磷酸铁包覆纳米锰酸锂的改性研究

以水热法合成的纳米MnO2为模板,合成了以棒状结构为组成单元的球状LiMn2O4纳米材料,并首次用FePO4对其进行了表面包覆改性。通过XRD、SEM、TEM、EDS等表征手段对材料的结构、形貌及组成元素进行了分析,并测试了材料的电化学性能。结果表明,经过1%(质量分数)FePO4包覆的LiMn2O4材料的电化学性能得到明显改善,在1C下首次放电比容量达128.6mAh/g,循环100次后仍保持97.3mAh/g,容量保持率为75.7%;在0.1C下充电,在0.1C、0.2C、0.5C、1C、2C、3C、4C下连续放电,放电比容量分别可达131.2mAh/g、128.0mAh/g、127.1mAh/g、126.0mAh/g、117.8mAh/g、110.9mAh/g和104.6mAh/g。     

基于响应面方法的支架结构模型修正研究

为减小有限元建模中不可避免的误差,以支架结构模型为研究对象,选取结构不同部件的三个弹性模量和三个密度参数作为设计变量。根据中心复合设计,建立试验样本空间,利用样本参数的显著性分析结果筛选修正参数。结合线性回归方法,建立支架模态频率与修正参数的二阶多项式。以试验模态分析结果为依据,完成支架结构模型修正。响应面方法修正后的模态频率与试验模态频率具有一致性,且避免重复调用有限元模型,大大提高修正效率,具有修正响应快速性和工程实用性。     

Multiobjective optimization and analysis of copper–titanium diboride electrode in EDM of monel 400™ alloy

Electrical discharge machining (EDM) is one of the most accepted machining processes in the precision manufacturing industry. In EDM process, finding an alternative tool material is the demand in modern manufacturing industry. Therefore, an attempt had been made to fabricate copper–titanium diboride powder metallurgy electrode to test in EDM on monel 400? material. The experiments are planned using center composite second-order rotatable design and the model is developed by response surface methodology. The machining characteristics have analyzed using the developed model. In this study, four input parameters such as titanium diboride percentage, pulse current, pulse on time, and flushing pressure are selected to evaluate the material removal rate (MRR) and tool wear rate (TWR). The adequacy of the developed regression model has tested through analysis of variance test. The desirability-based multiobjective optimization is used to find the optimal process parameter which has given maximum MRR and minimum TWR. The optimum process parameters obtained were titanium diboride of 16%, pulse current of 6 A, flushing pressure of 1 Mpa, and pulse on time of 35?µs. The validity of the response surface model is further verified by conducting confirmation experiments.     

On the electro-osmotic flow in a saturated porous medium

Electro-osmosis in a saturated porous rigid medium is studied by both theoretical and experimental approach. Relationships giving liquid and electrical coupled macroscopic flows are obtained from the homogeneization method. They point out possible non symmetrical cross effects that explain deviations from Onsager reciprocal relations. Experiments on a kaolinite are reported which exhibit an important non symmetrical coupling.     

硅烷偶联剂表面接枝包覆纳米SiO2的研究

采用硅烷偶联剂γ-（甲基丙烯酰氧）丙基三甲氧基硅烷（MPS）处理纳米SiO2,并用FT-IR、ζ-电势、TG、TEM对纳米SiO2的处理效果进行了表征.结果表明,纳米SiO2的接枝率随偶联剂MPS加入量的增加而增加;当pH值为4,MPS/SiO2为50%,反应温度为110 ℃、时间为90 min时,纳米SiO2表面MPS的接枝包覆率达到35.7%;此时纳米SiO2粒子在乳液中的分散更为均匀.     

LCD Mura缺陷的B样条曲面拟合背景抑制

针对机器视觉检测TFT-LCD Mura缺陷时存在的图像整体亮度不均匀、背景复杂等影响检测准确性的问题,提出一种基于B样条曲面拟合的背景抑制方法。在最小二乘法准则的约束下,采用双三次B样条曲面拟合算法拟合出背景,并添加光顺项调整拟合精度,用原始图像减去拟合背景,从而消除亮度不均匀背景对缺陷分割造成的影响。为提高算法速度,对原始图像进行分块拟合,并将双三次B样条函数分解为一元函数求解,减小了计算量,同时避免了对原函数求解时容易出现的病态解问题。实验结果表明,该算法准确、高效。     

飞行器RCS计算中曲面剖分技术研究与实现

飞行器RCS预估计算是隐身技术研究中的重要研究内容。论述了利用飞行器外形的特点,在满足飞行器设计误差的前提下使用平面和柱面对飞行器的整机作NURBS曲面逼近,然后用柱面和平面剖分代替曲面的剖分。实现了飞行器整机模型的指定边长的三角剖分。这种方法不同于有限元计算的网格剖分,具有网格单元与曲面曲率无关和剖分速度快等特点。     

低温燃料电池阳极催化剂的研究进展

阳极催化剂是低温燃料电池的关键材料之一,研制新型催化剂对燃料电池的性能及成本起着关键作用。从改变催化剂的组成、分散度及调控催化剂的表面结构3个方面综述了近年来低温燃料电池阳极催化剂的研究进展,并展望了该领域今后的发展方向。