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61.
Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations 总被引:2,自引:0,他引:2
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases. 相似文献
62.
Generalized difference control of parallel streams temperatures 总被引:1,自引:0,他引:1
A furnace with multiple parallel passes and multiple burners is commonly seen in petroleum refineries. In order to maintain the furnace running in a safe, stable, and high-efficiency state it is necessary to control the outlet temperatures of the multiple passes to be the same. Due to the fact that the process of the oil heating in such furnace is nonlinear, multivariable, time varying, has serious coupling among passes, has frequent dynamic changes and a large time delay, traditional control methods have trouble in controlling these temperatures, and some advanced control methods, including predictive control, adaptive control, and robust control, are usually too complex for convenient use. In this paper, a control technique, called differences control technique (DsCT), is proposed to distribute the stream flowrates such that the stream temperatures are as identical as possible. The principle of the proposed technique is explained and demonstrated, and the results of its application to a real-life petroleum refinery furnace are also reported. The DsCT technique has the following advantages: it does not need complicated design procedures, the controller structure is simple, it is easy to apply, and it can be canonically applied to furnaces with different number of passes. 相似文献
63.
Probabilistic analysis of a static frame model 总被引:1,自引:0,他引:1
This paper describes our efforts during our participation in the Sandia Validation Workshop. The focus of the paper is the calibration of material models and simulation of random fields to characterize the variations of material properties across spatial field. Both parametric and non-parametric methods were used to represent uncertainty. Part of the challenge of this problem is the small amount of data that is available for the necessary probabilistic analyses in support of calibration, validation, accreditation and prediction activities. The analysis methods and corresponding results are described. 相似文献
64.
提出一种配电网电容电流测量的新方法,在零序电压互感器的开口三角侧串联一个可调电感,通过注入一个变频恒流信号寻找配电网的谐振频率,改变可调电感的数值后寻找另一谐振频率,联立2个谐振方程求解电容电流,该方法消除了电压互感器漏抗对测量的影响。开发了配电网电容电流测量仪,经模拟试验和现场测试表明,该方法具有安全、快捷、准确等特点,适用于中性点不接地或经随调式消弧线圈接地配电网。 相似文献
65.
This paper presents the mass transfer results from an impinging liquid jet to a rotating disk. The mass transfer coefficients were measured using the electrochemical limiting diffusion current technique (ELDCT). Rotational Reynolds number (Rer) in the range of 3.4 × 104–1.2 × 105, jet Reynolds number (Rej) 1.7 × 104–5.3 × 104 and non-dimensional jet-to-disk spacing (H/d) 2–8 were taken into consideration as parameters. It was found that the jet impingement resulted in a substantial enhancement in the mass transfer compared to the case of the rotating disk without jet. 相似文献
66.
Mayank Kashyap 《Powder Technology》2008,183(3):441-453
The effect of electric field on the hydrodynamics of nanoparticles was studied in a fluidized rectangular bed, with electrodes attached to two parallel walls. It was shown that the electric field of the order of 3 times the gravity markedly decreased the bed expansion and increased the solids volume fraction of nanoparticles fluidized by air. In these experiments, a light diode assembly was utilized to infer the local solids volume fractions within a rectangular bed of 10 nm silica particles. These experimental measurements yielded a two dimensional solids volume fraction distribution within the rectangular bed. The experimental results provided some new insights into the distribution of solids within the bed. The agglomerate diameters were computed using a momentum balance with the drag given by the Ergun equation and the empirical Richardson-Zaki method. Both methods yielded agglomerate diameters of the order of 100 μm and showed dependence on the strength of the electric field. The electric field decreased the granular temperature of the nanoparticles. 相似文献
67.
S. K. Chen A. Serquis G. Serrano K. A. Yates M. G. Blamire D. Guthrie J. Cooper H. Wang S. Margadonna J. L. MacManus‐Driscoll 《Advanced functional materials》2008,18(1):113-120
By applying a combination of characterisation tools, changes in structural and superconducting properties with nominal Mg non‐stoichiometry in MgxB2 are found. The non‐stoichiometry produces enhanced in‐field critical current densities (Jc's) and upper critical field / irreversibility field (Hc2/Hirr(T)) values. Upper critical fields of ~ 21 T (4.2 K) were obtained in nominal Mg‐deficient samples compared to ~ 17 T (4.2 K) for near‐stoichiometric samples. 相似文献
68.
69.
This paper deals with the decomposition analysis of energy-related CO2 emissions in Greece from 1990 to 2002. The Arithmetic Mean Divisia Index (AMDI) and the Logarithmic Mean Divisia Index (LMDI) techniques are applied and changes in CO2 emissions are decomposed into four factors: income effect, energy intensity effect, fuel share effect and population effect. The period-wise and time series analyses show that the biggest contributor to the rise in CO2 emissions in Greece is the income effect; on the contrary, the energy intensity effect is mainly responsible for the decrease in CO2 emissions. A comparison of the results of the two techniques gave an insight in the intricacies of energy decomposition. Finally, conclusions and future areas of research are presented. 相似文献
70.