羧基化高纯单壁碳纳米管修饰电极对乙酰甲喹的高灵敏检测

采用羧基化高纯单壁碳纳米管(c SWCNTs)固载于金电极表面来构筑乙酰甲喹电化学传感器。运用循环伏安法(CV)、差分脉冲伏安法(DPV)和电化学交流阻抗法(EIS)测定传感器的性能。结果显示,该传感器对乙酰甲喹的电化学还原具有显著的催化性能,修饰电极的峰电流达到-128.40μA,是裸电极峰电流的1167倍。通过对传感器性能影响因素的考察,得到最优制备条件为cSWCNTs涂覆量为4μL(质量分数0.10%分散液),搅拌速度1000 r/min,pH=7.0的PBS浓度为0.2 mol/L,-0.5V电压下富集30 min。在该条件下制备的传感器峰电流与乙酰甲喹在1～500nmol/L范围内呈良好的线性关系,相关系数为0.998,方法的检出限为0.76nmol/L。该传感器被成功地应用于实际样品检测,加标回收率在81.7%～124.0%。     

A novel method for camera external parameters online calibration using dotted road line

On board camera is the most important information source for driver assistant application which is based on computer vision. One problem for on board camera is that the external parameters are easy to be changed when moving on the road. Traditional method either calibrates external parameters offline or calibrates external parameters semi-online, which both need human intervention. By observation, it is found that corner connection of dotted road lane can form two groups of parallel lines. Using this geometric characteristics and through theoretical derivation, a novel online camera external parameter calibration method is proposed which focus on the situation when vehicle is moving. The pro of this method is that it maintains relatively high calculation accuracy and more important, it does not require any human intervention in whole calibration process. Experimental and comparison results show that this method is simple and have accurate results which fully meet the requirements of practical application.     

A virtual actuator and sensor approach for fault tolerant control of LPV systems

In this paper, a fault tolerant control (FTC) strategy using virtual actuators and sensors for linear parameter varying (LPV) systems is proposed. The main idea of this FTC method, initially developed for LTI systems, is to reconfigure the control loop such that the nominal controller could still be used without need of retuning it. The plant with the faulty actuator/sensor is modified adding the virtual actuator/sensor block that masks the actuator/sensor fault. The suggested technique is an active FTC strategy that reconfigures the virtual actuator/sensor on-line taking into account faults and operating point changes. The stability of the reconfigured control loop is guaranteed if the faulty plant is stabilizable/detectable. The LPV virtual actuator/sensor is designed using polytopic LPV techniques and linear matrix inequalities (LMIs). A two-tank system simulator is used to assess the performance of the proposed method. In particular, it is shown that the application of the proposed technique results in an improvement, in terms of performance, with respect to the LTI counterpart.     

Development of a variable selection method for soft sensor using artificial neural network and nonnegative garrote

This paper developed a new variable selection method for soft sensor applications using the nonnegative garrote (NNG) and artificial neural network (ANN). The proposed method employs the ANN to generate a well-trained network, and then uses the NNG to conduct the accurate shrinkage of input weights of the ANN. This paper took Bayesian information criterion as the model evaluation criterion, and the optimal garrote parameter s was determined by v-fold cross-validation. The performance of the proposed algorithm was compared to existing state-of-art variable selection methods. Two artificial dataset examples and a real industrial application for air separation process were applied to demonstrate the performance of the methods. The experimental results showed that the proposed method presented better model accuracy with fewer variables selected, compared to other state-of-art methods.     

IMAGING OF PARTICLE MOTION IN FLUID-SOLID SYSTEMS USING A GAMMA CAMERA

A new approach is presented for the characterization of particle motion in fluid-solid systems based on dynamic imaging with a gamma scintillation camera. A two-dimensional spouted bed of 200-500 micron diameter anion exchange resin beads was used as a test system. One or several beads were radiolabeled with the 140 keV gamma emitting radionuclide 99m-Tc pertechnetate, and particle velocity, panicle path, the spatial distribution of particle residence times, and local bed density were determined from the measured temporal and spatial distributions of particle activity. While care must be exercised in the interpretation of data when the scale for changes in the spatial distribution of activity approaches the limits of camera resolution, the method is quantitative, non-invasive, and well suited to the study of systems having symmetry in one spatial dimension.     

无线传感器网络连通恢复综述

针对无线传感器网络中连通恢复问题,分析和总结了近年来相关的主要方向和研究成果,同时对无线传感器网络连通恢复解决方法进行了分类和总结,并指出了其中的不足与未来的研究方向。     

带速度控制的能量高效的数据收集算法

无线传感网络中, 在保证节点能耗较低, 从而延长网络寿命的基础上, 减小数据收集时延是数据收集的核心问题。为此, 提出了一种带速度控制的能量高效的移动数据收集方法。该方法首先基于节点剩余能量进行动态分簇, 每个簇形成两个簇头来分担簇头能耗; 然后给小车装载双天线, 使得节点能够MIMO数据上传; 最后利用TSP问题找到一条最优路径, 并对移动小车的速度进行控制, 以便小车能够更快地收集数据。仿真实验结果表明, 该方法能够均衡网络流量, 延长网络寿命; 与其他算法相比, 数据收集时延较短。     

基于无线传感网的智能环境监控系统设计

针对传统环境监控系统存在的缺点,设计了一种新型无线传感器网络的环境监控系统。系统采用分布式融合结构,通过终端节点的多种传感器采集环境信息,终端对信息预处理后实时将信息传输到协调器。协调器融合各终端传感器信息,提取精确信息上传至融合中心,融合中心通过分析数据发布命令给控制中心,控制中心利用单片机驱动电机可以自动或手动控制风机和水泵对环境进行调节和控制。同时,系统还具有自动预警功能。通过验证,该系统稳定、可靠,能广泛应用于不同领域的分布式多点环境监控。     

汽车胎压监测系统的设计及其通信抗干扰研究

针对大多数直接式汽车胎压监测系统组件集成度低、体积和功耗较大等问题,提出了一种基于短距离无线通信ZigBee技术的新型胎压无线监测系统的设计。主要采用TI的CC2530芯片和英飞凌SP12集成式数字传感器,实现对汽车轮胎内部状态的实时监测。采用软硬件协同设计以降低系统功耗,并通过多点轮询通信方式和ZigBee高级加密设置保障了其无线通信的抗干扰能力。     

硅压阻式气压高度计的设计与实现

采用硅压阻式压力传感器,以ATmega88PA为控制器设计了气压高度计。内嵌全温度范围的曲面拟合算法进行温度补偿及线性化处理,解决了压力传感器的温漂和非线性问题,并用海拔高度与气压的关系计算高度。测量结果通过RS-485接口发送给上位机。测试结果表明,该气压高度计压力测量误差优于0.50‰,分辨率为0.01 h Pa,线性度为0.999 9;标准大气环境下高度测量误差为0.16 m,线性度为0.999 8。该气压高度计具有质量小、功耗低、精度高、工作可靠等优点。