Various poly(arylsilane)s The poly(carbosilane)s prepared in this way are of higher molecular weight than when prepared by the Wurtz-type condensation route previously reported. TG shows 40–50% overll weight loss attained at 500–600°C. 相似文献
Two-dimensional plain-weave silicon carbide fiber fabric reinforced silicon carbide (2D-SiC/SiC) composites were molded by
stacking method and densified through precursor infiltration and pyrolysis (PIP) process. SiC coating was deposited as the
fiber/matrix interphase layer by chemical vapor deposition (CVD) technique. Fiber/matrix debonding and relatively long fiber
pullouts were observed on the fracture surfaces. Additionally, the flexural strength and elastic modulus of the composites
with and without fiber/matrix interphase layer were investigated using three-point bending test and single-edge notched beam
test. The results show that the fiber fraction and the porosity of 2D-SiC/SiC composites with and without coating are 27.2%
(volume fraction) and 11.1%, and 40.7% (volume fraction) and 7.5%, respectively. And the flexural strength and elastic modulus
of 2D-SiC/SiC composites with and without coating are 363.3 MPa and 127.8 GPa, and 180.2 MPa and 97.2 GPa, respectively. With
a proper thickness, the coating can effectively adjust the fiber/matrix interface, thus causing a dramatic increase in the
mechanical properties of the composites.
Foundation item: Project(NCET-07-0228) support by the New Century Excellent Talents in University 相似文献
The gasification of biomass derived char obtained via vacuum and atmospheric pyrolysis of Populus tremuloides has been studied in the ranges of 725–960°C and 0.1 to 6 MPa. CO2 was used as the oxidizing gas. The results show that char reactivity is influenced by the preheating rates and that pressure effects are significant between 850°C and 950°C. A correlation based on the expression: df/dt = k0{exp(-E/RT)}(1 - f)afβPyCO2 was used to fit the experimental data. In general, vacuum pyrolysis derived char showed a higher reactivity than atmospheric pyrolysis chars. An explanation based on a higher oxygen content of the vacuum pyrolysis char is suggested. 相似文献