自然光下溴氨酸光催化降解试验研究

采用溶胶-凝胶法制备CdS/TiO2复合型光催化剂,并以溴氨酸为降解对象,在太阳光下研究其降解性能,从色度、COD、TOC等不同角度对降解结果进行检测.结果表明：在太阳光下CdS/TiO2能够有效降解溴氨酸废水,CdS/TiO2的最佳比例为0.2∶1;反应中催化剂的最佳用量为2.0 g/L;溴氨酸光催化降解遵循表观一级动力学反应.在对某实际染料废水的降解中,色度和COD的最大去除率分别为94.71%和58.02%.     

浙东沿海13座一线水闸混凝土结构的老化现状分析及启示

通过浙东沿海13座一线水闸混凝土结构老化现状的调查分析,对影响混凝土耐久性的主要因素进行了分析汇总.混凝土保护层破裂剥落导致钢筋锈蚀,是结构老化的最常见表现.改善混凝土材料自身耐久性和保证工程施工质量,是提高结构耐久性的根本性措施.按耐久性设计混凝土配合比,应当成为今后混凝土科学发展的重要方向.     

再生混凝土密肋复合墙体受力性能试验研究

对3榀1∶2比例模型,再生骨料取代率分别为100%、50%和0%的密肋复合墙体的力学性能进行对比试验.研究了再生混凝土密肋复合墙体的破坏机制、承载力、延性、刚度退化等性能.研究发现:墙体属于剪切破坏;最大水平承载力,50%取代率的墙体和普通混凝土墙体相比没有下降,而100%取代率墙体承载力下降18%;延性系数,随着取代率的增加而提高.试验表明:50%取代率密肋复合墙体具有良好的力学性能,应用于实际工程完全可行;而100%取代率墙体需慎用.     

Enhancing thermal and dynamic-mechanical properties of epoxy reinforced by amino-functionalized microcrystalline cellulose

In this study, microcrystalline cellulose (MCC) was chemically modified with 3-(aminopropyl)triethoxysilane and added to epoxy to improve chemical, thermal and dynamic-mechanical characteristics of the composites. The composites were manufactured aided by sonication with 1.0%, 2.5%, or 5.0% wt/wt of untreated MCC or amino-functionalized MCC (MCC-Si). The epoxy/MCC-Si composites showed a decrease in the ─OH band by Fourier-transform infrared spectroscopy, and X-ray diffraction analysis indicated better dispersion. The incorporation of MCC-Si in epoxy resin decreased the heat of reaction, increased activation energy values (E_a) and pre-exponential factor (A), and did not affect thermal degradation. All conversion degree (α) versus temperature curves for the composites showed a sigmoidal shape. MCC-Si composites showed better dynamic-mechanical properties than the MCC counterparts, and the functionalization effect was evidenced in storage modulus (E') and loss modulus (E"). At 2.5% wt/wt of MCC-Si content an increase of 119% in E' at the glassy region, 127% in E' at the rubbery region and 173% in E" was observed compared to the neat resin, whereas the T_g barely changed among samples. Good adhesion between the amino-functionalized MCC and the epoxy matrix was observed at the fracture surface, evidencing that surface modification of MCC improves their chemical interaction.     

光催化氧化法降解有机污染物影响因素及其效率提高途径

分析了催化剂类型、污染物性质、反应条件等因素对光催化氧化法降解有机污染物的影响,从催化剂改性、高效光催化氧化反应器及光催化与其他技术联用等方面探讨了提高光催化氧化效率的途径,展望了光催化氧化法发展前景及其工业化应用时需解决的关键问题。     

超声波技术在农药残留研究中的应用

从超声波萃取和超声波降解两方面，综述了近几年国内外超声波技术在农药残留研究中的应用及研究现状。     

Thermogravimetric analysis of methyl methacrylate‐graft‐natural rubber

The thermal degradations of methyl methacrylate‐graft‐natural rubber (MG) at different heating rates (B) in nitrogen were studied by thermogravimetric analysis. The results indicate that the thermal degradation of MG in nitrogen is a one‐step reaction. The degradation temperatures increase along with the increment of heating rates. The temperature of initial degradation (T₀) is 0.448B + 362.4°C, the temperature at maximum degradation rate, that is, the peak temperature on a differential thermogravimetric curve (T_p) is 0.545B + 380.7°C, and the temperature of final degradation (T_f) is 0.476B + 409.4°C. The degradation rate at T_p is not affected by B, and its average value is 48.9%; the degradation rate at T_f is not affected by B either, and its average value is 99.3%. The reaction order (n) is 2.1 and is not affected by B. The reaction activation energy (E) and the frequency factor (A) increase along with B, and the apparent reaction activation energy (E₀) is 254.6 kJ/mol. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2952–2955, 2002     

磺酰脲类除草剂的微生物降解

微生物降解是磺酰脲类除草剂降解的重要途径之一。笔者对磺酰脲类除草剂微生物降解途径及影响微生物降解的因素进行了分析，对磺酰脲类除草剂微生物降解的研究现状做了简要综述，提出了微生物降解领域的发展趋势和有待解决的问题。     

Applications of rheological torque–time curves to the study of thermooxidative degradation of polypropylene powder

The torque–time curves of polypropylene (PP) powder treated under various thermooxidative degradation conditions were obtained through processing in the mixing chamber of a rheometer. Meanwhile, the Fourier transform infrared (FTIR) spectra of the corresponding samples were determined, and the quantitative analysis of the carbonyl indices of the FTIR spectra of the samples of the PP powder was carried out to provide evidence for the rheological characterization. PP granules, to which an antideteriorant was added before they were commercially supplied so good antidegradation could be achieved, was investigated for the sake of contrast. The analysis of the experimental results showed that the height of the torque–time curve of the PP powder and the corresponding value of the equilibrium torque could be used to characterize or evaluate the variations of the thermooxidative degradation of the PP powder. Under the same processing conditions, the heights of the torque–time curves of the PP powder and the corresponding values of the equilibrium torque decreased with the enhancement of the thermooxidative degradation treatment before mixing; on the contrary, the heights and areas of the characteristic bands of the carbonyl groups in the FTIR spectra of the PP powder and the corresponding values of the carbonyl index increased. The quantitative analysis of the FTIR spectra provided evidence for the conclusion that the heights of the torque–time curves of the PP powder and the corresponding values of the equilibrium torque could be used to characterize or evaluate the thermooxidative degradation of the PP powder. If the treatment under thermooxidative degradation conditions weakened or the degradation of the PP powder just began (i.e., in the viscosity range for processability), the evaluation method using the heights of the torque–time curves of the PP powder or the corresponding values of the equilibrium torque could provide more sensitivity than the method using the values of the carbonyl index. Consequently, the method using the heights of the torque–time curves to evaluate the thermooxidative degradation of the PP powder had its advantages. The application of the torque–time curves could be used to evaluate not only the variation of the thermooxidative degradation of the PP powder treated under aging conditions before mixing but also the variation of the degradation, including the mechanochemical degradation, of the PP powder during the period of mixing. The dependence of the variation of the degradation of the polymer on the processing time during mixing could be evaluated by the study of the variation of the torque–time curves. It can be concluded that the application of torque–time curves to the evaluation of degradation of PP powder has the advantages of being convenient, real‐time, in situ, online, and production‐oriented. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

考虑多因素作用下的RC梁抗力时空退化模型

为研究钢筋混凝土结构锈蚀后的力学性能和抗力退化规律,基于RC梁加速锈蚀试验结果,首先综合考虑均匀锈蚀和点蚀同时发生的影响,对钢筋截面面积的时变模型进行分析,其次探讨裂缝宽度与氯离子扩散系数及RC梁抗力的关系,随后考虑受拉主筋锈蚀不均衡的影响,对结构抗力计算模型进行讨论,最后基于材料性能和结构尺寸的空间变异性,建立RC梁抗力时空退化模型,并对桥梁服役100 a后的抗力进行预测.研究发现:当考虑各参数的空间变异性时,不考虑裂缝影响得到的抗力值比考虑裂缝影响得到的抗力值高了9.91%;考虑各参数空间变异性时的抗力值比不考虑时下降了14.68%;适当的选取波动系数和单元尺寸对考虑结构各参数的空间变异性十分重要;潮汐区和浪溅区环境下结构的剩余抗力分别为初始抗力的43.23%和36.45%,较海岸线大气区环境下的抗力值分别下降了6.73%和21.35%,因此在结构服役期间,应尽量做好防腐措施,减少氯离子侵蚀对结构耐久性的破坏.