的主要原因。钎焊侧界面发生了冶金反应,界面处生成1~2 μm的反应层。     

激光熔覆Co基合金温度场的数值模拟

为了分析Co合金熔覆的温度场,采用有限元法建立了低碳钢表面上激光熔覆预置钴基合金粉末过程的3维模型,考虑温度变化对热物理参量的影响以及表面对流换热和辐射散热等影响因素,使用SYSWELD软件对激光熔覆过程中的温度场进行了分析,并进行了验证。结果表明,激光熔覆过程中的温度场变化是由非稳态到稳态的过程,光斑附近等温面较为密集,远离光斑处等温面较稀疏;在其它工艺参量不变的情况下,扫描速率为5mm/s时熔覆过程的稀释率为8.26%,可以获得良好的冶金结合;利用SYSWELD软件的校核功能,获得了扫描速率为3mm/s和4mm/s时熔覆过程中较为合适的功率分别为1.6kW和1.87kW。研究结果对工艺参量的优化和控制熔覆层稀释率提供了借鉴和指导作用。     

激光熔覆镍基和钴基自熔合金的研究

本文采用镍基、钴基自熔合金通过激光熔覆获得性能优良的合金覆层,改善了叶片的耐磨性、耐蚀性,达到了提高使用寿命达10倍以上的目的。