三氯乙烯与糠醛水溶液的液液平衡及萃取模拟计算

本文采用液液平衡釜了糠醛水溶液与三氯乙烯的液液平衡数据，用ＵＮＩＱＵＡＣ方程关联糠醛－水－三氯乙烯体系的液液平衡数据，以ＵＮＩＱＵＡＣ方程的模型，采用液液萃取法模拟计算糖醛和水的分离结果。     

Microscopic fatigue processes in a plain-weave glass-fibre composite

This paper focuses on the microscopic damage and progressive failure of a composite reinforced by plain-weave glass cloth under tensile fatigue loading. The fatigue process was divided into three stages like that of multi-directional laminates. It was found that the internal damage at each stage (matrix cracks, debonds in the weft, successive debonds in the warp and ‘metadelaminations’ between warps and wefts) occurred near the cross-over point of the fabric. The modulus decay mechanism was explained by considering the progression of this internal damage. From the end of the first stage to the beginning of the middle stage, a characteristic damage state (CDS) (called a ‘meta-CDS’) was observed. It was found that woven composites have a unit area of damage accumulation (called a ‘unit cell’) and the damage of each unit cell and its distribution control the total fatigue damage of the material.     

Knowledge extraction for production management

A procedure and underlying algorithm for extracting knowledge from production and inventory databases to support engineering management activities is described. The process searches for, detects and isolates behaviour patterns inherent in the data. It relates these patterns to production irregularities, suggests connections with specific causes and helps propose possible corrective or preventive actions. The approach is based on a four-phase procedure: (1) the decision-maker focuses on the subject or difficulty at issue, represented by a target concept; (2) the KEDB algorithm, based on a machine learning approach, processes the relevant database and provides knowledge characterizing and classifying the target concept; (3) the output is interpreted in Pareto fashion as a series of possible circumstances explaining the target concept behaviour; and (4) based on these causes, the decision-maker decides on possible corrective actions to improve the situation, or preventive actions to forestall unfavourable conditions. A case study based on an actual quality control database is detailed.     

二(二甲苯基)丙烷合成工艺的研究

二氯丙烷(DCP)与二甲苯在混合金属氯化物催化剂(HD90)作用下合成二(二甲苯基)丙烷,生产过程简单,产品收率高。在60—80℃的温度下,二甲苯与二氯丙烷摩尔比为6∶1,HD用量50克/摩尔DCP的条件下反应5—6小时,二(二甲苯基)丙烷的收率可达88％以上。     

Physicochemical characteristics and leachability of scale and sludge from Bulalo geothermal system, Philippines

Scale and sludge from Bulalo geothermal field, Philippines, have been characterized by whole rock analysis, radioactivity counting, size analysis, light microscopy, scanning electron microscopy, and X-ray diffraction. Their leachability was assessed by regulatory leaching procedures and by sequential extraction. Both scale and sludge consisted mostly of oxides of Si, Al, and Fe with no radionuclides detected. The scale had 10% S content. Sulfides and silicates were important phases in both samples having size ranges from submicron to 2 mm. Geothermal soils at Bulalo have higher than normal soil levels of As, S, Cu, Cr, Zn, and Pb but regulatory leaching tests indicated that these elements are not released. However, the sequential extraction showed that As, Cu, and Zn were leachable under extreme conditions.     

沈阳太平洋广场空调冷热源方案比较

对一幢１１．５万ｍ＾２的四星级综合建筑的空调冷热源不同的蓄冷和取冷比较了四种方案，论证了其中直燃型溴化锂吸收式冷热水机组供冷供暖、小型燃油锅炉供蒸汽的方案最为合理。     

三维定量储层地质模型与参数动态预测方法

提出了三维定量储层地质模型及其参数动态预测方法，用该方法可预测储层开采状态，水淹区及剩余油区分布和各剩余油区的可采储量，三维定量储层地质模型的预测图件可为合理开采提供依据。     

脱苯工艺的节能改造

焦化厂富油脱苯工艺中，管式炉法较蒸汽法节能。本溪钢铁公司焦化厂产焦１８０万ｔ／ａ的装置，其富油脱苯工艺由蒸汽法改为管式炉法后，每年可节煤７０００ｔ。     

Extraction of halide quaternary salts in an organic solvent/water system: Hydrodynamics and mass transfer

The hydrodynamic characteristics and mass transfers of halide quaternary salts between two immiscible phases in a stirred membrane permeation cell were investigated. The concentration of quaternary salt, temperature, solvent and the four kinds of halide quaternary salts were evaluated to achieve the extractive optimum condition. The diffusivity, overall mass‐transfer coefficients and individual mass‐transfer coefficients were determined and correlated in terms of the conventional Sh‐Re‐Sc relationship. The transfer time of quaternary salts across the membrane and the thickness of the hydrodynamic diffusion boundary layer were determined as well, so as to characterize the extractive phenomenon of quaternary salts between the two phases that is useful in phase‐transfer catalysis.     

Use of helical parameters to generate candidate conformations for crystal packing: illustrative application to a polyimide

This communication describes the application and extension of a method for calculating the helical parameters with which to describe molecular conformations. The method, which was originally developed by Shimanouchi and others, is applied to a polyimide of 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA) and 2,2-dimethyl-1,3-(4-aminophenoxy)propane (DMDA) which has eight torsional bonds in the chemical repeat unit. Discrete low energy states for these torsions were determined by Ramanchandran energy maps of sequential dihedral pairs or single bond torsional energy diagrams. The total number of possible low energy conformations for these states is 1152 including conformationally related isoenantiomorphs. The method conveniently generates the conformations for subsequent crystal structure packing and refinement. Consideration of these together with the X-ray data of Cheng and co-workers reduces the number to about 15 with about a 2/1 conformation and a c axis of approximately 49.2 Å. Of these, about half appear to be good candidates for crystal packing.