全文获取类型
收费全文 | 66094篇 |
免费 | 6411篇 |
国内免费 | 2890篇 |
专业分类
电工技术 | 2820篇 |
技术理论 | 2篇 |
综合类 | 3418篇 |
化学工业 | 14792篇 |
金属工艺 | 2131篇 |
机械仪表 | 3327篇 |
建筑科学 | 1660篇 |
矿业工程 | 1501篇 |
能源动力 | 2532篇 |
轻工业 | 11683篇 |
水利工程 | 454篇 |
石油天然气 | 20827篇 |
武器工业 | 160篇 |
无线电 | 1584篇 |
一般工业技术 | 2663篇 |
冶金工业 | 1620篇 |
原子能技术 | 93篇 |
自动化技术 | 4128篇 |
出版年
2024年 | 327篇 |
2023年 | 847篇 |
2022年 | 1559篇 |
2021年 | 1951篇 |
2020年 | 2209篇 |
2019年 | 2296篇 |
2018年 | 1963篇 |
2017年 | 2489篇 |
2016年 | 2712篇 |
2015年 | 2558篇 |
2014年 | 3803篇 |
2013年 | 4099篇 |
2012年 | 4378篇 |
2011年 | 4533篇 |
2010年 | 3279篇 |
2009年 | 3072篇 |
2008年 | 2831篇 |
2007年 | 3647篇 |
2006年 | 3834篇 |
2005年 | 3407篇 |
2004年 | 2973篇 |
2003年 | 2794篇 |
2002年 | 2577篇 |
2001年 | 2276篇 |
2000年 | 1919篇 |
1999年 | 1548篇 |
1998年 | 1210篇 |
1997年 | 1008篇 |
1996年 | 795篇 |
1995年 | 612篇 |
1994年 | 465篇 |
1993年 | 308篇 |
1992年 | 273篇 |
1991年 | 205篇 |
1990年 | 151篇 |
1989年 | 105篇 |
1988年 | 66篇 |
1987年 | 50篇 |
1986年 | 27篇 |
1985年 | 63篇 |
1984年 | 56篇 |
1983年 | 40篇 |
1982年 | 27篇 |
1981年 | 10篇 |
1980年 | 16篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
A heavy crude oil has been treated with deuterated alkylating reagents (CD3I and C2D5I) and directly analyzed without any prior fractionation and chromatographic separation by high-field Orbitrap Fourier Transform Mass Spectrometry (FTMS) and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) using electrospray ionization (ESI). The reaction of a polycyclic aromatic sulfur heterocycles (PASHs) dibenzothiophene (DBT), in the presence of silver tetrafluoroborate (AgBF4) with ethyl iodide (C2H5I) in anhydrous dichloroethane (DCE) was optimized as a sample reaction to study heavy crude oil mixtures, and the reaction yield was monitored and determined by proton nuclear magnetic resonance spectroscopy (1H-NMR). The obtained conditions were then applied to a mixture of standard aromatic CH-, N-, O- and S-containing compounds and then a heavy crude oil, and only sulfur-containing compounds were selectively alkylated. The deuterium labeled alkylating reagents, iodomethane-d3 (CD3I) and iodoethane-d5 (C2D5I), were employed to the alkylation of heavy crude oil to selectively differentiate the tagged sulfur species from the original crude oil. 相似文献
42.
Francesco Di Girolamo Andrea Masotti Isabella Lante Margherita Scapaticci Cosima Damiana Calvano Carlo Zambonin Maurizio Muraca Lorenza Putignani 《International journal of molecular sciences》2015,16(9):20896-20912
Extra virgin olive oil (EVOO) with its nutraceutical characteristics substantially contributes as a major nutrient to the health benefit of the Mediterranean diet. Unfortunately, the adulteration of EVOO with less expensive oils (e.g., peanut and corn oils), has become one of the biggest source of agricultural fraud in the European Union, with important health implications for consumers, mainly due to the introduction of seed oil-derived allergens causing, especially in children, severe food allergy phenomena. In this regard, revealing adulterations of EVOO is of fundamental importance for health care and prevention reasons, especially in children. To this aim, effective analytical methods to assess EVOO purity are necessary. Here, we propose a simple, rapid, robust and very sensitive method for non-specialized mass spectrometric laboratory, based on the matrix-assisted laser desorption/ionization mass spectrometry (MALDI-TOF MS) coupled to unsupervised hierarchical clustering (UHC), principal component (PCA) and Pearson’s correlation analyses, to reveal corn oil (CO) adulterations in EVOO at very low levels (down to 0.5%). 相似文献
43.
Mohamed Becherif 《Asian journal of control》2019,21(4):2137-2154
Induction machines (IM) constitute a theoretically interesting and practically important class of nonlinear systems. They are frequently used as wind generators for their power/cost ratio. They are described by a fifth‐order nonlinear differential equation with two inputs and only three state variables available for measurement. The control task is further complicated by the fact that IM are subject to unknown (load) disturbances and the parameters can be of great uncertainty. One is then faced with the challenging problem of controlling a highly nonlinear system, with unknown time‐varying parameters, where the regulated output, besides being unmeasurable, is perturbed by an unknown additive signal. Passivity‐based control (PBC) is a well‐established structure‐preserving design methodology which has shown to be very powerful to design robust controllers for physical systems described by Euler‐Lagrange equations of motion. PBCs provide a natural procedure to "shape" the potential energy yielding controllers with a clear physical interpretation in terms of interconnection of the system with its environment and are robust vis á vis to unmodeled dissipative effects. One recent approach of PBC is the Interconnection and Damping Assignment Passivity‐Based Control (IDA‐PBC) which is a very useful technique to control nonlinear systems assigning a desired (Port‐Controlled Hamiltonian) structure to the closed‐loop. The aim of this paper is to give a survey on different PBC of IM. The originality of this work is that the author proves that the well known field oriented control of IM is a particular case of the IDA‐PBC with disturbance. 相似文献
44.
45.
Mohamed Abdellatif 《Color research and application》2015,40(6):564-576
The spectral overlap of color‐sampling filters increases errors when using a diagonal matrix transform, for color correction and reduces color distinction. Spectral sharpening is a transformation of colors that was introduced to reduce color‐constancy errors when the colors are collected through spectrally overlapping filters. The earlier color‐constancy methods improved color precision when the illuminant color is changed, but they overlooked the color distinction. In this article, we introduce a new spectral sharpening technique that has a good compromise of color precision and distinction, based on real physical constraints. The spectral overlap is measured through observing a gray reference chart with a set of real and spectrally disjoint filters selected by the user. The new sharpening method enables to sharpen colors obtained by a sensor without knowing the camera response functions. Experiments with real images showed that the colors sharpened by the new method have good levels of color precision and distinction as well. The color‐constancy performance is compared with the data‐based sharpening method in terms of both precision and distinction. © 2014 Wiley Periodicals, Inc. Col Res Appl, 40, 564–576, 2015 相似文献
46.
Effect of Different Cosolvents on Transesterification of Waste Cooking Oil in a Microreactor 下载免费PDF全文
Biodiesel was prepared from waste cooking oil combined with methanol. The process was performed via transesterification in a microreactor using kettle limescale as a heterogeneous catalyst and various cosolvents under different conditions. n‐Hexane and tetrahydrofuran were selected as cosolvents to investigate fatty acid methyl esters (FAMEs). To optimize the reaction conditions, the main parameters affecting FAME% including reaction temperature, catalyst concentration, oil‐to‐methanol volumetric ratio, and cosolvent‐to‐methanol volumetric ratio were studied via response surface methodology. Under optimal reaction conditions and in the presence of the cosolvents n‐hexane and tetrahydrofuran, high FAME purities were achieved. Considering the experimental results, the limescale catalyst is a unique material, and the cosolvent method can reduce significantly the reaction time and biodiesel production cost. 相似文献
47.
Izabella Jackowska Monika Bojanowska Monika Staszowska-Karkut Monika Sachadyn-Król 《International Journal of Food Science & Technology》2019,54(12):3175-3184
Ozonation is an innovative way to preserve high quality of seed during storage and it is an alternative to harmful organophosphorus agents. Disclosure of changes in the rapeseed oil under the influence of oxidative action of ozone on the seeds was the aim of the work and is presented for the first time. Two ozone concentrations and different length of ozonation were applied. The changes in tocopherols, phenolics, flavonoids contents, antiradical activity and oxidative stability were examined. The average vitamin E concentration was 33 mg per 100 g of oil before and 31.7 after ozonation of seeds. The average content of phenolic compounds was 14.3 mg of sinapic acid g−1 and 16.9 after the ozone treatment. Changes in the flavonoids content and antioxidant activity were observed too. Ozonation caused a decrease in the vitamin E concentration which resulted also in reducing the quenching of free radicals and reduction of oil induction time. 相似文献
48.
49.
Numerical dissipation acts as artificial viscosity to make smoke viscous. Reducing numerical dissipation is able to recover visual details smeared out by the numerical dissipation. Great efforts have been devoted to suppress the numerical dissipation in smoke simulation in the past few years. In this paper we investigate methods of combating the numerical dissipation. We describe visual consequences of the numerical dissipation and explore sources that introduce the numerical dissipation into course of smoke simulation. Methods are investigated from various aspects including grid variation, high-order advection, sub-grid compensation, invariant conservation, and particle-based improvement, followed by discussion and comparison in terms of visual quality, computational overhead, ease of implementation, adaptivity, and scalability, which leads to their different applicability to various application scenarios. 相似文献
50.
Shailesh J. Patil 《Chemical Engineering Communications》2019,206(5):605-618
Jatropha oil is a promising nonedible feedstock for producing renewable diesel. In this work, the hydrotreatment processing of jatropha oil was investigated. Instead of using conventional alumina-supported Co–Mo, Ni–Mo, and Ni–W catalysts that need sulfidation pretreatment, noble metals such as Pd and Ru were chosen. Trials were performed in an isothermal trickle-bed reactor and the reaction conditions were as follows: temperature 603–663?K, weight hourly space velocity (WHSV) 1 to 4/h, pressure 1.5–3?MPa, and H2/oil ratio 200–800 (v/v). Yield of n-C15 to n-C18 hydrocarbons was maximized (70.3 and 43.8% for Pd/Al2O3 and Ru/Al2O3, respectively) at the following conditions: T?=?663 K, WHSV?=?2/h, P?=?3?MPa, and H2/oil ratio?=?600 (v/v). Since Ru favored cracking reactions to a larger extent than Pd, the yield of C15 to C18 hydrocarbons over Ru/Al2O3 was lowered. Using simple first-order plots for oil conversion, activation energies for the hydrotreating process over Pd/Al2O3 and Ru/Al2O3 were found and they were equal to 109 and 121?kJ/mol, correspondingly. 相似文献