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21.
Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations 总被引:2,自引:0,他引:2
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases. 相似文献
22.
提出一种配电网电容电流测量的新方法,在零序电压互感器的开口三角侧串联一个可调电感,通过注入一个变频恒流信号寻找配电网的谐振频率,改变可调电感的数值后寻找另一谐振频率,联立2个谐振方程求解电容电流,该方法消除了电压互感器漏抗对测量的影响。开发了配电网电容电流测量仪,经模拟试验和现场测试表明,该方法具有安全、快捷、准确等特点,适用于中性点不接地或经随调式消弧线圈接地配电网。 相似文献
23.
Dong Zhang 《Korean Journal of Chemical Engineering》2008,25(5):1205-1207
Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release
and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce3+ and Ce4+. Several methods have recently been described to prepare the CeO2-ZrO2 solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO2-ZrO2 solid particles. The Ce-Zr alcogel is dried and calcined in flowing N2 not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high
surface area over 90 m2g−1, which drops to 40 m2g−1 following treatment at 900°C. 相似文献
24.
M. Jayasankar 《Materials Letters》2007,61(3):790-793
Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm. 相似文献
25.
向浩萍 《石油化工管理干部学院学报》2003,(2):26-29
在明确中国石化集团公司收入分配制度改革的目标模式下,从健全和完善企业激励机制的角度,对炼化企业职工收入分配制度中工资和奖金的分配设计提出改进措施和建议。 相似文献
26.
R. Boroch J. Wiaranowski R. Mueller-Fiedler M. Ebert J. Bagdahn 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(1):2-12
The aim of this work is to characterize the strength properties of polycrystalline silicon (polysilicon) with the use of tensile and bending test specimens. The strength of thin polysilicon films with different geometry, size and stress concentrations has been measured and correlated with the effective size of the specimen and its stress distribution. The test results are evaluated using a probabilistic strength approach based on the weakest link theory with the use of STAU software. The use of statistic methods of strength prediction of polysilicon test structures with a complex geometry and loading based on test values for standard material tests specimen has been evaluated. 相似文献
27.
官泓 《有色冶金设计与研究》2003,24(3):49-51
阐述水厂设计中对水厂规模、水源地、净水厂位置及净水工艺的确定过程,根据原水的特点,通过分析对无阀滤池进行改良。 相似文献
28.
We consider an integrated scheduling and distribution model in which jobs completed by two different machines must be bundled together for delivery. The objective is to minimize the sum of the delivery cost and customers' waiting costs. Such a model not only attempts to coordinate the job schedules on both machines, but also aims to coordinate the machine schedules with the delivery plan. Polynomial-time heuristics and approximation schemes are developed for the model with only direct shipments as well as the general model with milk-run deliveries. 相似文献
29.
Measurements of gel time of the epoxy system DGEBA(n=0)/m-XDA were carried out using rheometry and dielectric analysis with the objective of checking the validity of Mangion-Johari equation (DEA) and Harran-Laudouard criterium (rheometry) for gel time determination. In this work, gel times obtained by rheometry and dielectric analysis are compared and conversions at gel time calculated. From the experimental results obtained for gel times it was found a reasonable agreement between the two techniques that lead to gel conversion values very close to those obtained using Flory equation. 相似文献
30.