边界对齐的平滑三维对称标架场

为了把广泛应用于网格四边形化和纹理合成的二维表面标架场拓展到三维,提出一种生成三维对称标架场的方法.不同于表面对称标架场(四对称方向场),二维标架场的对称性能用一个切平面的旋转角度来表示,而三维对称标架场的对称性却不能这样简单地表示.为了解决这个问题,利用球面函数来获得一个对称性表述,该表述对于绕任意一个轴的π/2旋转以及它们的复合是不变的.基于球面函数的表示可以获得一个有效的标架场光顺程度的度量,并以球面调和分析进行加速计算;基于一组边界约束,可以通过极小化这个度量函数来获得一个光顺的标架场,该标架场在表面上能很好地对齐法线.最后通过表面投影、流线追踪和奇异点来可视化这个标架场,并将这个光顺的标架场用于六面体网格生成,且讨论了它在生成高质量纯六面体网格方面的潜力,其与表面标架场在生成四边形网格方面的潜力是一致的.     

Controllable synthesis of pure monodispersed zirconia nanopowders with tetragonal phase

Nanopowders of pure zirconia have been synthesized using citric acid (CA)-assisted lamellar liquid crystal template method. The microstructure of the zirconia powder prepared at the different mole ratios of CA to zirconium oxynitrate (ZN) was characterized by FT-IR, X-ray diffraction (XRD), laser particle size analyzer, Raman spectroscopy, and scanning electron microscope (SEM) methods. The phase structure of the sodium dodecyl sulfate (SDS)/C₁₀H₂₁OH/H₂O system before and after adding mixing solution CA and ZN was determined by POM (Polarizing Optical Microscope). The results show that lamellar structure of the SDS/C₁₀H₂₁OH/H₂O system after adding mixing solution CA and ZN is stable. The presence of CA inhibits agglomeration and growth of zirconia particle. The crystallite size of zirconia powders decreases and agglomerates lowly with addition of CA. Fourier transform infrared spectrometry (FI-IR) analyses reveal that the structure of chelating organic complex is maintained in zirconia structure at high-temperature calcination to cause oxygen vacancies which stabilizes the tetragonal phase of zirconia. The zirconia powders remained the single metastable tetragonal phase at the molar ratios of CA to ZN ranging from 1:3 to 5:1. The crystallite size of zirconia with spherical morphology varied from 32.2 to 20.1 nm with the increase of the molar ratio of CA to ZN in the range of 1:3 to 5:1.     

DQ型高效催化剂在环管PP装置上的应用

介绍了使用DQ型球形高效催化剂在上海石油化工股份有限公司塑料事业部70kt/a环管连续法工业聚丙烯生产装置上应用研究的结果，并对结果进行了讨论。     

球形氧化锆的湿法制备过程研究

以氯氧化锆和碳酸氢铵为原料，采用连续反应沉淀法制备了微米级球形氧化锆前驱体，此前驱体在500℃下于空气气氛中煅烧2h得到球形氧化锆粉体。探讨了锆盐溶液浓度、加料速度、pH、反应时间对粉体颗粒粒径大小及其分布的影响。经SEN，XRD，TG—DSC和激光粒度测试仪分析，结果表明在最佳工艺条件下制备的氧化锆前驱体颗粒呈球形，分散性好，粒径分布在8—18μm。     

2000m3低温丙烯球罐球壳板型式和材料的选择

大型球罐球壳板型式和材料的选择是设计的首要环节,从这两方面论述了设计时选择的过程。     

聚丙烯球形高效催化剂的工业应用研究

介绍了DQ-2型球形高效催化剂在间歇式液相本体法聚丙烯生产装置上进行工业应用的试验研究，试验证明，该催化剂具有节水、节电、反应平稳且操作时间短等聚合反应特性，催化剂活性平均为42kgPP／(gCat)，一级品率达90％，并与非球型高效催化剂进行了比较。     

Preparation and application of polybenzoxazine adsorption resin

The synthesis and application of polybenzoxazine adsorption resin was studied. First, the precursor was synthesized by the solventless method. And then a kind of spherical and granular polybenzoxazine resin was obtained using reverse‐phase suspension polymerization technique in the process of solidification. Besides, the influence of dispersion medium, the volume ratio of precursor to medium, the solidification temperature, and the agitation speed were studied in detail in the process of polymerization. Second, the spherical shape of the polybenzoxazine resin was identified by scanning electronic microscope and the thermal stability of resin was measured by thermogravimetric analysis. Finally, the adsorption capacity of the spherical resin on pyridine was studied in cyclohexane systems. The correlation coefficient of Langmuir adsorption constant temperature line was bigger than 0.99, which indicated that the equilibrium sorption date was coincident with the Langmuir isotherm equation. And the saturated adsorptive capacity of dried resin achieved 222.2 mg g^?1. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Coding scheme based on spherical polar coordinate for control over packet erasure channel

Like feedback strategy, coding scheme is an important part of networked control system design as well. On the basis of spherical polar coordinate, a novel coding scheme is proposed for stabilization problem of discrete linear time invariant system subject to packet erasure channel with feedback. The coding scheme uses encoder without access to control inputs. In the case that a decoder does not use control inputs, a definite relation between the quantized data and the corresponding quantization error is established, which helps to analyze the stability of system, and a selective quantization method is adopted, by which finite data rate is obtained. In the case that a decoder uses control inputs, instead of quantizing the system state at each time step as usual, the encoder quantizes the initial state all the time by updating quantizer. Sufficient conditions guaranteeing the system stable are presented for two cases, respectively, and the corresponding design methods for coding schemes are given. Copyright © 2012 John Wiley & Sons, Ltd.     

压力敏感性材料球形孔洞动态扩展问题

为进一步研究岩土材料爆炸场的特点,采用椭圆型屈服准则和自相似假设,并结合Hopkins三区模型,研究幂硬化材料球形孔洞动态扩展问题.通过对弹性区的研究得出弹性区应力的分布和弹塑性交界处的连续条件;然后在塑性区给出一个求解动态扩展问题的非线性微分方程组;最后通过打靶法数值求解该非线性微分方程组,给出满足边界条件的数值解,并讨论材料参数对场量的影响.结果表明,椭圆型屈服准则能很好地描述压力敏感性材料中孔洞的动态扩展.