尿素醇解法合成氨基甲酸乙酯的研究

对尿素醇解法合成氨基甲酸乙酯工艺进行了系统地研究,全面考察了反应温度、原料配比、反应时间及搅拌速度等因素对反应性能的影响。研究发现在反应温度为140℃,乙醇与尿素的摩尔比为4∶1,反应3.5 h,氨基甲酸乙酯最高收率为79.2%。     

Computer simulation of the filling process in gas‐assisted injection molding based on gas‐penetration modeling

Gas‐assisted injection molding can effectively produce parts free of sink marks in thick sections and free of warpage in long plates. This article concerns the numerical simulation of melt flow and gas penetration during the filling stage in gas‐assisted injection molding. By taking the influence of gas penetration on the melt flow as boundary conditions of the melt‐filling region, a hybrid finite‐element/finite‐difference method similar to conventional‐injection molding simulation was used in the gas‐assisted injection molding‐filling simulation. For gas penetration within the gas channel, an analytical formulation of the gas‐penetration thickness ratio was deduced based on the matching asymptotic expansion method. Finally, an experiment was employed to verify this proposed simulation scheme and gas‐penetration model, by comparing the results of the experiment with the simulation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2377–2384, 2003     

Data-mining based SQL injection attack detection using internal query trees

Detecting SQL injection attacks (SQLIAs) is becoming increasingly important in database-driven web sites. Until now, most of the studies on SQLIA detection have focused on the structured query language (SQL) structure at the application level. Unfortunately, this approach inevitably fails to detect those attacks that use already stored procedure and data within the database system. In this paper, we propose a framework to detect SQLIAs at database level by using SVM classification and various kernel functions. The key issue of SQLIA detection framework is how to represent the internal query tree collected from database log suitable for SVM classification algorithm in order to acquire good performance in detecting SQLIAs. To solve the issue, we first propose a novel method to convert the query tree into an n-dimensional feature vector by using a multi-dimensional sequence as an intermediate representation. The reason that it is difficult to directly convert the query tree into an n-dimensional feature vector is the complexity and variability of the query tree structure. Second, we propose a method to extract the syntactic features, as well as the semantic features when generating feature vector. Third, we propose a method to transform string feature values into numeric feature values, combining multiple statistical models. The combined model maps one string value to one numeric value by containing the multiple characteristic of each string value. In order to demonstrate the feasibility of our proposals in practical environments, we implement the SQLIA detection system based on PostgreSQL, a popular open source database system, and we perform experiments. The experimental results using the internal query trees of PostgreSQL validate that our proposal is effective in detecting SQLIAs, with at least 99.6% of the probability that the probability for malicious queries to be correctly predicted as SQLIA is greater than the probability for normal queries to be incorrectly predicted as SQLIA. Finally, we perform additional experiments to compare our proposal with syntax-focused feature extraction and single statistical model based on feature transformation. The experimental results show that our proposal significantly increases the probability of correctly detecting SQLIAs for various SQL statements, when compared to the previous methods.     

螺旋齿轮塑件注塑模设计

分析了斜齿轮塑件的工艺特性,给出了实用的注塑模结构,介绍了斜齿轮注塑模各系统的结构设计,论述了模具的工作原理。该模具利用定模推出机构和推管旋转脱模机构解决了螺旋齿轮脱模难的问题。模具结构紧凑,推出可靠,安装维修操作方便,成型塑件质量好,生产效率高。     

多点多板多分型面注塑模具的简化设计

应用锁扣装置、组合拉杆结构，减少导柱数量，简化了多点多板多分型面注塑模具的设计。     

前大油田注水系统防腐防垢技术的研究

前大油田注水系统腐蚀、结垢问题十分突出,开发了适用于前大油田注水水质的JYSJ-Q型杀菌剂、JYHZJ-Q型缓蚀阻垢剂,并通过试验确定了配套加药工艺.经现场应用,有效缓解了注水系统的腐蚀结垢问题,获得了显著的社会效益及经济效益.     

按平均收缩率计算注塑模成型尺寸的公式修正

讨论了现用计算公式的缺陷及原因,提出4个修正公式,并举例说明了修正后公式对确定合理的模具公差和保证注塑件顺利生产的重要经济意义。     

注塑用聚氯乙烯干混粉料流变性能的研究

用国产注塑机直接采用聚氯乙烯(PVC)干混粉料注塑硬质聚氯乙烯(RPVC)管件是一个新课题。本文着重介绍在美国哈克(HAAKE)EU-5型转矩流变仪上筛选配方,对PVC干混粉料在加强稳定化、阻止热分解、改善加工性能和实现内外润滑的平衡等方面,进行初步探讨;同时结合生产实践,阐述了干混粉料的制备,机筒模具温度、塑化注塑压力等工艺全过程的控制条件,以及注塑管件在出现缺陷时的解决办法。     

自密封阀在氨汽提尿素装置中的应用与维修

介绍自密封阀的密封原理及其在氨汽提尿素装置中的应用,对其长期运行中出现的泄漏及泄漏原因进行分析,根据不同的泄漏方式分别提出了现场维修的方法.     

汽车用塑料注塑新技术的进展

综述了汽车用塑料的注射成型技术的进展，简单介绍了气体辅助注射成型(GAIM)、水辅助注射成型、熔芯注射成型、反应注射／增强反应注射(RIM／RRIM)成型等技术的特点、生产的汽车部件及最新动向。