卵磷脂改善泥浆性能的研究

研究了卵磷脂改善泥浆性能的作用。通过在一定含水量的泥浆中，比较加入卵磷脂前与加入卵磷脂后的泥浆性能，以及比较加入不同系列型号的卵磷脂问的泥浆性能，得到卵磷脂对泥浆性能的影响，从而优化出改善泥料性能的卵磷脂的种类与用量。     

Settling velocities of particles in bubbly gas-liquid mixtures

The axial dispersion-sedimentation model is commonly used to describe the axial concentrations of solids in three phase bubble columns at low liquid velocities. When the two parameters of this model, the particle settling velocity and the solids axial dispersion coefficient, are uncoupled by the use of various assumptions, physically unrealistic values of these parameters often result. Direct experimental measurements of solids settling rates in bubbly gas-liquid mixtures were carried out. The measured mean settling velocities decreased slightly with gas flow rate and were equal to or slightly less than the single particle free settling velocity in the liquid alone. Solids axial dispersion coefficients were also obtained from the solids settling rate distribution data, and gave values considerably less than the experimental liquid axial dispersion coefficient.     

The tribological behavior of micrometer and nanometer TiO2 particle‐filled poly(phthalazine ether sulfone ketone) composites

Micrometer and nanometer TiO₂ particle‐filled poly(phthalazine ether sulfone ketone) (PPESK) composites with various filler volume fractions from 0.5 to 7.5 vol % were prepared by heating compression molding. The friction and wear behaviors of the PPESK composites were evaluated using the block‐on‐ring test rig by sliding PPESK‐based composite blocks against a mild carbon steel ring under dry friction conditions. The wear debris and the worn surfaces of the PPESK composites filled with micrometer and nanometer TiO₂ particles were investigated by using a scanning electron microscope (SEM), while the structures of PPESK composites and wear debris were analyzed with IR spectra. Experimental results show that antiwear properties of the PPESK composites can be improved greatly by filling nanometer TiO₂ particles, and the friction coefficient decreases when the filler volume fraction is below 2.5%, but when the filler volume fraction is above 2.5% the friction coefficient increases gradually with increasing filler volume fraction. In the case of micrometer TiO₂ filler, wear rates increase with increasing filler volume fractions under identical test conditions, and the friction coefficients are less sensitive to the filler volume fraction. It was also found that the wear mechanism of micrometer TiO₂ particle‐filled PPESK is mainly severe adhesion and abrasive wear, while that of nanometer TiO₂ particle‐filled PPESK is mainly slight abrasive wear. In the former case, there are no transfer film formed on the surface of the counterpart steel, and wear debris are in the form of long and large ribbon. While in the latter case, the wear debris was granule and their size was about 10 μm. In case of 1 vol % nanometer TiO₂ particle‐filled PPESK composites, the transfer film was fairly thinner and smoother, and the transfer film provided better coverage on the surface of steel ring, while that of 7.5 vol % was thicker and discrete. These account for the different friction and wear behavior of micrometer and nanometer TiO₂ particle‐filled PPESK composite. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 906–914, 2004     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

基于FA/MR分析方法的徐州市大气颗粒物PAHs源解析

在徐州市布设3个采样点,进行大气颗粒物采样.通过因子分析法（FA）判断徐州市大气颗粒物中多环芳烃的主要来源,并利用多元逐步回归法（MR）确定各污染源对多环芳烃污染的贡献率.结果表明,徐州市大气颗粒物中多环芳烃的主要来源为交通污染源、燃煤污染源和高温加热源,贡献率分别为61.4%、20.5%和16.1%.     

Electrodeposition of Ni-Co-Fe2O3 composite coatings

Ni-Co-Fe₂O₃ composite coatings were electrodeposited using cetyltrimethylammonium bromide (CTAB)-modified Watt’s nickel bath with Fe₂O₃ particles dispersed in it. The effects of the plating parameters on the chemical composition, structural and morphological characteristics of the electrodeposited Ni-Co-Fe₂O₃ composite coatings were investigated by energy dispersive X-ray (EDS) spectroscopy, X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results reveal that Fe₂O₃ particles can be codeposited in the Ni-Co matrix. The codeposition of Fe₂O₃ particles with Ni-Co is favoured at high Fe₂O₃ particle concentration and medium stirring, and the deposition of Co is favoured at high concentration of CTAB. Moreover, the study of the textural perfection of the deposits reveals that the presence of particles leads to the worsening of the quality of the observed 〈220〉 preferred orientation. Composites with high concentration of embedded particles exhibit a preferred crystal orientation of 〈111〉. The more the embedded Fe₂O₃ particles in the metallic matrix, the smaller the sizes of the crystallite for the composite deposits.     

温度和初始颗粒大小对絮体破碎再絮凝的研究

鉴于絮体的形成/破碎/再絮凝过程在适当条件下具有强化去除水中颗粒物的效果,研究温度和初始颗粒大小对絮体破碎再絮凝去除水中颗粒的影响.采用PDA2000透光率脉动检测仪对絮体破碎再絮凝过程进行在线监测.结果表明,在较低温度条件下,絮体破碎后能有较大的恢复率;初始颗粒越大,絮体大小恢复率越高,由较小初始颗粒产生的絮体经破碎后再絮凝其再生能力不如大颗粒,沉后水浊度与大颗粒相比不具有降低优势.当电中和机理占主导作用时,絮体破碎后能重新絮凝,絮体大小能恢复到破碎之前;而当网捕卷扫机理占主导作用时,絮体的恢复能力不如电中和条件,再絮凝能力降低.絮体破碎后再絮凝的沉后水浊度明显低于破碎前,水温对其结果的影响不大.絮体破碎后再絮凝,适用于较大的初始颗粒和较低水温.     

Numerical simulation of electroosmotic flow in hydrophobic microchannels

Electroosmotic flow (EOF) is a promising way for driving and mixing fluids in microfluidics. For the parallel-plate microchannel with the hydrophobic surface, this paper solved the governing equations using the finite element method (FEM), and the effects of microchannel height, electric strength and ionic concentration on EOF were thus investigated. The simulation indicates that the transient characteristics of EOF are similar in hydrophobic and hydrophilic microchannels, the steady time of EOF is proportional to the square of microchannel height, and the scale is microsecond. EOF velocity is proportional to the electric strength and independent of the channel height, and decreases slowly with the ionic concentration, which is lower than that in hydrophilic microchannel due to the presence of slip length in hydrophobic microchannel. The results can provide valuable insights into the optimal design of microchannel surfaces to achieve accurate EOF control in hydrophobic microchannel. Supported by the National Natural Science Foundation of China (Grant No. 50730007)     

干燥、粉碎一体化装置

本文对干燥、粉碎一体化装置的典型设备惰性粒子流化床干燥器进行剖析,介绍应用情况,并作了经济性评价。