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91.
92.
In this study,a comprehensive investigation on different cluster configurations of the ~9Be nucleus is performed with a simple cluster approach.With this goal,the elastic scattering angular distributions of ~9Be by ~(27)A1,~(28)Si,~(64)Zn,~(144)Sm,~(208)Pb,and ~(209)Bi target nuclei are reanalyzed for α + α + n,d + ~7Li,~3H + ~6Li,~3He + ~6He and n + ~8Be cluster configurations of the ~9Be projectile within the framework of the optical model.The theoretical results are compared with each other as well as the experimental data.The results provide an opportunity for a test of different cluster configurations in explaining the elastic scattering of~9Be nucleus. 相似文献
93.
C.A. González-Rugerio R. Fuhrmeister D. Sudhoff J. Pilarczyk A. Górak 《Chemical Engineering Research and Design》2014
The design of catalytic distillation (CD) columns is a challenging task because of the superposition of chemical reaction and distillation in one apparatus. In this work, a method to design a cost-optimal CD column for chemical systems with large number of components and chemical reactions is presented. The method is based on the following steps: (1) estimation of the number of theoretical stages and catalyst volume by the decomposition of the CD column into a sequence of chemical reactors and non-reactive distillation columns, (2) estimation of the column diameter and operating conditions using an equilibrium stage model, and (3) design of the column applying an optimisation algorithm and using a rigorous non-equilibrium stage model to represent the CD process. The method is applied to determine the optimal column configuration and operating conditions for the synthesis of tert-amyl ethyl ether from ethanol and isoamylenes. Eight components and four chemical reactions were selected to represent the chemical system in the simulations. 相似文献
94.
Simulations of biological macromolecules have evolved tremendously since the discoveries of the 1970s. The field has moved from simple simulations in vacuo on picosecond scales to milliseconds of accurate sampling of large proteins, and it has become a standard tool in biochemistry and biophysics, rather than a dedicated theoretical one. This is partly due to increasing computational power, but it would not have been possible without huge research efforts invested in new algorithms and software. Here, we illustrate some of this development, both past and future challenges, and in particular, discuss how the recent introduction of modern ensemble methods is breaking the trend of ever-longer simulations to instead focus on throughput and sampling. This has not only helped simulations become much more accurate, but it provides statistical error estimates, which are critical, as simulations are increasingly used to predict properties that have not yet been measured experimentally. 相似文献
95.
《Journal of Industrial and Engineering Chemistry》2014,20(5):2830-2839
β-Cyclodextrin (CD) was grafted onto montmorillonite/iron oxides to prepare a novel magnetic CD/MMT/iron oxide composite by low-temperature plasma technology, and applied to remove U(VI) from aqueous solutions. The sorption irreversibility was attributed to inner-sphere binding of U(VI) on CD/MMT/iron oxide surface sites. The thermodynamic parameters indicated that the sorption of U(VI) on CD/MMT/iron oxide was an endothermic and spontaneous process. The maximum sorption capacity of U(VI) on CD/MMT/iron oxide was considerably higher than that of U(VI) on other reported materials. The CD/MMT/iron oxide can be potentially used as a cost-effective material for the purification of actual U(VI)-bearing effluents. 相似文献
96.
Untersuchungen zur Dauerfestigkeit carbonitrierter Proben aus den Einsatzstählen 18CrNiMo7‐6und 20MnCr5
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C. Stöberl H. Bomas B. Clausen F. Hoffmann H.‐W. Zoch 《Materialwissenschaft und Werkstofftechnik》2015,46(6):533-549
The endurance limit of carbonitrided specimens of 18CrNiMo7‐6 and 20MnCr5 case hardening steels were examined under bending conditions. Four variants were manufactured differing in heat treatment and surface conditions. Besides conventional gas carburised variants, carbonitrided specimens with a low and a raised nitrogen content of 0.2 and 0.45% at the surface as well as a carbonitrided and ground variant were examined. The specimens were tested with stress ratios R = –1 and 0. Depending on the nitrogen content cyclic loading evokes compressive residual stresses at the specimens' surfaces, caused by elastic‐plastic deformation. Specimens of the ground variant show additionally a decrease of the residual austenite content when cycled. The induced compressive residual stresses are substantially responsible for high endurance limits at both stress ratios and are the key for understanding the beneficial effect of carbonitriding in this regard. 相似文献
97.
针对折叠翼飞行器发射离筒瞬间姿态变化及折叠翼机构展开性能问题,对影响飞行器离筒性能的主要因素进行了研究,对飞行器离筒过程进行了受力分析,分析了影响飞行器离筒性能的主要因素,建立了飞行器离筒过程理论模型和ADAMS仿真模型,对飞行器离筒过程中低头角变化、离筒时间、离筒速度、离筒最大应力、折叠翼机构展开时间和折叠翼展开同步性等参数进行了计算;对比分析了两种方法所得计算结果;分析了发射角对飞行器离筒过程中低头角和接触力的影响。研究结果表明,两种计算方法计算结果误差在5%以内,可以相互验证;水平发射时飞行器离筒低头角为0.49°、离筒时间为163 ms、离筒速度为14.12 m/s;随着发射角的增加飞行器离筒低头角减小,离筒过程最大冲击力减小;计算结果为飞行器发射性能提供了理论依据。 相似文献
98.
99.
The last decade has seen a growing interest in hybrid electrically conducting nanocomposites. This article aims to provide a detailed overview of the present status of research in carbon nanotube–polyaniline (CNT/PANI) composites, from processing to structural and property evaluations. CNT/PANI are synthesized by electrochemical and chemical processing. When chemical methods are used, the main challenge is to obtain processable CNT/PANI in the emeraldine salt (ES) form composites. Stable dispersions of ES–CNT in organic media are prepared using the post doping method, inverse emulsion polymerization, or ex situ polymerizations. On the contrary, stable water dispersions of CNT/ES are prepared using hydrophilization of a preformed CNT/ES composite, direct synthesis of micelle–CNT hybrid templates, interfacial polymerization, covalent functionalization of CNT with a water soluble polymer, or using electrostatic interactions between two oppositely charged ES and CNT aqueous colloids. Moreover, the strategies for the synthesis of ternary CNT/PANI composites incorporating noble metal nanoparticles, metal oxide, or graphene sheets are also presented and analyzed in depth. Finally, we give a review of potential applications, including chemical sensors, capacitors, fuel cells and electronic devices. 相似文献
100.
Luis Gonzlez-Osuna Alfredo Sierra-Cristancho Emilio A. Cafferata Samanta Melgar-Rodríguez Carolina Rojas Paola Carvajal Cristian Cortez Rolando Vernal 《International journal of molecular sciences》2022,23(5)
Senescent cells express a senescence-associated secretory phenotype (SASP) with a pro-inflammatory bias, which contributes to the chronicity of inflammation. During chronic inflammatory diseases, infiltrating CD4+ T lymphocytes can undergo cellular senescence and arrest the surface expression of CD28, have a response biased towards T-helper type-17 (Th17) of immunity, and show a remarkable ability to induce osteoclastogenesis. As a cellular counterpart, T regulatory lymphocytes (Tregs) can also undergo cellular senescence, and CD28− Tregs are able to express an SASP secretome, thus severely altering their immunosuppressive capacities. During periodontitis, the persistent microbial challenge and chronic inflammation favor the induction of cellular senescence. Therefore, senescence of Th17 and Treg lymphocytes could contribute to Th17/Treg imbalance and favor the tooth-supporting alveolar bone loss characteristic of the disease. In the present review, we describe the concept of cellular senescence; particularly, the one produced during chronic inflammation and persistent microbial antigen challenge. In addition, we detail the different markers used to identify senescent cells, proposing those specific to senescent T lymphocytes that can be used for periodontal research purposes. Finally, we discuss the existing literature that allows us to suggest the potential pathogenic role of senescent CD4+CD28− T lymphocytes in periodontitis. 相似文献