工业酚水稀释的RBF神经网络预测控制

针对酚水稀释过程中酚水流量不便测量的工程情况,提出了一种基于RBF（径向基）神经网络的预测控制方法.在酚水罐每个液位变化周期内使用计算机定时测量液位高度,并将这些高度值作为目标输出,在每个循环结束时训练RBF网络,利用RBF网络的逼近能力来实时预测酚水流量,从而控制清水的配比,实现酚水质量浓度的稳定.该方法可避免测量误差带来的干扰,提高控制精度.     

Well-defined polymer precursors synthesized by RAFT polymerization of N,N-dimethylacrylamide/N-acryloxysuccinimide: random and block copolymers

N,N-dimethylacrylamide (DMA) and N-acryloxysuccinimide (NAS) were copolymerized by the reversible addition–fragmentation chain transfer (RAFT) polymerization technique, to obtain random and block copolymer precursors onto which different side-groups may be statistically grafted via the reactive NAS units. These reactive copolymers have interesting applications in various fields such as coatings and paints, water purification and biology. Random poly(DMA-co-NAS) copolymer chains were synthesized with a 75/25 molar ratio, high conversion, an excellent molecular weight (MW) control from 5000 to 130 000 g mol⁻¹, and low polydispersity index (M_w/M_n<1.1). Poly(DMA-b-NAS) block copolymers were synthesized by a two step method, in which a poly(DMA) homopolymer was prepared first and then used as macro-chain transfer agent to polymerize NAS. For example, a poly(DMA-b-NAS) sample was obtained with an average molecular weight of 44 300/7400 g mol⁻¹ corresponding to 447 DMA and 44 NAS units. Such block copolymers had not yet been synthesized by any controlled polymerization technique. They can be used to prepare polymers with exactly the same backbone and an increasing number of different side groups (e.g. hydrophobic, ionic or fluorescent).     

Characterization of konjac glucomannan–quaternized poly(4‐vinyl‐N‐butyl) pyridine blend films and their preservation effect

Novel polymer blends were prepared from a mixture of 2 wt % konjac glucomannan and 4 wt % quaternized poly(4‐vinyl‐N‐butyl) pyridine (QPVP) in aqueous solution and dried at room temperature for 72 h. Their structure and properties were studied by infrared, wide‐angle X‐ray diffraction, scanning electron microscopy, thermogravimetric analysis, and differential scanning calorimetry. Thermal stability in the dry state was reduced with increasing content of QPVP. Compared with QPVP film, the tensile strength of the films was improved in the dry state. The maximum value of 12.74% tensile break elongation was reached when the content of QPVP was 30%. Structural analysis indicated that clear phase separation was observed when the content of QPVP was only 50%. Results from the filmcoating preservation experiments with lychee showed that this blend film had water‐holding ability. The fruit weight loss rate and rot rate both decreased in various degrees. The potential uses of these novel polymer films could be as preservative films. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1868–1875, 2004     

以尿素为氮源的高氮复合肥生产技术

笔者根据多年的实践经验 ,阐述以尿素为氮源 ,生产高氮〔w(N)≥ 2 0 %〕复肥的现实意义及生产技术要点 ,具体介绍 2个高氮复肥 (2 30 7)、(2 0 10 15 )的配方实例及操作要点     

二氰基取代的四硫富瓦烯硫杂冠醚衍生物的合成及性质研究

在甲苯溶液中,在亚磷酸三乙酯存在下,采取高度稀释的方法,使4,5-二氰基-1,3-二硫杂环戊二烯-2-酮分别和多缩硫杂冠醚进行交叉偶联反应,成功地得到了不对称的2,3-二氰基四硫富瓦烯衍生物。用1HNMR、MSI、R和EA表征了其结构,并用循环伏安法研究了它们的电化学性质,用1HNMR初步评价了衍生物对钠离子的配合性能。     

定转子圆度智能测量装置驱动研究

本文讲述了水电站机组定转子圆度测量装置的基本原理和构成,重点阐述圆度测量装置步进电机驱动部分的电路设计及如何使用TILF2407A DSP芯片来设计驱动程序.     

基于扩充的GIX/M/1/N排队系统的主动队列管理算法性能评价模型

为了评价主动队列管理(AQM Active Queue Management)算法的性能,通过在标准的排队系统GIX/M/1/N中嵌入主动队列管理(AQM)算法的方法,建立了一个扩充的GIX/M/1/N排队系统。利用该扩充的GIX/M/1/N排队系统和Internet业务流量自相似性的特征,提出了一种评价AQM算法在非响应业务流量下的性能的分析方法,并据此评价了TD,RED,GRED和Adaptive RED等4个经典的AQM算法。为了验证该分析方法的合理性,利用NS2进行了一系列的仿真实验。结果表明,该分析方法所得结果与仿真实验所得结果一致,因此该分析方法能用于评价AQM算法的性能。     

Invariance properties of RAMS and linear time

An operation on integers isLTTC if it is computable in linear time on a Turing machine (using the dyadic or binary representation of integers). AnLTTC-RAM (respectivelyI-RAM) is a RAM which only uses LTTC operations (respectively operations in the setI).The address-free time complexity measure of a RAM evaluates execution times using the logarithmic cost criterion but assumes that addressing operations are performed for free.     

Prevalence and personality correlates of Facebook bullying among university undergraduates

The purpose of the present study was to examine the prevalence of cyber-bullying through Facebook in a sample of 226 Greek university undergraduates, and to explore whether big five personality characteristics, narcissism, as well as attitudes toward Facebook, technological knowledge and skills were predictive of such behavior. Participants completed a self-report questionnaire measuring the above constructs. Results indicated that almost one third of the sample reported Facebook bullying engagement at least once during the past month, with male students reporting more frequent involvement than females. Bullying through Facebook was predicted by low Agreeableness and more time spent on Facebook only for males, whereas for females none of the studied variables predicted engagement in Facebook bullying. Findings are discussed in terms of prevention and intervention strategies.     

Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes

Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N,N-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed.