层流等离子体射流铝合金表面熔覆SiCp/Al-Si涂层的磨损过程

采用层流等离子体炬作为加热热源，在ZL104铝硅合金表面制备镍包SiCp／Al-Si复合熔覆层。磨损过程中，该熔覆层中的SiCp颗粒微凸体对磨轮的切削产生的切屑，在熔覆层表面形成机械混合层(MML)，此机械混合层硬度较高，耐磨性好，使熔覆层在磨损过程中经历了较长距离的磨损孕育阶段，从而改变了铝合金的磨损过程，延缓了中等磨损向严重磨损的转变。     

连铸辊表面堆焊层开裂原因分析

采用化学成分、金相组织和扫描电镜断口分析及显微硬度测定等手段对连铸辊表面堆焊层开裂部位进行了取样分析。结果表明，堆焊工艺制定不当，热影响区的过热区形成高碳粗大马氏体组织及保留了较大的焊接应力．是导致堆焊层开裂的主要原因。并提出了改进措施和建议。     

硼离子注入对多晶Ni力学性能及微观结构的影响

用能量为50keV,剂量为3×10~(17)ions/cm_2的B~+注入多晶Ni,通过力学性能实验研究了多晶Ni注入前后表面硬度和疲劳性能的变化,以及多晶Ni表面层注入和疲劳前后化学成分、滑移特征、裂纹萌生、断裂方式和微观结构的变化。结果表明,B~+注入多晶Ni后,表面区域形成一个不同组织结构的由Ni-B非晶、Ni_3B和Ni_4B_3第二相以及辐照损伤组成的多层次的注入层,提高了多晶Ni的表面硬度,并使其疲劳极限提高16％。探讨了B~+注入影响多晶Ni疲劳极限的几种可能机制。     

Study on the microstructure and mechanical properties of medium carbon Cr-Si-Mn-Mo-V steel for cast inserted dies

1 Introduction It is known that the die is a key piece of equipment during the development of the automobile industry. Until now, the inserted dies for trimming, reshaping and punching of the automobile covering components were made of forged steel of T10A and Crl2MoV [1,2] and cast iron alloy by built up welding [3,4]. Because of the complicated forging process, the directivity of forged inserted die, the long time taken for production and the large amount of metal, forged inserted dies are…     

焙烧HDS失活催化剂提取钒的动力学

在固定床反应器中 ,用空气焙烧HDS失活催化剂 ,再用碳酸钠水溶液浸取钒和钼。研究了钒焙烧转化率随失活催化剂粒径、焙烧温度及焙烧时间的变化关系 ,结果表明 :实验数据可以用收缩未反应核模型拟合。当催化剂平均粒径小于 6 0 μm ,或在较低反应温度及较低转化率下 ,内扩散阻力可以忽略不计 ,过程受化学反应控制 ;而当平均粒径大于 6 0 μm ,且在较高反应温度及较高转化率下 ,过程同时受化学动力学与内扩散控制。分别导出了 2种情况下焙烧钒的动力学方程式 ,并按方程式计算得到反应温度在 92 3～ 112 3K时的活化能为 5 6 .12kJ·mol-1。     

热处理对D618堆焊层组织和性能的影响

研究了高碳高铬铸铁型硬质合金堆焊层在不同热处理条件下的组织、硬度与耐磨性。研究结果表明D618硬质合金堆焊层经850℃加热后空冷或850℃加热后油冷＋400℃回火，具有较高的硬度和优异的耐磨蚀磨损性能，比35CrMo低合金钢碳氮共渗（850℃油冷＋200℃回火）后的耐腐蚀磨损性能提高3－12倍。     

Investigation into the evolution of corrosion product layer (CPL) of 1018 C-steel exposed to multiphase environment using FIB and EIS techniques

This communication reports into the effects of flow, fluid composition and the effectiveness of imidazoline inhibitors on the evolution and distribution of corrosion products on 1018 C-steel exposed to CO₂ corrosion. Focused ion beam technique was used to measure the thickness of the corrosion product layer (CPL), in contrast to the conventional techniques used to observe the cross-section of specimens. Morphological analysis using scanning electron microscopy revealed topographical variations on the surface with the change in the multiphase environment. The CPL was found to be more porous in nature with the presence of oil in the multiphase environment. Electrochemical impedance spectroscopy was also used in the present study to measure the corrosion rates and was subsequently correlated to the CPL evolution for 1018 C-steel in multiphase environment.     

加工TiNi形状记忆丝的新工艺

采用模拟试样研究了Ti/TiAl、Nb/TiAl和NbTi/TiAl 3种复合材料的界面特性。结果表明,爆炸试样的界面反应层厚度远小于热等静压试样的界面反应层厚度。在同一条件下热等静压成型的这3种复合材料,其界面差异明显:Ti/TiAl和NbTi/TiAl试样的界面反应层较厚,界面结合强度较高;Nb/TiAl试样的界面反应层较薄,界面结合强度较低。     

Effect of gas composition on cementite decomposition and coke formation on iron

Cementite decomposition and coke formation in the metal dusting process of iron were investigated at 700 °C in CO-H₂-H₂O gas mixtures. The presence of graphite deposited on the surface initiates the decomposition of cementite into iron and graphite. The morphology of the reaction products varies with gas composition. For CO concentrations less than 5 vol%, particles of iron or even closed iron layers have been observed at the cementite/graphite interface. With increasing CO content the amount of iron in the interface decreases. At CO concentrations higher than 30 vol%, iron could not be detected at the interface by optical microscopy. Thermo-gravimetric analysis shows that the rate of carbon take-up increases with increasing CO concentration reaching a maximum at about 60-75 vol%.The morphologies of graphite in the coke layer can be identified as three types: porous graphite clusters with embedded iron-containing particles, compact bulk graphite with a uniform thickness and a columnar layered structure, and filamentous carbon with iron-containing phases at the tip or along its length. For gas mixtures with low CO concentrations, e.g. 5 vol%, porous graphite clusters are the main form of carbon although filamentous carbon can be seen at the early stage of reaction. With increasing CO concentrations to, e.g. 30 vol%, a compact bulk graphite is formed on the top of the surface. Under this compact graphite, there is an inner layer of graphite which is the combination of porous graphite clusters and filaments. These two layers of graphite are clearly distinguishable when CO content reaches more than 75 vol%. In this case, the main form of graphite in the inner layer is filamentous carbon. The compact graphite layer suffers a serious deformation and forms many cracks because of the growth of catalytic filamentous carbon underneath. These filaments grow outside from compact graphite crevices and finally cover the whole surface. The higher the CO content in the gas, the more the tendency of filamentous carbon formation. The interplay between morphologies of carbon formation and metal dusting has been discussed.     

钢铬钛共渗工艺的研究

对工业纯铁、45钢和3Cr2W8V钢的低真空铬钛共渗进行了研究,探讨了共渗层的组织结构、生长过程以及温度、时间等工艺因素的影响。