Hydrogen Yield from Low Temperature Steam Reforming of Ethanol

Low temperature steam reforming of ethanol in the temperature range of 200–360°C was studied to maximize the production of H₂. The optimum reaction conditions in presence of a suitable catalyst can produce mainly the desired products H₂ and CO₂. Cu/Al₂O₃ catalysts with six different concentrations ranging from 0 to 10 wt.% Mn, were prepared, characterized and studied for the ethanol-steam reforming reaction. Maximum ethanol conversion of 60.7% and hydrogen yield of 3.74 (mol H₂ / mol ethanol converted) were observed at 360°C for catalyst with 2.5 wt.% Mn loading.     

层状复合硅酸钠的合成及性能测试

详细介绍了层状复合硅酸钠（LCS）的生产方法及其在洗衣粉中的应用，用LCS制得的洗衣粉，去污力优于无水偏硅酸钠、层状结晶硅酸钠和4A沸石，试验表明LCS是目前应用效果较好的无磷洗涤助剂。     

承压含水层地下水稳定流的有限层分析

有限层法是一种对空间某一方向进行数值离散,而在其余两方向采用连续函数的半数值半解析方法.该方法能有效地将三维问题简化为一维问题求解,从根本上解决了常用数值分析方法在模拟三维地下水运动时存在的计算工作量大、占用内存多、耗时大等缺点.文中基于有限层法的优点,推导了以伽辽金法结合贝塞耳函数为基础的层状非均质各向异性承压含水层的稳定流有限层方程,并编制了相应的计算程序.通过对2个经典算例的数值解与解析解对比分析,验证了该方法的正确性.     

Production of agrochemical from waste polyesters

In this study, agrochemical was produced from waste polyesters. Reactions of waste polyesters [poly (ethylene terephthalate) (PET) and poly (butylene terephthalate) (PBT)] powder with ethylene glycol (EG) in the presence of tetrahydrofurane (THF) using 0.003 mol lead acetate as a catalyst were carried out in a batch reactor at 470 K and at atmospheric pressure conditions. Reactions were undertaken with various particle size ranges from 50 to 512.5 μm, and reaction time from 30 to 70 min for reactions of polyesters. Low molecular weight product of polyester was obtained during this process. In the next stage, hydroxylamine hydrochloride (HAHC), cyclohexylamine (CHA), and potasium hydroxide (KOH) solution were introduced to convert low molecular weight product of polyester into terephthalohydroxamic acid (TPHA) by introduction of HCl (Hydrochloric Acid) as per stoichiometric requirement. TPHA can be used as an agrochemical (insecticide) with appreciable efficiency. To increase the polyester conversion rate, external catalyst (0.003 mol lead acetate) was introduced during the reaction. The product was deposited on the surface of unreacted polyester, which was removed from the surface by introducing dimethyl sulfoxide (DMSO). To accelerate the reaction rate, DMSO, CHA, and THF were introduced during the reaction, which has an industrial significance. Depolymerization of polyester was proportional to the reaction time. Depolymerization of polyester was inversely proportional to the particle size of polyester. Analyses of value‐added product (TPHA) and byproducts [EG and BD (1,4‐butanediol)] as well as polyesters were undertaken. A kinetic model is developed, and experimental data simulated with it, which was consistent with the model. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2504–2510, 2006     

二氧化锆负载催化剂的应用

由于二氧化锆是唯一同时拥有酸性和碱性及氧化性和还原性的金属氧化物，而且还是p-型半导体，易于产生氧空穴，作为催化剂载体，可和活性组分产生相互作用，因此由它负载的催化剂与其他物质负载的催化剂相比较，具有更多的优良性能。综述了ZrO₂负载的铜和铁等金属的催化剂和固体超强酸的应用，并简述了添加适量助剂对催化剂催化性能的影响。     

曝气生物滤池处理生活污水效能沿滤层高度的变化

采用曝气生物滤池处理生活污水,研究水中污染物沿滤层高度变化情况,以确定曝气生物滤池去除各污染物的有效滤层高度。研究结果表明,曝气生物滤池可有效处理生活污水。在二级滤池、滤层总高度4 m、滤速5.0 m/h条件下,出水COD、氨氮和总磷均能达到城镇污水处理厂综合排放标准。滤池总去除率,COD 90.39%,氨氮71.14%,总磷95.46%。曝气生物滤池去除COD主要在滤层0~2.6 m段,去除率75%,占总去除率的82.9%;去除氨氮主要在2.6~4.0 m段,去除率49.50%,占总去除率的69.6%;去除总磷主要在1.2~2.6段,去除率61.78%,占总去除率的64.7%。用曝气生物滤池处理生活污水,要达到《城镇污水处理厂综合排放标准》,滤层高度应在4 m左右。     

融合通信业务门户系统中业务逻辑层的扩展与实现

融合通信业务是提供语音、视频、数据和信息服务的综合业务．该业务提供自助服务门户系统,供集团客户管理员和个人用户对业务进行统一管理,业务门户使用SSH（Spring,Struts,Hibernate）框架搭建系统架构,但传统的基于SSH框架的系统实现方式不能满足该业务丰富的业务需求,因此需要对系统的业务逻辑层进行扩展．本文首先介绍融合通信业务组网环境和自助服务门户系统的功能需求,进而分析该系统对业务逻辑层的区别于其它系统的特殊需求,然后给出了业务逻辑层的扩展方案和具体实现．该业务逻辑层可以与复杂组网环境中的多种设备进行通信,充分发挥了SSH框架的能力．     

矩形毛坯最优层排样方式的动态规划算法*

讨论矩形毛坯无约束二维剪切排样问题,提出层排样方式的动态规划算法,使板材所含毛坯总价值最大。排样时使用一组平行的剪切线将板材分割为多个层,层的长度等于板材的长度或宽度,宽度等于最左边主毛坯的高度。通过动态规划算法确定所有可能尺寸层的最大价值和板材中层的最优组合。实验结果表明,该算法在满足实际应用要求的同时,板材利用率和计算时间两方面都较有效。     

载铜活性炭催化剂-微波法联用处理黄姜皂素废水

以硝酸铜为活性成分材料制备活性炭载体催化剂,采用载铜活性炭-微波联用的废水处理工艺,对黄姜皂素废水的COD降解效果进行了研究,并考察了催化剂用量、微波功率、微波处理时间、水样pH值、催化剂使用次数等影响因素。结果表明：在载铜活性炭的催化作用下,微波辐射处理能使黄姜生产皂素废水的COD迅速降低,去除率达到60%左右,明显优于单纯载铜活性炭或微波的处理效果。     

煤夹层地质条件下单桩承载特性分析

以南宁市地质条件下某桩基工程为例,采用有限元法对持力层存在煤夹层条件下桩基础的变形、应力进行计算,分析了煤夹层应力分布特征及其承载力的验算问题。研究表明：（1）当煤层厚度相同时,埋深越大,沉降越小;当煤层埋深相同时,煤层越厚,沉降也越大。（2）当埋深在1d～3d（d为桩径）时,煤层对持力层应力分布所起的＂扩散传递＂作用十分突出,超过3d时则影响很小;煤夹层越厚,扩散效果越明显,但当其厚度达到1.0 m时,煤夹层对持力层应力的扩散作用明显减弱。（3）煤层埋深越小,其最大主应力越大。桩端以下应力扩散的主要影响范围在3d以内,煤层越薄,其内部应力越大,煤层厚度增大也会导致沉降增大。模拟值与实测值吻合较好。