冷轧机板形控制系统弯辊力预设定模型开发

针对某公司六辊冷轧机,采用影响函数法建立了辊系变形计算模型并开发了相应的计算程序。利用所建辊系变形模型结合轧机的板形控制策略,建立了针对轧机的理论和在线两种弯辊力预设定模型。实例计算表明,所开发模型精度符合实际要求,可用于生产实际,为提高轧机板形控制预设定精度,改善轧机产品的板形质量提供了理论依据。     

Thermal Interaction between Permafrost and the Qinghai-Tibet Railway

Measures were taken to protect the thermal regime of the roadbed embankment after construction and to lower permafrost temperatures in the rich-ice and warm permafrost regions along the Qinghai-Xizang Railway. However, these measures were taken only for some sections of the railway, leaving many sections unprotected. This article addresses those areas where no measures were taken and presents analysis of the variation of soil temperatures under the embankment in seasonal frozen soil areas, degrading permafrost areas, and warm and cold permafrost areas. The results show that soil temperatures, maximum seasonal freezing depth, and the permafrost table under the embankment differ according to the different frozen soil areas after embankment construction. In seasonal frozen soil areas and degraded permafrost areas, the seasonal frost layer remained frozen the next year under the shaded shoulder of the embankment. In degrading permafrost areas, a thaw layer between the permafrost table and the bottom of the seasonal frost formed under the embankment. In warm permafrost areas, the permafrost table under the embankment was unstable and soil temperatures near the permafrost table showed an obvious increasing trend. In cold permafrost areas, the permafrost table under the embankment was clearly raised and temperature lowered in the soil near the permafrost table, which is advantageous to permafrost thermal stability under the embankment. In particular, the differ-ence in solar radiation from the slope exposed to the sun to the shady slope of the embankment is responsible for the difference in the soil thermal regime and the permafrost table, which potentially can affect roadbed stability.     

Nano-to-macroporous TiO2 (anatase) by cold sintering process

Cold Sintering Process (CSP) was applied on commercial nanopowders to produce nanostructured TiO₂ anatase with nano-to-macro porosity. Nanoporous TiO₂ based materials were obtained by applying CSP at 150 °C and pressures up to 500 MPa on three TiO₂ nanopowders with different specific surface area (s.s.a. = 50, 90 and 370 m²/g), using water as transient aqueous environment. Although TiO₂ is insoluble in water, a density of 68% and s.s.a. = 117 m²/g were achieved from the powder with the highest specific surface area. A post annealing process at 500 °C increased the density up to 73% with a s.s.a. = 59 m²/g, and the crystallites dimensions passed from 110 Å in the powder to 130 Å in CSP material and 172 Å after post annealing. Finally, macroporosity was produced by using thermoplastic polymer beads as sacrificial templates within TiO₂ nanopowder during CSP, followed by a debonding at 500 °C.     

Effects of ambient temperature on firing behavior and unregulated emissions of spark-ignition methanol and liquefied petroleum gas/methanol engines during cold start

The effects of the ambient temperature on the firing behavior and the unregulated emissions (formaldehyde and unburned methanol emissions) of electronically controlled inlet port injection spark-ignition methanol and liquefied petroleum gas (LPG)/methanol engines during the cold start were investigated experimentally by means of a single-cycle fuel injection strategy. The test results indicated that the minimum amount of methanol injected per cycle to ensure the methanol engine reliable firing increases 86% with the reduction of the ambient temperature from 301 to 289 K. With the ambient temperature below 289 K, the methanol engine cannot be started reliably without the other assistant measures even with a large methanol injection. The LPG only played a part of start-aids in the LPG/methanol engine. Using additional LPG injected into the inlet port results in a reliable firing of the LPG/methanol engine at low ambient temperature during cold start. When the ambient temperature drops, the mass ratio of injected LPG/methanol for the reliable firing of the LPG/methanol engine during cold start increases rapidly. The maximum combustion pressure in the cylinder, the maximum instantaneous engine speed, and the formaldehyde emissions increase significantly and the unburned methanol decreases obviously with the rise of the ambient temperature.     

Hexafluorozirconic acid based surface pretreatments: Characterization and performance assessment

A new phosphate-free pretreatment from Henkel Corp. named TecTalis^®, was investigated. The treatment bath is composed of dilute hexafluorozirconic acid with small quantities of non-hazardous components containing Si and Cu. The corrosion resistance of treated steel was compared to samples treated in a phosphate conversion coating bath, in simple hexafluorozirconic acid and in TecTalis without the addition of the Cu-containing component. Atomic Force Microscopy (AFM) and Transmission Electron Microscopy (TEM) were used to characterize the coating surface morphology, structure and composition. A Quartz Crystal Microbalance (QCM) was used for studying film growth kinetics on thin films of pure Fe, Al and Zn. Electrochemical Impedance Spectroscopy (EIS) was performed on treated and painted steel for studying long-term corrosion performance of the coatings. The phosphate-free coating provided long-term corrosion performance comparable to that of phosphate conversion coatings. The coatings uniformly cover the surface in the form of 10–20 nm sized nodules and clusters of these features up to 500 nm in size. The coatings are usually about 20–30 nm thick and are mostly composed of Zr and O with enrichment of copper at randomly distributed locations and clusters.     

Preparation of presintered zirconia blocks for dental restorations through colloidal dispersion and cold isostatic pressing

This work proposes an effective method for dispersion of zirconia suspension for dental block preparation and optimizes the cold isostatic pressing (CIP) pressure to improve the densification of slip-casted zirconia blocks. Two batches of 44 wt% zirconia suspension were prepared using distilled water in a pH 2 medium containing 0.5 wt% polyethyleneimine as dispersant. The first batch was sonicated for different durations (from 5 min to 30 min), and the second batch was dispersed through ball milling at rotational speeds of 200, 300, and 400 rpm for 60, 90, and 120 min. All suspensions were subjected to sedimentation test and particle size measurement. Results revealed that the optimum ultrasonication duration was 10 min, which yielded the smallest particle size of 133 nm. Ball milling at 300 rpm for 120 min achieved the maximum dispersion of particles, with an average size of 75 nm. Under the optimum conditions of ultrasonication duration, ball milling duration, and ball milling speed, the particle size decreased to 48 nm, which is close to the primary particle size. These dispersion techniques and parameters were selected for preparing a suspension to be consolidated into blocks through slip casting and were enhanced through CIP at pressure ranging from 100 MPa to 300 MPa. CIP compaction at 250 MPa significantly increased the shrinkage percentage of green zirconia blocks, with pore radius decreased to 18 nm. The density of zirconia pressed at 250 MPa and presintered at a low temperature of 950 °C was 59% of the theoretical density and was higher than that of commercial presintered blocks. Thus, CIP should be conducted under a compaction pressure of 250 MPa to produce dense and homogeneous zirconia blocks.     

氧漂稳定剂与冷轧堆

本文对印染前处理工艺中的过氧化氢漂白稳定剂,分为含硅酸盐、非硅酸盐及冷轧堆等三种情况作了详细的总结与讨论。简单介绍了冷轧堆工艺、氧漂稳定剂的稳定机理与常用螯合剂。为读者提供了五十六篇文献资料及一些有益的工艺配方。     

Experimental based full process simulation of alumina selective laser processed parts densified by cold isostatic pressing and solid state sintering

The compound process of cold isostatic pressing (CIP) of alumina selective laser processed (SLP) parts and solid state sintering (SSS) and its full process simulation were realized in this paper, focusing on studying the overall deformation, relative density distribution, grain growth and sintering stress variation during the process. Especially, correlation was established between the macroscopic deformation and microscopic evolution. Model parameters for alumina are presented, which were optimized in accordance with the experimental results. CIPed part still exhibited density inhomogeneity, of which SSS tended to increase the overall density and homogenize density distribution. The sintering behavior was studied with the employment of dilatometer experiments. Furthermore, compared with conventional heating strategy, fast firing turned out to decrease sintering production time as well as drive the matter diffusion and densification process. The master sintering curve (MSC) moves upward a little under the condition of fast firing.     

Automated and Continuous Production of Microstructured Metallic Plates via Cold Embossing

Many critical issues need to be addressed when microstructured reactors are manufactured in large unit volumes. The most crucial of these are cost, ease of production, and reliability. The lack of breakthrough manufacturing technology to provide high‐efficiency, low‐cost, high‐precision plates is a hindrance to the early market implementation of systems requiring metallic microstructured plates. This contribution focuses on the development and optimization of a combined embossing and bending tool for the quick and continuous manufacture of easily machined plates.