钛酸铝材料研究进展及应用

钛酸铝是一种优异的高熔点、低膨胀无机非金属材料。主要阐述了钛酸铝材料的微观结构，以及热分解、热膨胀及其影响因素。简述了钛酸铝材料的制备方法。讨论了合成的工艺条件及添加剂对钛酸铝材料性能的影响，并对其应用作了简单介绍。最后提出了改善钛酸铝材料性能的技术途径。     

THIRD-ORDER ASYMPTOTIC PROPERTIES OF ESTIMATORS IN GAUSSIAN ARMA PROCESSES WITH UNKNOWN MEAN

Abstract. This paper deals with the third-order asymptotic theory for Gaussian autoregressive moving-average (ARMA) processes with unknown mean μ. We are interested in the estimation of ρ = ( α₁…, α_p, β₁…, β_q ), where α ₁…, α_ρ and β ₁…, β_q are the coefficients of the autoregressive part and the moving-average part, respectively. First, we investigate the third-order asymptotic optimality of the bias adjusted maximum likelihood estimator (MLE) of ρ in the presence of the nuisance parameters μ and ² (innovation variance). Next, for a Gaussian AR(1μ μ, ²), we propose a mean corrected estimator α_c1c2 of the autoregressive coefficient. We make a comparison between the bias adjusted estimator α_c1c2* and the bias adjusted MLE, in terms of their probabilities of concentration around the true value, or equivalently, in terms of their mean squared errors. Finally some numerical studies are provided in order to verify the third-order asymptotic theory.     

Effect of MgO Addition on the Bondability and Interfacial Reaction between Dielectric and Glass-Ceramics for the Fabrication of Multi-Component Ceramic Substrates

Bondability and interfacial reaction between dielectric and insulator layers have been examined to obtain a basic understanding of bonding mechanisms. Lead-containing complex perovskite was used as a dielectric material. Two kinds of glass-ceramics were used as insulator material; lead borosilicate glass containing Al_2O3 (insulator A) and the same containing Al₂O₃ and M_gO (insulator B). Dielectric and insulator layers did not bond when insulator A was used. When insulator B was used, however, strong bonding was achieved between the two layers by firing the powder compacts at temperatures between 800° and 1000°C. Addition of M_gO to lead borosilicate glass increased the thermal expansion coefficient to that of the dielectric and enhanced the formation of reaction layers, resulting in good bonding. Two reaction layers were identified. The main reaction products were enstatite and bredigite for one layer contacting the dielectric, and enstatite and a compound with the same diffraction pattern as that of faujasite for the other layers contacting insulator B.     

倾斜下降管内油气水三相流流型转变的实验研究

对倾斜下降管倾角变化对油气水三相流流型转变的影响进行了研究 ,通过大量实验得到流型图 ,发现倾角对流型转变有重大影响 :倾角增大到 3 0°时 ,增大气流量 ,泡状流已不再转变为间歇流 ,而是分层流 ;倾角变化对环状流和间歇流之间的转变影响显著。得到的界限方程规律与实验现象及流型图符合良好     

Al2TiO5-ZrTiO4-ZrO2 Composites: A New Family of Low-Thermal-Expansion Ceramics

The characterization and properties of ceramic composites containing the phases Al₂TiO₅, ZrTiO₄, and ZrO₂ are described. The range of compositions investigated gives very low average thermal expansions (α_24–1000°C as low as −2.0 × 10⁻⁶°C⁻¹) and excellent high-temperature stability. The low thermal expansions are apparently due to a combination of microcracking by the titanate phases and a contractive phase transformation by the ZrO₂. The crystal chemistry and microstructure of the product are processing dependent. Although the composites represent a complex microcracking system, the low thermal expansions and high-temperature stability make them potential candidates for commercial applications requiring thermal shock resistance.     

基于高斯核的SVM的参数选择

基于高斯核的支持向量机应用很广泛,高斯核参数σ的选择对分类器性能影响很大,本文提出了从核函数性质和几何距离角度来选择参数σ,并且利用高斯函数的麦克劳林展开解决了参数σ的优化选择问题。实验结果表明,该方法能较快地确定核函数参数σ,且 SVM 分类效果较好,解决了高斯核参数σ在实际应用中不易确定的问题。     

400kt／a硫铁矿制酸装置挖潜扩能改造

介绍400 k t/a硫铁矿制酸装置的挖潜改造。通过调整工艺技术指标,增加少量设备和催化剂,将硫酸装置的生产能力从400 k t/a提高到450 k t/a,改造后各项技术经济指标均达到要求,2005年第1季度实现利润1 479万元,取得了明显的经济效益。     

Thermal Expansion of Solid Solutions in the ZrTiO4—In2O3—M2O5 (M = Sb, Ta) System

Axial and dilatometric thermal expansions and phase transformations were studied for solid solutions having the α-PbO₂ structure in the ZrTiO₄—In₂O₃—M₂O₅ (M = Sb, Ta) system with nominal formulas of Zr _x Ti _y In _z Sb _z O₄ and Zr _x Ti _y In _z Ta _z O₄ where x + y + 2 z = 2. With increased substitution of z , the cell volume increased, the difference in the b parameters at room temperature between those quenched from 1400° and 1000°C decreased, and the thermal expansion decreased. The axial thermal expansion of ZrTi _y In _z · Ta _z O₄ with z = 0.3 was almost identical with that of HfTiO₄, and those with z = 0.4 and z = 0.45 were smaller than that of HfTiO₄. Unit-cell volumes of these compound were compared with those of single oxides to make it clear that the unit-cell volume of ZrTiO₄ was small anomalously and to distinguish the normal and abnormal substitution systems. These results were explained by the working hypothesis proposed for these compounds.     

板壳式换热器设置膨胀节的判定

介绍板壳式换热器的主要特点和应用。当壳体与板束温差较大时,笔者通过对产品开发的生产实践,提出解决板壳式换热器要否设置膨胀节的类似判定方法。     

不同氧磷比对磷酸盐包边玻璃性质的影响规律

包边技术是提高大尺寸激光玻璃饱和增益系数的关键技术.采用传统的方法熔制玻璃,研究了P2O5含量对P2O5-Al2O3-B2O3-CuCl-Na2O-ZnO磷酸盐包边玻璃的折射率、热膨胀系数、玻璃转变温度、膨胀软化温度以及化学稳定性的影响.结果表明:当P2O5的摩尔分数为60%左右,玻璃样品具有最高的折射率(1.5220)、最低的玻璃转变温度(352.4℃)、较好的化学稳定性[0.52mg/(cm2·d)]和适宜的热膨胀系数(128.427×10-7/℃),是用作钕磷酸盐激光玻璃硬包边的理想材料.