Effect of External Recycle and Double-Pass Barrier Location on Membrane Extraction in Cross-Flow Modules

Abstract

The dispersion free membrane extraction through a cross-flow rectangular membrane module with arbitrary location of an impermeable plate placed for double-pass and external-recycle operations in raffinate phase, has been investigated. Theoretical treatment was analogous to the heat transfer in heat exchangers for the mass transfer in mass exchangers. An experiment was carried out in a cross-flow conduit of stainless steel inserted with a membrane sheet made of microporous polypropylene to extract acetic acid from aqueous solution by methyl iso-butyl ketone. Theoretical predictions are in agreement with the experimental results. Considerable improvement in mass-transfer performance is obtainable if the width of the first-pass subchannel, ΔB decreases, as well as the width of the second-pass subchannel, (1?Δ)B increases. The mass-transfer rate increases also when the reflux ratio increases. Based on the economic point of view, the suitable value of Δ (B is the width of a membrane sheet) may be 0.2.     

综放工作面过小窑破坏区浅析

阐述了新阳煤业207工作面由于小窑破坏,材料巷、运输巷不同程度的受空巷影响,导致回采推进速度减慢,给正常生产带来不良影响。分析了工作面现场实际条件及作业中出现的问题,总结了综采工作面过空巷的经验,提出了应对措施,应用效果良好。     

Quantitative cross impact analysis with latent semantic indexing

Cross impact analysis (CIA) consists of a set of related methodologies that predict the occurrence probability of a specific event and that also predict the conditional probability of a first event given a second event. The conditional probability can be interpreted as the impact of the second event on the first. Most of the CIA methodologies are qualitative that means the occurrence and conditional probabilities are calculated based on estimations of human experts. In recent years, an increased number of quantitative methodologies can be seen that use a large number of data from databases and the internet. Nearly 80% of all data available in the internet are textual information and thus, knowledge structure based approaches on textual information for calculating the conditional probabilities are proposed in literature. In contrast to related methodologies, this work proposes a new quantitative CIA methodology to predict the conditional probability based on the semantic structure of given textual information. Latent semantic indexing is used to identify the hidden semantic patterns standing behind an event and to calculate the impact of the patterns on other semantic textual patterns representing a different event. This enables to calculate the conditional probabilities semantically. A case study shows that this semantic approach can be used to predict the conditional probability of a technology on a different technology.     

Critical heat flux and mass loss rate for extinction of flaming combustion of timber

The critical mass loss rate and critical heat flux for self-extinction of flaming combustion during steady-state burning of timber was measured in this study for a range of timber species. A vertical mass loss calorimeter was used to provide the external heat flux and to measure the mass loss of the timber samples. The results showed that the critical mass loss rate was dependent upon the timber species but did not show a clear dependency with the timber density. Critical mass loss rates and heat fluxes for self-extinction exist for each of the timber species tested for both the solid timber and cross laminated timber (CLT). Debonding of both the char layer and the individual lamella of the CLT caused increased mass loss rates, re-ignition after self-extinction and increased flame lengths. Both char and ply fall-off were observed.     

Performance of PAM/PEI gel system for water shut‐off in high temperature reservoirs: Laboratory study

A polymer gel is one of the common remediate methods to either reduce or totally block excessive water production in oilfields. Some systems demonstrated an excellent performance in treating the problem like polyacrylamide tert‐butyl acrylate (PAtBA)/polyethylenimine (PEI). In this study, polyacrylamide (PAM) was introduced as a cheap alternative to PAtBA that can tolerate high salinity reservoirs. The thermal stability of the PAM/PEI polymeric gel in saline water was examined at 150°C (302F). Samples prepared in sea water showed better stability compared with distilled and field water. Dynamic rheology and core‐flooding experiments were used to evaluate the PAM / PEI gel system at high temperatures. NaCl and NH₄Cl were evaluated as a possible retarders for delaying the gelation time in order to achieve a successful placement. NH₄Cl was found to be more effective retarder. Core‐flooding tests were conducted in sandstone and carbonate cores. The subject polymer gel was injected at rates typical of those in field applications. The injectivity of PAM/PEI was tested in Berea sandstone cores with initial permeability of ～45 mD. The post‐treatment of the system showed a permeability reduction of ～94% for a period of two weeks. The injectivity in low permeability carbonate cores required more retardation compared with the injectivity in sandstone cores. The gel reduced the permeability to brine in Indiana limestone core by 99.8% for more than 5 months. Rheology of cured gel samples indicated that the gel strength needs about one day of curing in the core for the strength to stabilize. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41869.     

Plasticization effects of dihydroxyl soybean oil improve flexibilities of epoxy‐based films for coating applications

Novel bio‐based coating materials were developed through cationic ring‐opening photopolymerization of dihydroxyl soybean oil (DSO) with commercial epoxy monomers [i.e., epoxidized soybean oil (ESO) and 3,4‐epoxycyclohexylmethyl‐3,4‐epoxycyclohexanecarboxylate (ECHM). The ether cross‐linking and post‐polymerization of the polymeric network were observed using Fourier transform infrared spectroscopy. Thermal properties of the bio‐based coating materials and their copolymerization behaviors were examined using differential scanning calorimetry and a thermogravimetric analyzer. Cross‐link density and molecular weight between cross‐link were obtained from dynamic mechanical analysis. ECHM/DSO (1 : 1.43 weight ratio) films showed the highest elongation at break (49.2%) with a tensile strength of 13.7 MPa. After 2 months of storage, the elongation at break and tensile strength of films were 32% and 15.1 MPa, respectively. ESO/DSO films (w/w ratios of 1 : 0.1, 1 : 0.15, and 1 : 0.2) exhibited stable flexibility of 11–13% of elongation at break without significant reductions in tensile strength (2.5–4.4 MPa) during a 2‐month shelf life. Optical transparencies of the films were comparable to commercial glass and polymers, and water uptake properties (0.72% and 2.83%) were significantly low. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41773.     

Improving properties of ceramic silicone rubber composites using high vinyl silicone oil

Reactive high vinyl silicone oil (HVSO) was selected to prepare the ceramic silicone rubber composites. The effects of HVSO on the mechanical properties and thermal stabilities of ceramic silicone rubber composites were investigated. The structures of the cross‐linked network of silicone rubber with or without HVSO were studied. The intermolecular space of silicone rubber was enlarged, and the cross‐linked point was concentrated by addition of HVSO, which was demonstrated by cross‐linking densities, scanning electron microscope (SEM) images, and dynamic mechanical analysis (DMA). The cross‐linked network model was formed with the slipping of the cross‐linked points along with the silicone rubber chain. Mechanical properties of composites were enhanced by the formation of this cross‐linked network. The tear strength, tensile strength, and elongation at break of the composites were increased by 18.5%, 13.2%, and 37.4% by the adding of 2 phr HVSO, respectively. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41864.     

定向穿越管道的挤毁失效及其防护装置的设计

定向穿越敷管技术由于其特殊优势,被越来越多地应用于油气管道敷设,但复杂的地质条件又极易导致穿越管道挤毁失效,对油气输送安全造成严重威胁。为此,针对复杂地层中穿越管道的挤毁失效行为,分析了其失效原因,主要是由孔壁失稳、地层沉降和地下水渗流等所导致的。进而基于管材非线性及管土耦合作用,建立了无缺陷和凹陷穿越管道的挤毁数值计算模型,并对其挤毁行为进行了研究。结果表明:①无缺陷管道与凹陷管道的挤毁失效模式不同,完整穿越管道的挤毁过程可分为6个阶段,管道横截面经历了椭圆形、"新月"形、"葫芦"形及"8"字形变化过程;②而凹陷管道的挤毁过程可分为5个阶段,管道横截面经历了"心"形、"新月"形、"葫芦"形及"8"字形变化过程;③围土压力越大,管道的挤毁失效后果越严重。最后,设计了一种结构简单、易于操作且具有自主知识产权的定向穿越管道用防护装置,可以有效降低管道发生凹陷、挤毁等失效的概率,延长管道使用寿命,可用于穿越危险地层的油气管道防护。     

Thermosetting bismaleimide resins generating covalent and multiple hydrogen bonds

Prepolymerizations of 4,4′‐bismaleimidodiphenylmethane (BMI), diallyl isocyanurate (DAIC), and melamine (ML) at 160–170°C and subsequent compression molding at 200–280°C yielded cured BMI/DAIC/ML resins with feed molar ratios of 4/1/1, 3/1/1, and 2/1/1 (BMI‐DAIC‐ML411, 311, and 211). Similarly, cured BMI/DAIC 1/1 and BMI/ML 3/1 resins (BMI‐DAIC11 and BMI‐ML31) were prepared. The FT‐IR analysis revealed that the maleimide and allyl groups were almost consumed for all the cured resins, and the hydrogen bonding interaction became stronger with decreasing BMI contents for BMI‐DAIC‐MLs. Based on the cured structures elucidated from the FT‐IR result, the numbers of multiple hydrogen bonds and cross‐linking covalent bonds (N_MHB and N_CB), and total cross‐linking bond energy (E_TB) were evaluated to be 0, 7.92, and 618 for BMI‐DAIC‐ML411, 0.71, 7.81, and 627 for BMI‐DAIC‐ML311, and 0.95 mol kg^?1, 7.61 mol kg^?1, and 617 kcal kg^?1 for BMI‐DAIC‐ML211, respectively. A higher order of glass transition and 5% weight loss temperatures for BMI‐DAIC‐MLs was 411 > 311 > 211 in accordance with a higher order of N_CB. BMI‐DAIC‐MLs displayed a weak tan δ peak at 70–150°C due to dissociation of the hydrogen bonds. The flexural strength and modulus of BMI‐DAIC‐ML311 were higher than those of BMI‐DAIC‐ML411 in accordance with the difference of E_TB. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43121.