肝癌碘油栓塞后肝区平片所见碘油沉积量与疗效关系

本文分析了90例肝癌肝动脉灌注化疗碘油栓塞后,肝区平片所见碘油沉积量和疗效的关系。碘油沉积分为多,中,少三组,从ATP下降,肿瘤缩小率及一年生存率三方面比较。结果沉积多的与中等组三项都有显著差别;沉积中等的与少的组差别不明显。说明碘油沉积要达到一定的量后,疗效才会显著提高。同时分析了影响碘油沉积的几个因素。     

ATM网络的可用比特率业务

本文介绍了可用比特率业务的业务特点，速率控制机制以及该业务存在的问题。     

Reactivity of steam in exhaust gas catalysis III. Steam and oxygen/steam conversions of propane on a Pd/Al2O3 catalyst

A 1% Pd catalyst (38% dispersion) was prepared by impregnating a γ-alumina with palladium acetylacetonate dissolved in acetone. The behaviour of this catalyst in oxidation and steam reforming (SR) of propane was investigated. Temperature-programmed reactions of C₃H₈ with O₂ or with O₂ + H₂O were carried out with different stoichiometric ratios S(S =[O₂]/5[C₃H₈]). The conversion profiles of C₃H₈ for the reaction carried out in substoichiometry of O₂ (S < 1) showed two discrete domains of conversion: oxidation at temperatures below 350°C and SR at temperatures above 350°C. The presence of steam in the inlet gases is not necessary for SR to occur: there is sufficient water produced in the oxidation to form H₂ and carbon oxides by this reaction. Contrary to what was observed with Pt, an apparent deactivation between 310 and 385°C could be observed with Pd in oxidation. This is due to a reduction of PdO_x into Pd⁰, which is much less active than the oxide in propane oxidation. Steam added to the reactants inhibits oxidation while it prevents the reduction of PdO_x into Pd⁰. Compared to Pt and to Rh, Pd has a higher thermal resistance: no deactivation occurred after treatment up to 700°C and limited deactivation after treatment up to 900°C, provided that the catalyst is maintained in an oxygen-rich atmosphere during the cooling.     

Catalytic oxidation of sulphide ions to elementary sulphur in aqueous solutions over transition metal oxides

The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice.     

添加剂对尖晶石型锰酸锂性质表征的影响

以LiOH·H_20和MnO_2为原料,分别掺入H_2BO_3、Al_2O_3、SiO_2和P_2O_5等添加剂,用固相分段法制备尖晶石型锰酸锂。结果表明,SiO_2和P_2O_5可以有效地改善LiMn_2O_4的电化学性能,H_3BO_3对锰酸锂的电化学性能影响不大,而Al_2O_3破坏了LiMn_2O_4的电化学性能。面扫描结果显示,Si或P元素各自都均匀地分散于LiMn_2O_4的物相中。从元素电负性和原子半径的角度分析了B、Si、P和Al元素对尖晶石型LiMn_2O_4结构和性能的影响。     

An eight‐node hybrid‐stress solid‐shell element for geometric non‐linear analysis of elastic shells

This paper presents eight‐node solid‐shell elements for geometric non‐linear analysis of elastic shells. To subdue shear, trapezoidal and thickness locking, the assumed natural strain method and an ad hoc modified generalized laminate stiffness matrix are employed. A selectively reduced integrated element is formulated with its membrane and bending shear strain components taken to be constant and equal to the ones evaluated at the element centroid. With the generalized stresses arising from the modified generalized laminate stiffness matrix assumed to be independent from the ones obtained from the displacement, an extended Hellinger–Reissner functional can be derived. By choosing the assumed generalized stresses similar to the assumed stresses of a previous solid element, a hybrid‐stress solid‐shell element is formulated. Commonly employed geometric non‐linear homogeneous and laminated shell problems are attempted and our results are close to those of other state‐of‐the‐art elements. Moreover, the hybrid‐stress element converges more readily than the selectively reduced integrated element in all benchmark problems. Copyright © 2002 John Wiley & Sons, Ltd.     

Sensitizing Mechanism and Adsorption Properties of Dye—Sensitized TiO2 Thin Films

The dye-sensitized TiO2 complex films were prepared by the dye coat onto TiO2 surfaces,and the sensitizing mechanism and adsorption properties of the dye-sensitized TiO2 complex films were inverstigated.The influence of the application conditions of dye adsorbed on TiO2 films on the amount of dye adsorption was discussed.Experimental results show that the concentration,the temperature of dye solutions and the dipping time of TiO2 films in the dye solutions have a significant influence on the amount of dye adsorption.Cell test indicates that the conversion efficiency of light to electricity increases with the amount of dye adsorption.     

河口水流、波浪、潮流、泥沙、河床变形二维数学模型

根据河口“波浪掀沙，潮流输沙”的泥沙运动机制，引入“波浪幅射应力”反应波浪对水体和泥沙的驱动力．考虑波浪对底部泥沙作用力、波浪对水流挟沙能力的影响及风场对水流和泥沙运动的影响．同时考虑泥沙粒径大小、水体含盐度、含沙量及水流紊动程度等因素对絮凝沉速的影响．用ＡＤＩ算法求解沿水深平均方程，破开算子法解悬移质不平衡输沙方程及河床变形方程，引入通度概念处理岸滩不规则边界，建立河口水流、波浪、潮流、泥沙、河床变形二维数学模型．通过实测资料及卫星摇感图像对所建数学模型进行检验，表明它可以较好地预测河口泥沙的运动     

高温润滑涂层设计的系统考虑

航天、航空、核能等尖端技术迫切要求使用耐高温润滑涂层，以保护金属构件的表面，增加发动机、推进器的工作效率和输出功率，８０年代国际摩擦学界根据工业和国防的需要将高温润滑涂层和耐磨材料定为摩擦学学科发展的重要研究方向之一。本文对高温润滑涂层设计中遇到的典型环境、涉及到的关键问题、未来发展的途径等问题作了阐述。     

原料扩重的中压加氢改质装置投产

介绍燕山石化公司为扩大1Mt／a中压加氢改质装置的原料来源，改用大庆减二线油和重油催化裂化柴油组成的混合料开工投产的经验以及装置初期的运行条件。中压加氢改质技术可以生产优质柴油和蒸汽裂解制乙烯的原料，还可增产喷气燃料。