Gradient “Single-Crystal” Li-Rich Cathode Materials for High-Stable Lithium-Ion Batteries

As one of the high-energy cathode materials of lithium-ion batteries (LIBs), lithium-rich-layered oxide with “single-crystal” characteristic (SC-LLO) can effectively restrain side reactions and cracks due to the reduced inner boundaries and enhanced mechanical stabilities. However, there are still high challenges for SC-LLO with diverse performance requirements, especially on their cycle stability improvement. Herein, a novel concentration gradient “single-crystal” LLO (GSC-LLO), with gradually decreasing Mn and increasing Ni contents from center to surface, is designed and prepared by combining co-precipitation and molten-salt sintering methods, yielding a capacity retention of 97.6% and an energy density retention of 95.8% within 100 cycles at 0.1 C. The enhanced performance is mostly attributed to the gradient-induced stabilized structure, free of cracks and less spinel-like structure formation after long-term cycling. Furthermore, the gradient design is also beneficial to the safety of LLOs as suggested by the improved thermal stability and reduced gas release. This study provides an effective strategy to prepare high-energy, high-stability, and high-safety LLOs for advanced LIBs.     

基于聚类与时间耦合执行序列的任务分解方法

本文针对复杂任务分析中的高度耦合任务不易分解且需重构排序的问题,提出了一种基于聚类分析与改进时间-耦合执行序列的自适应任务分解方法。在矩阵最值遴选模型和任务序列转移策略相结合的基础上,设计了基于中间任务序列的任务矩阵分割算法;并进一步采用粒度自主循环调整机制,最终实现了复杂任务的自适应解耦分析。仿真验证结果表明,该方法能够有效实现复杂任务的解耦及序列重构,在作战任务分析领域具有很好的推广应用前景。     

硫酸盐干湿循环下带冷缝混凝土能量演化研究北大核心CSCD

为探究硫酸盐干湿循环作用下带冷缝混凝土受荷作用时的能量演化规律,制作了整浇和浇筑间隔0.25 d、0.5 d、1 d、7 d和28 d的带冷缝混凝土,基于单轴压缩实验及能量计算原理,研究了硫酸盐干湿循环对带冷缝混凝土强度和能量演化规律的影响。结果表明:带冷缝混凝土强度及损伤应力和峰值应力处弹性应变能与耗散能均随干湿循环呈先增大后减小的趋势,随着新混凝土与母体浇筑间隔的增加呈现减小的趋势;随着干湿循环次数的增加,损伤应力处储能水平Kad先减小后增加,说明损伤应力处储能水平越高,带冷缝混凝土越容易产生损伤,Kad可以作为混凝土破坏的预警指标。     

太阳能驱动的氢-冷-热-电综合能源系统性能分析

基于可再生能源的综合能源系统具有清洁低碳与安全高效的特点。提出一种以抛物面槽式太阳能集热器驱动的综合能源系统,该系统包括质子交换膜电解池、有机朗肯循环和吸收式制冷子系统。根据能量梯级利用原理和热力学分析理论,建立综合能源系统的稳态数学模型,分析热力参数变化对系统性能的影响规律。结果表明,在设计条件下,质子交换膜电解槽制氢效率、有机朗肯循环发电效率和吸收式制冷效率分别为58.65%、12.20%、36.93%,制氢功冷联供总效率为55.58%。系统总效率随着涡轮机入口温度升高先增加后减少;随着发生器出口温度升高而增加。另外,增加工作压力和膜厚度会导致电解槽电压升高和电解槽效率下降。研究结果可为以抛物面槽式太阳能集热器驱动的多联供系统的建立和评价提供参考。     

一种SVPWM简化算法的设计与实现

针对传统空间矢量脉宽调制（SVPWM）算法需要进行求反正切、求正弦、求余弦等三角运算,造成其在嵌入式MCU中实现较为复杂、计算量大的问题,介绍了一种简化的SVPWM算法。设计了一种和（a,b,c）三相参考系成逆时针90°夹角的（a'',b'',c''）参考系,使新的三相参考系和SVPWM扇区边界垂直,将（α,β）正交坐标系下的合成电压空间矢量U_s映射到（a'',b'',c''）参考系,根据a''、b''、c''轴分量的正负号直接判断矢量所在扇区。将PWM模块设置为中心对齐模式,跳过基本矢量维持时间的计算,根据标幺化的a''、b''、c''轴分量和U_s所在扇区直接计算PWM模块的占空比,采用七段式SVPWM方法实现对a、b、c三相相电压的SVPWM。所提算法简化了SVPWM中的空间矢量扇区判断和占空比计算,缩短了SVPWM的运算时间,为进一步提升逆变器的开关频率提供了空间。     

“信号与系统”课程教学实例

信号频谱分析是“信号与系统”课程中的重点内容,但学生在理解相关概念和理论时常存在较大的困难。针对这种现象,本文介绍了一种信号频谱分析的教学实例。该实例利用傅里叶变换的数值计算方法,对太阳黑子数进行频谱分析,并确定太阳活动的周期。本教学实例注重引导学生理论联系实际,既深化学生对频谱分析的基本概念与基本理论的理解,又有利于培养学生分析解决实际问题的能力。     

一种基于AHP和FIS的WSN路由算法

无线传感器网络（WSN）由许多传感器节点组成,这些传感器节点为了降低能量消耗会周期性地在醒与睡2种模式下进行切换。在异步WSN中,发送节点往往要等接收节点醒来才能进行数据转发,为了缩短该等待时延,发送节点选择多个节点作为候选转发节点,由于任何候选转发节点都有可能进行数据路由,使得邻居节点评估和候选转发节点选择对网络性能产生较大影响。为了更好地进行节点评估与选择,提出一种基于层次分析法（AHP）和模糊推理系统（FIS）的WSN路由算法DAF。将剩余能量、距离和角度作为评估准则,利用AHP确定评估准则的权重,通过FIS动态构建AHP中的成对比较矩阵,并根据该矩阵动态计算出邻居节点的评分,按评分高低选择候选转发节点。实验结果表明,在改变节点数量、睡眠时长和通信半径的对比测试中,DAF在生命周期、能量消耗和平均冗余传输性能方面均优于ORW和ORR算法。     

Fitting fatigue data with a bi‐conditional model

The formulation of a probability‐stress‐life (P‐S‐N) curve is a necessary step beyond the basic S‐N relation when dealing with reliability. This paper presents a model, relevant to materials that exhibits a fatigue limit, which considers the number of cycles to failure and the occurrence of the failure itself as statistically independent events, described with different distributions and/or different degree of scatter. Combining these two as a parallel system leads to the proposed model. In the case where the S‐N relation is a Basquin's law, the formulations of the probability density function, cumulative distribution function, quantiles, parameter and quantile confidence interval are presented in a procedure that allows practically any testing strategy. The result is a flexible model combined with the tools that deliver a wide range of information needed in the design phase. Finally, an extension to include static strength and applicability to fatigue crack growth and defects‐based fatigue approach are presented.     

Research on lease and sale of electric vehicles based on value engineering

Electric vehicles (EVs) acknowledged as potential means of transportation tools in the near future are widely accepted as the development trend of automobile industry due to its environment protection and fuel energy saving properties. As a product containing new technologies and concepts with little market experience and consumer identification, studying its life cycle operation modes will help to figure out an optimal approach to conduct EVs manufacturing and service. The two common operation modes, lease and sale of EVs, have their own advantages and weaknesses under different scenarios and consumer psychological status. Research and comparisons on the function, cost and value of two operation modes in full life cycle will simulate the rapid development of EVs forming a mature and dynamic operation mechanism. This paper utilised approaches in value engineering, putting forward customer requirements and technical elements of EV lease and sale based on quality assessment and customer-perceived value, proposing the metric method of function and cost coefficient by mathematical modelling, and conducting value coefficient analysis and comparison based on customer’s risk aversion psychology. An illustrative example raised for studying operation mode of three different kinds of EVs based on the analysis of value coefficient, providing guideline for manufacturer and servicers of EVs.