改进工艺操作方法 降低脱硅锆能耗

从分析脱硅的条件出发,引导出新的工艺操作方法、工艺参数和加料方法。用一年的生产实践说明该新工艺操作方法的技术经济效益。     

某厂锆（Zr）生产流程中不同产物的天然放射性核素含量测定

本文报道了某厂锆(Zr)生产流程中原料(锆英砂,主要成份为 ZrSiO_4)、半成品(ZrC,ZrCl_4)、废渣和成品锆中天然放射性核素~(238)U、~(226)Ra、~(232)Th 和~(40)K 含量测定结果。采用 NaI(Tl)γ能谱法进行测定,结果表明,原料、半成品和废渣中都含有一定的放射性,各生产环节应采取适当的防护措施;成品锆中基本不含放射性,可安全地应用于各个生产和生活领域。     

The magnetic applications choice among ferrite ceramics,metallic strips,or metal powder cores

Iron-based metallic strip materials such as iron, silicon-iron, and amorphous metal are used for low frequency (50–60 Hz. line) power applications. Low-loss Nickel-based alloys as high permeability strip or insulated powder cores are the choices for stable, low-level higher frequency applications. Iron-based powder cores offer low cost as power supply filter chokes. Ceramic ferrites combine highest frequency operation with low cost and reduced component size as transformers and chokes in telecommunication and high frequency power supply applications.     

Corrosion of metals and alloys in mixed gas environments at elevated temperatures

The attack of nickel, cobalt, iron, and alloys of these metals containing chromium and aluminum, by gases containing sulfur-oxygen, carbon-oxygen, and nitrogen-oxygen has been studied at temperatures of 600 and 900°C. The degradation of these metals and alloys was characterized by using standard analytical techniques with emphasis on optical metallography. Three types of accelerated degradation were identified for the attack of alloys by gases containing another oxidant in addition to oxygen. One type of degradation occurred because of the formation of reaction products composed of mixtures of phases involving both of the oxidants. Another type resulted from the reaction of second oxidant phases with oxygen. The third form of degradation involved the development of less protective phases due to thermodynamic instabilities. Thermodynamic stability diagrams are used to help account for the effects produced by different elements in the alloys.     

High cycle fatigue behaviour of Ti–6Al–4V alloy at elevated temperatures

High cycle fatigue behaviour of Ti–6Al–4V alloy was studied at 623 K and 723 K. Fatigue strength decreased at elevated temperatures compared with at ambient temperature. In the short life regime, fatigue strength was lower at 723 K than at 623 K, but in the long life regime it was nearly the same at both temperatures. At elevated temperatures, cracks were generated earlier at applied stresses below the fatigue limit at ambient temperature, indicating lowered crack initiation resistance. Small cracks grew faster at elevated temperatures than at ambient temperature, which became more noticeable with increasing temperature. After allowing for the elastic modulus, small cracks still grew faster at elevated temperatures.     

Processing study of a high temperature adhesive

An adhesive-bonding process cycle study was performed for a polyimidesulphone. The high molecular weight, linear aromatic system possesses properties which make it attractive as a processable, low-cost material for elevated temperature applications. The results of a study to better understand the parameters that affect the adhesive properties of the polymer for titanium alloy adherends are presented. These include the tape preparation, the use of a primer and press and simulated autoclave processing conditions. The polymer was characterized using Fourier transform infrared spectroscopy, glass transition temperature determination, flow measurements, and weight loss measurements. The lap shear strength of the adhesive was used to evaluate the effects of the bonding process variations.     

Structure and properties of polyimide‐bonded magnets processed from prepolymers based on diacetyl derivatives of aromatic diamines and dianhydrides

We report a novel method of polyimide (PI) synthesis from prepolymers based on dianhydrides and diacetyl derivatives of aromatic diamines that facilitate the preparation of a melt processable mixture at 300 ± 10°C of the prepolymer and magnetic Nd‐Fe‐B alloy to provide PI‐bonded magnets with enhanced properties. It is shown that chemical structure of the prepolymers strongly influences viscosity behavior via crystallization of the oligoimide in the melt, leading to formation of PI with rigid‐rod like structure. This structural ordering of the prepolymers based on diacetyl derivative of diamine used in this study, if not controlled, leads to exponential increase of melt viscosity with time, making it practically impossible to prepare melt processable mixture of the magnetic particles and the PI prepolymers at elevated temperatures. The results obtained demonstrate that appropriate dianhydrides and diacetyl derivatives of diamines that do not lead to crystallization of oligoimides in prepolymer mixture can be used under controlled processing conditions to prepare melt‐processable PI‐bonded magnets containing rigid‐rod like PI structure that significantly increases thermal stability of the magnets. The temperature dependencies of the magnetic properties of the PI‐bonded magnets under conditions that they are likely to encounter during their service life were found to be remarkably similar to that of commercial thermoplastic magnets such as injection‐molded nylon magnets. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 478–485, 2006     

红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.     

Evolution of insoluble eutectic Si particles in anodic oxidation films during adipic-sulfuric acid anodizing processes of ZL114A aluminum alloys

The effects of insoluble eutectic Si particles on the growth of anodic oxide films on ZL114A aluminum alloy substrates were in-vestigated by optical microscopy (OM) and scanning electron microscopy (SE...