Effect of organic dopants on electrodeposition and characteristics of polyaniline under the varying influence of H2SO4 and HClO4 electrolyte media

Electrodeposition of conducting polyaniline (Pani) was made under potentiostatic condition at pH 1.0 in different electrolyte media (H₂SO₄ and HClO₄) in the absence and presence of two organic dopants, disodium salts of naphthalene-1,5-disulphonic acid (NSA) and of catechol-3,5-disulphonic acid (CSA). The rate and yield of Pani deposition were dependent on the acid medium and the dopant employed. NSA in H₂SO₄ caused an increase in rate and yield but CSA decrease when compared to the rate and yield of H₂SO₄ alone. In HClO₄ medium, both the dopants showed a decrease. With regard to DC electrical conductivity, both the dopants exhibited an enhancement in H₂SO₄ medium but NSA a decline in HClO₄. Characterisation of the electrosynthesised polymer samples by various instrumental techniques (cyclic voltammetric: CV, FTIR, UV-Visible: UV-Vis, EPR, XRD, TGA and DTG methods) revealed that between the two acid media, H₂SO₄ was the better one. Further, it enlightened the role of two organic dopants in relation to the acid media. The advantageous role of NSA in H₂SO₄ had origin on its molecular characteristics such as non-polarity, larger π-electron cloud etc., while CSA could not perform such a role because of its easily oxidisable hydroxyl groups. In HClO₄, however, both the dopants could play only an unfavourable role owing to its greater polarity and oxidizing power than H₂SO₄.     

疲劳/蠕变复合作用下聚苯乙烯的交互损伤研究

探讨了在疲劳／蠕变复合作用下聚苯乙烯的损伤交互作用，结果表明，在疲劳／蠕变复合作用下聚苯乙烯存在疲劳和蠕变的交互损伤，其断裂寿命比纯疲劳或纯蠕变的断裂寿命低；断裂机制是疲劳循环载荷松动和活化了分子链或链段，从而促进蠕变运动和断裂，并且，疲劳／蠕变的交互损伤程度与温度密切相关。     

两栖装甲装备新型防腐材料的研究

沿海地区特殊海洋环境造成装甲装备的严重腐蚀,为了研制一种新型的耐蚀有机涂层,该文作者研究了有机硅改性环氧树脂的化学反应,并对改性树脂的性能进行了测试分析.结果表明,改性树脂克服了环氧树脂的耐温性差、亲水性强以及盐水渗透率高的性能缺陷,为进一步制备该地区装甲装备防腐涂料奠定基础.     

聚氨酯-聚丙烯酸酯共聚乳液的成膜和性能

通过XPS和接触角测试研究了聚氨酯-聚丙烯酸酯共聚乳液在不同基材上的成膜情况，并对共聚胶膜的耐水性和附着力进行了考察．由于该共聚乳液同时存在着亲水组分和疏水组分，所以它在不同的基材上成膜可导致其膜表面的组成成分不同，因而导致其耐水性和附着力也随基材而异。结果表明，亲水性的聚氨酯组分均富集于胶膜内部，但胶膜底层聚氨酯组分的含量却随基材的不同而不同。在憎水且表面张力较高的基材上，共聚胶膜的耐水性良好；共聚胶膜的附着力在表面张力较高的基材上也良好。     

阜新市细河改造工程坝基渗漏计算及处理效果分析

阜新市细河改造工程由四座橡胶坝和两岸防洪大堤组成，由于堤(坝)基第四系冲洪积层广泛发育，存在渗漏同题。合理选择施工处理方案，是工程成功的关键。作者根据场区不同的地质条件环境条件采取有针对性的不同处理方案，既解决了防渗问题又缩短了施工工期，降低工程造价，取得了很好的经济效益和社会效益。     

双自由度后坐保险机构的计算机动态仿真

在Workin Model 3D软件上对引信的双自由度后坐保险机构进行了有关计算机仿真计算，并结合具体实例进行了优化设计。     

闽西南地区推覆构造特征

闽西南地区推覆(滑脱)构造广泛发育,可划分为5种类型:发育于上古生界—中生界下三叠统溪口组中的拆离(滑脱)构造;形成于印支期的拆离(滑脱)构造,后受燕山早期及后期的褶皱作用形成褶皱拆离构造;印支期及燕山早期的中深层次逆冲推覆构造;燕山早期和晚期的浅层次逆冲推覆构造;分布于燕山早期浅层次逆冲推覆构造原地岩系之中的浅层次褶皱逆冲推覆构造,其中燕山早期中深层次逆冲推覆构造规模最大。      

The negated conditional: A litmus test for the suppositional conditional?

Under the suppositional account of conditionals, when people think about a conditional assertion, "if p then q," they engage in a mental simulation in which they imagine p holds and evaluate the probability that q holds under this supposition. One implication of this account is that belief in a conditional equates to conditional probability [P(q/p)]. In this paper, the authors examine a further implication of this analysis with respect to the wide-scope negation of conditional assertions, "it is not the case that if p then q." Under the suppositional account, nothing categorically follows from the negation of a conditional, other than a second conditional, "if p then not-q." In contrast, according to the mental model theory, a negated conditional is consistent only with the determinate state of affairs, p and not-q. In 4 experiments, the authors compare the contrasting predictions that arise from each of these accounts. The findings are consistent with the suppositional theory but are incongruent with the mental model theory of conditionals. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

高校电视台节目漫谈

结合高校校园电视台的职能和特点 ,深刻剖析了高校电视台几种类型节目的特点以及对高校校园文化的作用。     

建筑制图标准中图形符号适宜性、区分性的研究

应用线段长短、间距大小视觉反应的量化规律，提出设计图形符号大小的原则——既更使其大小满足“长”“短”“大”“小”的心理要求，又要互相之间在大小上有区分性。根据图形组织的相似、接近、连续三原则提出设计图形符号形状的原则——图形符号之间尽量减少相似、接近、连续，以保证较好的区分性。通过分析发现，现行建筑制图标准中的图形符号绝大部分在大小和形状具有适宜性、区分性。