聚合物溶液流经多孔介质时剪切降解的实验研究

测定了３种分子量的浓度１００ｐｐｍ ＨＰＡＭ水溶液，以不同的剪切速度流过低、中、高３种渗透率的人造砂岩岩芯后的粘度和特性粘数损失。研究了流经多孔介质时的剪切除解与剪切速率、介质渗透率、分子量之间的关系，得到了一些定性规律。     

GaAIAs/GaAs正面发光管的失效机理研究

研究和分析了高辐射GaAlAs/GaAs LED的退化机理。经高温加速老化,估算器件的工作寿命为10~5小时,并估算该器件的激活能为0.58eV。     

Model forecasts of atrazine in Lake Michigan in response to various sensitivity and potential management scenarios

For more than forty years, the herbicide atrazine has been used on corn crops in the Lake Michigan basin to control weeds. It is usually applied to farm fields in the spring before or after the corn crop emerges. A version of the WASP4 mass balance model, LM2-Atrazine, was used to assess the impact of the historical and future usage of this chemical on lake water concentrations. Long-term model forecasts were performed under various sensitivity and potential management scenarios. The model was calibrated to available lake data and results indicate that atrazine, under average conditions, is decaying very slowly in the lake (0.009/year). This kinetic decay translates into a half-life estimate of 77 years. If the average condition scenario were assumed to remain constant into the future and reflective of conditions in January 1, 2005, it is expected that the lake (excluding Green Bay) would eventually reach a volume-weighted average atrazine concentration of approximately 67 ng/L in the year 2157 (current model prediction is 48 ng/L for year 2011). These forecasted lake-wide concentrations are below known water quality criteria for the protection of aquatic ecosystems.     

Evaluation of the effects of operational parameters in the pretreatment of sugarcane bagasse with diluted sulfuric acid using analysis of variance

The pretreatment of lignocellulosic residues has been extensively studied as a method to disrupt the cellulose–hemicelluloses–lignin complex in biomass to access the sugars in their respective components. In this work, we carried out a study using sulfuric acid pretreatment of sugarcane bagasse by varying the following operational parameters: solid loading (10–30% of bagasse relative to the volume of the sulfuric acid solution), sulfuric acid concentration (0.5–2.5% relative to the dry mass of bagasse), reaction time (5–25?min), and temperature (135–195°C). The obtained solids from each pretreatment condition were submitted to enzymatic hydrolysis under the same process conditions: 0.232?g of Celluclast 1.5?L and 0.052?g of Novozym 188 per g of pretreated sugarcane bagasse, 72?h of hydrolysis, and 200?rpm of agitation at 50°C. Using central composite rotational design configuration in the experiments and analysis of variance, the results indicate that the conditions that produced larger quantities of glucose by enzymatic hydrolysis (0.35?g glucose/g pulp) with minimum amounts of degradation products were as follows: 20% solids loading, 15?min of reaction time, 1.5% sulfuric acid, and a minimum temperature of reaction of 170°C.     

On the feasibility of on-farm biogas-to-electricity conversion: To what extent is solid oxide fuel cells durability a threat to break even the initial investment?

Despite their promising features, adverse economic feasibility still hamper SOFCs wide implementation and this effect is emphasized as long as the system size is reduced. According to previous investigations, the biogas pre-treatment section represents a burden for the economic viability. Aiming at reducing the extent of installation costs in SOFC-based configurations, biogas partial upgrading through CO₂ gas-separation membranes is put forth as innovative solution against reforming. This innovative system concept is expected to make SOFCs more cost-effective, yet resulting feeding gas might cause a quicker SOFC performance decay. Besides solving this trade-off, the economic viability results strongly sensitive to subsidiary electricity prices in force according to the regulatory framework.This paper presents a comparative economic assessment regarding biogas-to-electricity conversion via Solid Oxide fuel cells (SOFCs) and mature technologies as internal combustion engines (ICEs). Results highlighted that, the innovative SOFC system is far more viable than reforming-based one, exhibiting a reasonable payback time, with an adequate subsidized electricity sale price (4 and 5 years for small/medium and large-size plants respectively when subsidy is 0.28 €/kWh), up to 1%_1000h degradation rate. On the other hand, whilst considering a SOFC degradation rate of 0.03%_1000h, the reforming-based system appears feasible only on large-size plants, yet recovering the initial capital expenditure in 9 years. Moreover, once the break-even point is reached, the gain in the net revenue produced by the innovative system is amplified in the event of small-size installation. This allows the possibility to undertake the risk of higher degradation rates (up to 2%_1000h) without jeopardizing the economic profitability. Therefore, in the present regulatory framework and under current capital costs projections, the innovative SOFC system appears as much profitable as ICE mature technology. Such effort in the design of the fuel pre-treatment unit can lever SOFC broad spreading into the market of small biogas producers.     

The design of long-life,high-efficiency PEM fuel cell power supplies for low power sensor networks

Field sensor networks have important applications in environmental monitoring, wildlife preservation, in disaster monitoring and in border security. The reduced cost of electronics, sensors and actuators make it possible to deploy hundreds if not thousands of these sensor modules. However, power technology has not kept pace. Current power supply technologies such as batteries limit many applications due to their low specific energy. Photovoltaics typically requires large bulky panels and is dependent on varying solar insolation and therefore requires backup power sources. Polymer Electrolyte Membrane (PEM) fuel cells are a promising alternative, because they are clean, quiet and operate at high efficiencies. However, challenges remain in achieving long lives due to factors such as degradation and hydrogen storage. In this work, we devise a framework for designing fuel cells power supplies for field sensor networks. This design framework utilize lithium hydride hydrogen storage technology that offers high energy density of up to 5000 Wh/kg. Using this design framework, we identify operating conditions to maximize the life of the power supply, meet the required power output and minimize fuel consumption. We devise a series of controllers to achieve this capability and demonstrate it using a bench-top experiment that operated for 5000 h. The laboratory experiments point towards a pathway to demonstrate these fuel cell power supplies in the field. Our studies show that the proposed PEM fuel cell hybrid system fueled using lithium hydride offers at least a 3 fold reduction in mass compared to state-of-the-art batteries and 3-5 fold reduction in mass compared to current fuel cell technologies.     

Aerobic degradation of nitrobenzene by immobilization of Rhodotorula mucilaginosa in polyurethane foam

Rhodotorula mucilaginosa Z1 capable of degrading nitrobenzene was immobilized in polyurethane foam. The nitrobenzene-degrading capacity of immobilized cells was compared to free cells in batches in shaken culture. Effects of pH and temperature on the nitrobenzene degradation showed that polyurethane-immobilized Z1 had higher tolerances toward acid, alkali, and heat than those of free cells. Kinetic studies revealed that higher concentrations of nitrobenzene were better tolerated and more quickly degraded by polyurethane-immobilized Z1 than by free cells. Moreover, the ability of polyurethane-immobilized Z1 to resist nitrobenzene shock load was enhanced. Experiments on the nitrobenzene degradation in different concentrations of NaCl and in the presence of phenol or aniline demonstrated that polyurethane-immobilized Z1 exhibited higher tolerance toward salinity and toxic chemicals than those of free cells. Immobilization therefore could be a promising method for treating nitrobenzene industrial wastewater. This is the first report on the degradation of nitrobenzene by a polyurethane-immobilized yeast strain.     

Coke Formation from Aircraft Engine Oils: Part II—Effects of Oil Formulation and Surface Composition

This is the second of two papers giving the results of a study undertaken to determine how aircraft engine oil degrades to form coke on oil-wetted surfaces. In part 2 the authors address the impacts of additives (which is related to oil types) and surface materials upon the oil coking process.

In Part 1 of this study, the authors showed that simple laboratory tests involving thin films of oil heated for specified timesltemperatures in open glass vials produced polymer and coke similar to the deposits seen on failed face seals taken from the operating aircraft engines and polymers isolated from used engine oils. Antioxidants inhibit and delay the coke producing reactions. After the antioxidant package is depleted to approximately 10 percent of the original level, the ester basestock undergoes accelerated oxidation to form oil-soluble polymers. As the oil spends additional time at elevated temperature, these polymers increase in molecular weight and undergo minor compositional changes becoming insoluble in the oil, producing deposits. If the time that a thin oil layer spends on a hot surface at elevated temperature can be limited so that the antioxidant does not deplete completely, coking can be prevented. This shifts the focus from coke minimization to coke prevention.

The authors results in Part 2 indicate that oil choice—which is largely a choice of antioxidant package—makes a large difference in how long oil can remain on a hot surface without forming polymer/coke deposits. For the oils studied in Part 2, the capabilities of the oils' antioxidant packages to inhibit coke formation varied 15 fold.

Surface material choice has minimal effect upon the rate of antioxidant depletion. However, once the antioxidant in the oil in a thin layer has become ineffective in inhibiting accelerated oxidation (approximately 10 percent of original concentration), the material the oil resides upon strongly effects the rate of the polymer/coke formation processes. Stainless steel speeds the process compared to a glass substrate.     

Micro modelling of solid oxide electrolysis cell: From performance to durability

An in-house micro model has been built to describe the electrochemical mechanisms governing both H₂ and O₂ electrodes operating in SOEC mode. A special attention has been paid to take into account the microstructure properties of the ionic, electronic and gas phases as well as the processes occurring therein.     

Tribochemical Surface Reaction and Lubricating Oil Film

A radioactive tracer technique was used to investigate a tribo-chemical surface reaction obtained by a thrust collar type friction Machine. Radioactive dibenzyl disulfide labeled with sulfur-35 was used as an additive. Steel and copper disks were used as friction specimens.

Radioactive copper sulfide on the friction surface was quantitatively measured with a G-M tube, and a kinetical analysis of the reaction was carried out.

The friction coefficient decreased linearly depending on the amount of surface produced on the friction surface. This dependency was accompanied by adsorption of dibenzyl disulfide, which made a more effective lubricating oil film and was enhanced by the sulfide on the friction surface.

The results of kinetical analysis were explained effectively by considering the oil film behavior related to the adsorptive action of the surface sulfide.