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81.
碳酸锂溶解度在工业结晶生产中是十分重要的基础数据。采用浸入式红外探头和拉曼探头在线监测溶液体系中CO32-和碳酸锂的特征峰峰强的变化,依据Lambert-Beer定律得出溶液体系中实时在线测定碳酸锂的溶解度。通过在线测定,测得碳酸锂在氯化钠-氯化钾溶液(cNaCl=0.446 6 mol/L,cKCl=0.015 8 mol/L)中的溶解度高于在水中的溶解度值。实验测试出的水中碳酸锂的溶解度数据还能与Van′t Hoff方程较好地关联,进一步测算碳酸锂在其他温度下水中的溶解度值。此外,该方法测定的碳酸锂在水中的溶解度数据比文献值中采用重量分析法测试出的溶解度数据偏小,是因为测试装置不同造成的。 相似文献
82.
E. Q. Xie W. W. Wang N. Jiang D. Y. He Department of Physics Lanzhou University Lanzhou China 《金属学报(英文版)》2002,15(2):221-226
1. IntroductionThe transition metal silicides have attraeted much attention because of their potentialapplicatiOIl in very large scale integration (VLSI) de.ice[1]. Near-noble metal silicides canbe used as Schottky al1d ohn1ic col1tacts in silicon-based d… 相似文献
83.
The molecular orientation at the outer surface of injection–stretch–blow‐molded bottles made from poly(ethylene terephthalate) was characterized and quantified by means of front‐surface reflection infrared spectroscopy based on a method developed previously. Results were obtained for two different bottle shapes (cylindrical and rectangular) molded at different injection mold temperatures (16, 38, and 60°C). For the cylindrical bottles, the preferred molecular chain orientation was found to be in the axial direction, with the Hermans orientation function near 0.3 for all three mold temperatures. For the less symmetrical rectangular bottles, a significant difference was observed between the large and small faces. For the large face, the orientation was mainly in the hoop direction; the Hermans orientation function was in the range of 0.3–0.5 and was essentially the same at all mold temperatures and positions along the bottle height. For the small face, on the other hand, the preferred orientation changed from the hoop direction near the bottom to the axial direction near the top, and the variation was more pronounced at lower mold temperatures. The utility of the front‐surface reflection technique was clearly demonstrated. It was also applied, with the use of an infrared microscope, to examine the orientation gradient across the wall thickness. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1319–1327, 2007 相似文献
84.
A. Domingue K. Piyakis E. Sacher M. Di Renzo S. D nomm e T. H. Ellis 《The Journal of Adhesion》1993,40(2):151-162
The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer. 相似文献
85.
Zinc Coated Steel/Epoxy Adhesive Systems: Investigation of the Interfacial Zone by FTIR Spectroscopy
The present study takes advantage of the ability of Fourier Transform Infrared Spectroscopy (FTIR) for the analysis of ultrathin organic films on metals. FTIR in the reflection mode (IRRAS) is used in order to study the interaction of ultrathin films of dicyandiamide (hardener of most one-pack epoxy resins) with various substrates, model ones such as gold or zinc and industrial ones such as steel and zinc-coated steels.
Pure zinc surfaces and, to a lesser extent, zinc-coated steels are shown to react with dicyandiamide after heating at 180°C, as evidenced by the frequency shift of the absorption band (at about 2200 cm-1) characteristic for nitrile groups. As real systems consist of thick layers of a fully formulated adhesive cured onto a metallic substrate, the direct investigation of such a buried interphase is no longer possible by FTIR and by most of the known spectroscopies. Some mechanically tested specimens are then analysed, after failure, by FTIR microspectrometry. The spectra obtained, corresponding to the fracture initiation zone which is about 100 μm in diameter, advocate for the presence of an ultrathin layer of modified polymer still covering the substrate. 相似文献
Pure zinc surfaces and, to a lesser extent, zinc-coated steels are shown to react with dicyandiamide after heating at 180°C, as evidenced by the frequency shift of the absorption band (at about 2200 cm-1) characteristic for nitrile groups. As real systems consist of thick layers of a fully formulated adhesive cured onto a metallic substrate, the direct investigation of such a buried interphase is no longer possible by FTIR and by most of the known spectroscopies. Some mechanically tested specimens are then analysed, after failure, by FTIR microspectrometry. The spectra obtained, corresponding to the fracture initiation zone which is about 100 μm in diameter, advocate for the presence of an ultrathin layer of modified polymer still covering the substrate. 相似文献
86.
Symon M. Mahungu Steven L. Hansen William E. Artz 《Journal of the American Oil Chemists' Society》1994,71(4):453-455
Static headspace and capillary gas chromatography/infrared spectroscopy-mass spectrometry were used to collect, separate,
identify and quantitate the oxidative and thermal decomposition products in heated triolein. Approximately 4 L of triolein
was heated in a deep-fat fryer at 190°C for 12 h each day for a total of 60 h, until it contained>-20% polymeric material.
The concentration of heptane and octane increased after 12 h heating, then decreased upon further heating, while the concentration
of volatile aldehydes decreased gradually during heating. After 12 h of heating, the concentrations of the major volatiles
changed as follows: heptane (16.36 to 30.17 ppm), octane (24.48 to 40.77 ppm), heptanal (21.68 ppm to 9.11 ppm), octanal (35.53
to 36.64 ppm), nonanal (68.95 to 43.16 ppm), (E)-2-decenal (135.00 to 89.00 ppm) and (E)-2-undecenal (88.50 to 61.00 ppm).
After 60 h of heating, when the oil contained over 20% polymeric material, the concentrations of heptane, octane, heptanal,
octanol, nonanal, (E)-2-decenal and (E)-2-undecenal were 5.16, 4.39, 5.45, 7.02, 18.07, 12.50 and 6.00 ppm, respectively. 相似文献
87.
88.
Crosslinked copolymers of acrylamide (AA) and ethylacrylate and some ion exchangers derived from them containing either primary amine groups, obtained by the Hofmann degradation of the amide groups, or carboxylic groups, obtained by the alkaline hydrolysis of the ester groups, were studied. Divinylbenzene and N,N′‐methylenebisacrylamide were used as crosslinkers. The starting copolymers and the corresponding ion exchangers were characterized by IR spectroscopy, swelling behavior, and thermogravimetric analysis. The ion‐exchanger properties were correlated with the crosslinker nature and the chemical reactions performed on the AA copolymers. The average molecular weight between two crosslinks, determined from the swelling data in water, was compared with that calculated on the basis of the copolymerization stoichiometry only for the carboxylic cation exchangers. In this way, the preservation of the crosslink density after the hydrolysis was revealed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2701–2707, 2003 相似文献
89.
90.
有机磷化物制备羟基磷灰石工艺条件的探讨 总被引:1,自引:0,他引:1
探索用有机磷化物制备羟基磷灰石的工艺条件:采用硝酸钙、氨水、磷酸三丁酯为原料进行正交对比研究,优化得到了制备较佳羟基磷灰石的工艺条件。优化的工艺条件为:原料中Ca/P(molar ratio)1.67;Ca(NO3)2、4H2O/NH3H2O(g/g)为0.99;烧结温度为850℃:恒温时间为5h,并对合成的样品进行了化学和红外光谱的分析。 相似文献