煤中吡啶型氮热解机理的量子化学研究

用密度泛函 ( DFT)方法 ,在 UB3LYP/6- 31 G( d)水平上研究了煤中吡啶型氮的热解机理 ,对热解过程中由于官能团周围环境的不同而形成的三类吡啶自由基进行了量子化学计算 ,通过对键的 Mulliken布居数等计算结果的分析 ,分别得到了这三类自由基的热解途径 .并优化得到了反应物、中间体和产物的几何构型 .计算结果表明 ,吡啶型氮主要是以 HCN的形式释放出来的 .NH3 是 HCN二次反应的产物 .     

Rapid pyrolysis of brown coal and oil shale

A brown coal, peat and oil shale were subjected to a rapid pyrolysis process and medium-heat-value gases together with tar were collected. The char residue was of high activity and suitable for gasification to create a two-stage gasification system. The coal-tar is used for manufacturing liquid fuels and chemicals.     

Cinétique de dégagement des matières volatiles lors de la pyrolyse d'électrodes de carbone industrielles

In aluminium plants, the anode baking process is associated with an important release of volatile combustible matter. It is the purpose of this study to investigate the kinetics of the evolution of these volatiles. A large thermogravimetry set-up has been designed in such a way that it could simulate real plant conditions. Samples of two distinct masses have been subjected to pyrolysis at different heating regimes. The loss of weight together with the concentrations of the released gases were recorded on a continuous basis during the temperature rise. Kinetic results were found for methane, hydrogen and tar. No variation of the order of reaction with the heating rate was observed, whereas the activation energy and the pre-exponential factor increased. Furthermore, for the range of sample dimensions studied, it was found that the mass of the solid had no significant influence on the kinetic parameters.     

探究Flash CS6之“创建补间动画”

随着Flash软件版本的不断升级,传统的一些功能也有了颠覆性的改变。2013年底在建设课题《艺术设计网络辅助教学平台的开发研究》(项目编号12535201)过程中,为《Flash动画制作》网络课程录制微课视频时,比平时执教中更深切地体会到了这一点。其中感触最深的就是"动作补间动画"的全新突破。本文从老版本与新版本的使用对比,最终得出结论,是执教者的经验总结。     

基于iebook的电子书播放外部视频功能的实现

Exe类型电子书制作软件集成文字内容和小图片非常容易,效果也很不错,但是对集成高品质的音视频、数码照片等大容量数据文件却无能为力。通过对iebook超级精灵自带模板以及Exe电子书文件的深入分析,把flash技术、流媒体对象和file协议有机结合,实现动态加载指定相对路径下的外部视频文件到电子书中,大大提高了iebook超级精灵在处理多媒体方面的实用性。     

Organolithium route to poly(arylsilane)s

Various poly(arylsilane)s The poly(carbosilane)s prepared in this way are of higher molecular weight than when prepared by the Wurtz-type condensation route previously reported. TG shows 40–50% overll weight loss attained at 500–600°C.     

CO2 gasification of wood charcoals derived from vacuum and atmospheric pyrolysis

The gasification of biomass derived char obtained via vacuum and atmospheric pyrolysis of Populus tremuloides has been studied in the ranges of 725–960°C and 0.1 to 6 MPa. CO₂ was used as the oxidizing gas. The results show that char reactivity is influenced by the preheating rates and that pressure effects are significant between 850°C and 950°C. A correlation based on the expression: df/dt = k₀{exp(-E/RT)}(1 - f)^af^βP^yCO₂ was used to fit the experimental data. In general, vacuum pyrolysis derived char showed a higher reactivity than atmospheric pyrolysis chars. An explanation based on a higher oxygen content of the vacuum pyrolysis char is suggested.     

《Flash交互动画》实训教学实践

本文通过将三个较典型的Flash交互动画的程序案例作为《Flash交互动画》的实训教学案例,循序渐进由简到难,旨在让学生初步掌握通过AS 3.0的脚本语言编程实现用鼠标或键盘对动画播放的控制。     

流域水文模型在临界雨量分析中的应用研究

为提高无资料地区临界雨量分析结果的精确度,采用双曲正切产流模型和单位线流域汇流模型,结合山西省清凉寺沟流域水文下垫面产汇流模型参数,对实测暴雨洪水进行了模拟分析。结果表明:径流深及洪峰流量的合格率均为75%,参数是合理、可靠的,据此得出了该流域不同流量级时的临界雨量。     

大容量闪存的层次型热数据识别框架

热数据识别对于提高闪存垃圾回收的效率、延长闪存寿命都有重要的作用。针对大数据量下热数据识别难的情况,该文提出一种层次型热数据识别框架,采用在多个层次上记录热数据的方法。实验证明,该框架能够在消耗较少资源的情况下,识别和预测出大数据量中的热数据。