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21.
A simple transient performance of floating cum tilted-wick type solar still has been presented by incorporating the effects of water flowing over a glass cover, heat capacity of tilted-wick water surface and floating-wick water surface. Explicit expressions for flowing water, glass, tilted-wick water surface and floating-wick water surface temperature and efficiency of the system have been derived. Numerical calculations have been carried out for a typical day in the month of March 2004. The relative standard deviations between the numerical and experimental results of different temperature components of the proposed still have been found. The results indicate that the relative standard deviations between theoretical and experimental results are less than 8% (glass cover), 2% (tiltedwick water surface), 1% (floating-wick water surface) and 2% (flowing water at the lower end of the glass cover) an average for the working hours of the day. Moreover, based on the numerical results, the following conclusions have been drawn: (i) glass cover temperature decreases significantly; (ii) the effect of water flowing over the glass cover has a fascinating effect on the production of distillate output during peak sunny hours; (iii) water flow rate of 1.5 m/s is optimum, and beyond it the efficiency decreases. Experimental investigations have been performed at Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, India.  相似文献   
22.
The dynamics of the crystal size distribution in a continuous mixed suspension, mixed product removal crystallizer is modeled stochastically. The model is fairly general in that it involves a size-dependent growth rate function: this size-dependent growth rate as a possible cause of deviation on the behavior of the crystallizer from that of an idealized or simplified counterpart has been investigated based upon the model.  相似文献   
23.
In this work, we present the solution of the equations that govern the reactant transport in a well mixed system that contains particles where diffusion and first-order reaction occur. The transport equations are coupled by an interfacial boundary condition that includes mass transfer resistance. The statement of the problem allows arbitrary time depending feed functions. The evaluation of the solution obtained by the Laplace method requires the solution of an eigenvalue problem. We discuss the evaluation of the solution, and typical results for three different feed functions: step, pulse and oscillatory functions are presented. The resulting equations are able to show the effect of internal and external mass transfer limitations on the particle and fluid concentrations and on kinetic experimental results.  相似文献   
24.
A detailed transport model for the Multitrack setup, a TAP-like system, has been developed, which allows further analysis of adsorption, diffusion and catalysis phenomena. This includes the transport in the void part between the pulse valve and the reactor inlet. The effects of viscous flow and thermal transpiration, aspects that have not been studied in detail before for this type of setup, have been analyzed. A new expression for the modeling of the output signal is proposed depending on the positioning of the MS detector used in the study. The transport parameters of the model have been estimated by the analysis of the experimental pulse responses of the empty reactor system and the reactor charged with an inert packed bed. The proposed model reproduces the experimental pulse responses very well, and therefore can be extended to study systems with reacting or adsorbing beds by including the corresponding rate equations for the processes occurring in the bed of particles.  相似文献   
25.
V.A. Kondratenko  M. Baerns   《Catalysis Today》2007,121(3-4):210-216
An effect of oxygen species formed from O2, N2O and NO on the selectivity of the catalytic oxidation of ammonia was studied over a polycrystalline Pt catalyst using the temporal analysis of products (TAP) reactor. The transient experiments were performed in the temperature range between 773 and 1073 K in a sequential pulse mode with a time interval of 0.2 s between the pulses of the oxidant (O2, N2O and NO) and NH3. In contrast to adsorbed oxygen species formed from NO, those from O2 and N2O reacted with ammonia yielding NO. It is suggested that the difference between these oxidising agents may be related to the different active sites for dissociation of O2, N2O and NO, where oxygen species of various Pt-O strength are formed. Weaker bound oxygen species, which are active for NO formation, originate from O2 and N2O rather than from NO. These species may be of bi-atomic nature.  相似文献   
26.
A mathematical model has been developed for the simulation of the ammonia oxidation in a reverse flow reactor. Computer simulations were carried out with a kinetic scheme, based upon elementary reaction steps. Aim was to explore the potential of a reverse flow reactor for selective oxidation of NH3 to produce either N2, NO, or N2O via a dedicated operation procedure. Therefore, the conversion of NH3 and the selectivity toward N2, NO, or N2O, were compared for a reverse flow operation and a steady state, once-through operation.A new operation concept of reverse flow operation in combination with a periodically lower feed concentration is proposed. The novel reactor concept shows a better performance compared to normal reverse flow operation and to steady state, once-through operation. The results indicate that reverse flow operation can be applied for manipulation of conversion and selectivity. A periodically lower feed concentration may increase the conversion, even up to levels that exceed the steady state value.  相似文献   
27.
This paper reports an experimental study of both the transient and steady-state heat transfer behaviour of a gas flowing through a packed bed under the constant wall temperature conditions. Effective thermal conductivities and convective heat transfer coefficient are derived based on the steady-state measurements and the two-dimensional axial dispersion plug flow (2DADPF) model. The results reveal a large temperature drop at the wall region and the temperature drop depends on the axial distance from the inlet. The 2DADPF model predicts the axial temperature distribution fairly well, but the prediction is poor for the radial temperature distribution. Length-dependent behaviour of the effective heat transfer parameters and non-uniform flow behaviour are proposed to be responsible. A comparison with previously published correlations and data in the literature shows that the relationships proposed by Bunnell et al. and Demirel et al. agree well with the measured effective radial thermal conductivity, whereas the wall-fluid heat transfer coefficient is better represented by the Li-Finlayson correlation.  相似文献   
28.
In recent years, although an increasing number of literature have been devoted to circulating fluidized bed (CFB), the prediction of velocities over which different fluidization regimes exist is still difficult. In this study, a transient method was applied which readily allows one to identify operational features and critical transitions. The method is based on stopping the solids flow rate into the riser when riser is operating in fully dense transport regime. The analysis of transient pressure drop data across the riser during a solids flow cut-off experiment against its time derivative demonstrate the three distinct operating regimes that exist as the gas deplete the solid out of the riser. The transient was compared to data taken under steady state operations using statistically designed experiments. Results indicated that although there were significant differences when comparing operations in dilute conditions, there were no significant differences between the two methods in the fast fluidized and dense transport regimes. The transient method was capable of reproducing the solids circulation dependence on riser solids holdup and on the axial pressure profile. This transient method offers an accurate, easy, rapid, and reproducible means of characterizing CFB operations over a wide range of flow conditions. The lack of accuracy in the dilute regime is conjectured to be due to the wide particle size distribution that resulted in segregation during the transient testing.  相似文献   
29.
This study was aimed at investigating the effect of particle size, mostly in the submicron range, on break-through stage of filtration. Latex beads, with diameters ranging from 0.46- to 2.967-μm were filtered through filter grains of diameters 0.1-, 0.175- and 0.45-mm. Experimental conditions were chosen so as to obtain breakthrough curves. The experimental results showed that the initial efficiency follows the pattern reported by previous experimental and theoretical studies, i.e., lower efficiency for 0.825-μm particles which fall in the range of critical size. However, the particle removal during the transient stage increased with an increase in particle size for the range of sizes studied. This pattern is qualitatively confirmed by the theoretical predictions of Vigneswaran and Chang (1986) model. This study also provides experimental verification of the effect of the ratio of particle size and grain size at different stages of filtration.  相似文献   
30.
摘要 以电容电压作为输出反馈的Boost变换器是一个非最小相位系统,非最小相位反应引起的负调严重的影响系统的暂态性能及稳态性能。研究引起负调与变换器参数之间的关系对Boost变换器优化设计是一个关键问题。本文根据Boost变换器小信号数学模型推导给出非最小相位系统的负调电压表达式,指出衡量负调电压的两个指标:负调电压大小和负调电压峰值时间。根据负调电压表达式分析了输入电压、储能电感、占空比、占空比变化量、负载、滤波电容等参数对负调电压的影响。研究结果表明:输入电压和占空比变化量仅影响负调电压大小;储能电感、占空比、负载、滤波电容不仅影响负调的大小,同时影响负调的峰值时间。研究所得结论为Boost变换器的参数优化设计以及减小负调电压提高系统暂态性能及稳态性能提供了理论依据。仿真和实验结果验证了理论分析的正确性。  相似文献   
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