催化氧化法合成脂肪醇醚羧酸盐的研究进展

详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20～60℃,反应时间3～6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50～90℃反应2～6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95％,选择性达90％以上。     

Synthesis,Functionalization, and Bioconjugation of Monodisperse,Silica‐Coated Gold Nanoparticles: Robust Bioprobes

Herein, we report an efficient process for preparing monodisperse Au@SiO₂ nanoparticles using homogeneous shaking and without the use of surface‐coupling silane agents or large stabilizers. The resulting pure‐silica surface of the Au@SiO₂ nanoparticles is very important for straightforward surface functionalization with different functional groups via well‐established silica surface chemistry. Subsequent covalent bioconjugation of the aldehyde‐functionalized Au@SiO₂ nanoparticles with various biomolecules is successfully employed to make robust nanoprobes for fast, colorimetric DNA and protein detection based on the sequence‐specific hybridization properties of DNA and the specific binding affinity between proteins, respectively.     

铂与氢、水和苯分子相互作用的量子化学研究

采用量子化学程序Gaussian98(A.9)从头算的B3LYP方法，全优化计算铂对氢、水和苯的化学吸附作用，得到了3种相关络合物PtX、PtXX和Ptxxx(X=H，H2O或C6H6)的平衡几何构型和电子结构信息，并探讨了这些络合物的成键性质，以及苯环与铂原子之间的分子轨道作用性质。结果表明，苯环与铂原子之间有很强的成键作用，并随着游离氢原子和水分子的参与，作用强度有很大变化。苯分子吸附在金属铂上，它的芳香性得到不同程度的降低，苯环被活化，苯环与铂原子之间形成η^2型π键络合物；水参与作用后，苯环与铂原子之间形成σ络合物；氢和水同时参与作用后，苯环与铂原子之间仅有很弱的π轨道作用。     

树状大分子/金属纳米复合物的制备与催化作用

综述了一类新的有机/无机杂化纳米材料———树状大分子/金属纳米复合物的制备及其催化作用。树状大分子/金属纳米复合物是以树状大分子为模板或稳定剂,通过还原树状大分子内或树状大分子间螯合金属离子制备。讨论了树状大分子/金属纳米复合物在水、有机溶剂、氟/有机两相溶剂和超临界CO2中的催化作用。     

石油天然气长输管线用钢新进展

本文介绍了１９９０年以来国外在石油天然气长输管线用钢方面的最新成果，以获得较低的强度和韧性匹配为目的经轧后加速冷却工艺后的钢的强度的预测和控制；具有优良抗氢致裂纹的含硼、微碳、低硫、Ｎｂ－Ｔｉ微合金化、Ｘ６５－Ｘ８０级管线钢的开发，满足于特殊性能要求的ＴｉＯ处理技术及Ｘ８０级ＴｉＯ细化晶粒钢、低硬度和低屈强比钢，以及复合板加工耐腐蚀钢管的生产。     

圆盘式高速金属冷锯机锯切功率的实验研究

对１６００圆盘式高速金属冷锯机进行了锯切功率的实验研究。对某厂四种有代表性的产品，用不同的进锯速度，实测每种条件下的锯切功率变化，和最大瞬时锯切功率与平均锯切功率之比。并以实测数据为基础，得出每种产品以进锯速度为自变量的平均锯切功率回归公式。这些工作，不仅可以为这种冷锯机锯切功率的理论研究提供依据，还可直接为使用和设计这种冷锯机给出具体参考数据。     

Stress concentration and fatigue of profiled reinforcing steels

Stress concentrations arise from profiles of ribbed reinforcing steel bars and in this study the results of calculated stress concentration factors (SCF), by using finite element method, are related to the fatigue test results. It is apparent that the degree of confinement of a ribbed bar embedded in concrete not only affects the magnitude of the ultimate bond stress but also the bond stress-slip relation. Thus the rib geometry or profile pattern is designed for optimum bond characteristics and not for fatigue considerations. However the rib geometry influences the fatigue performance through the SCFs arising from the root radius, width and flank angles of the profiles. It is shown that these latter factors have a significant influence on the fatigue behaviour of reinforcing steel bars.     

孟加拉HATHAZARI 132kV电缆回流线取舍探讨

针对孟加拉Hathazari 100MW重油发电机组EPC工程132kV电缆现场实际设计、采购和敷设情况,通过理论计算探讨回流线取舍问题。     

Accelerated sintering of PtRh/Al2O3 catalysts in an oxygen periodic pulse flow

PtRh catalysts were prepared by coimpregnation, with chlorine-free precursors of a -alumina. They were sintered at 973 K under a continuous flow of O₂ (1% in Ar or air) or of a flow of Ar into which pulses of O₂ were injected periodically. Under the latter conditions the sintering was significantly accelerated, particularly for a certain value of the period of O₂ pulses.