Irrigated composite liner designs for fast hydration and prevention of thermal desiccation of geosynthetics clay liners

In composite liners made of geomembrane (GMB)-geosynthetics clay liners (GCLs), maintaining bentonite in the GCL in a suitably hydrated state is critical for their performance. Hydration of GCL from subsoil, following industry best practice, is time consuming and conditional on suitable water chemistry in subsoil. In addition, under thermal gradients, dehydration occurs, with moisture migrating downwards to the subsoil, leading to the development of cracks in the bentonite and hence loss of performance.Two novel ideas are proposed in this paper, namely hydration of GCLs by artificial irrigation and hydraulic separation of the liner system from the underlying subsoil. Three new composite liner designs allowing for actively irrigating a geosynthetic clay liner (GCL) through a geocomposite layer were investigated. In two of the three designs, the hydraulic connection between the GCL and the subsoil was broken by placing an additional GMB between them. The new designs were tested in column experiments under 20 kPa overburden pressure and temperatures of up to 78 °C applied to the top of the liner. The performances of the new designs were compared to that of a standard GCL-GMB design where GCL was allowed to hydrate from a well-graded sandy subsoil. Three scenarios for the staging of hydration and thermal load application were investigated.Under active hydration of the composite liners, it took less than 14 days for the GCLs to reach a gravimetric water content ω of 110–130%, compared to 49 days taken to reach ω~95% under hydration from the subsoil. GCLs in the new designs in which the hydraulic connection with the subsoil was broken, remained well-hydrated (ω>100%) after 14 days of heating and no cracks appeared in the bentonite. On the other hand, the GCL in the conventional design experienced severe desiccation under the same conditions. The new designs hence offer a viable solution to the problem of slow hydration and/or thermal desiccation of GCLs.     

Effect of added polymer on the desiccation and healing of a geosynthetic clay liner subject to thermal gradients

The desiccation and subsequent hydraulic conductivity of both a standard (GCL_A) and polymer-enhanced (GCL_B) Na-bentonite GCL hydrated from a well-graded sandy subsoil under 20 kPa, then subjected to a thermal gradient, and finally rehydrated and permeated with distilled water or 0.325 mol/L Na⁺ synthetic brine are reported.With moderate temperature of 40 °C applied to the top of the liner, GCL_B experienced less cracking than GCL_A, but this advantage disappeared when temperatures increased. Both desiccated specimens of GCL_A and B showed significant self-healing when permeated with distilled water and their hydraulic conductivities quickly reduced to around 10⁻¹¹ m/s at 20 kPa upon rehydration. However, when GCL_B desiccated specimens were permeated with the synthetic brine, their hydraulic conductivities were found to be one to two orders of magnitude higher than corresponding values obtained with distilled water. On the other hand, GCL_A (with no polymer treatment) maintained its hydraulic conductivities at the same level obtained with distilled water. It is concluded that caution should be exercised in using polymer-bentonite in applications in which GCLs are subjected to significant thermal gradients unless there is data to show they are resistant to thermal effects.     

Desiccation survival of Acinetobacter spp. in infant formula

Acinetobacter spp. are included under category B in the FAO-WHO list of organisms of concern for neonatal health following the consumption of powdered infant formula. However, the ability of Acinetobacter spp. to maintain their viability in desiccated infant formula over a storage period consistent with the shelf-life of commercially available powdered infant formula (2 years) has not been demonstrated. In this study, 9 clinical and food isolates of Acinetobacter baumannii, A. calcoaceticus, and Acinetobacter genomosp. 3 were desiccated in infant formula and then reconstituted at designated time points. Bacterial viability was followed for a maximum period of 24 months or until the strain became undetectable (<5 × 10² cfu/ml). For comparative purposes, one Enterobacter hormaechei and two Enterobacter cloacae strains were also monitored for their desiccation survival. The seven clinical and food strains remained cultivable for the whole duration of the study and showed biphasic survival curves. The initial drop in viable count was up to 3.5 log₁₀ cfu/ml within 18 h of desiccation exposure. By the end of the study, the reduction in viability was between 3.6 and 4.8 log₁₀ cfu/ml. In contrast the A. baumanii and A. calcoaceticus species type strains only persisted for 6 and 9 months, respectively, possibly due to laboratory adaptation. The E. cloacae and E. hormaechei strains were undetectable after 12 and 17 months, respectively. The persistence of Acinetobacter spp. strains in desiccated powdered infant formula, supports the FAO-WHO designation of this organism as a risk to neonatal health.     

Desiccation of adhering and biofilm Listeria monocytogenes on stainless steel: Survival and transfer to salmon products

The foodborne bacterial pathogen, Listeria monocytogenes, commonly contaminates foods during processing, where the microorganisms are potentially subjected to low relative humidity (RH) conditions for extended periods of time. The objective of this study was to examine survival during desiccation (43% RH and 15 °C) of biofilm L. monocytogenes N53-1 cells on stainless steel coupons and to assess subsequent transfer to salmon products. Formation of static biofilm (2 days at 100% RH and 15 °C) prior to desiccation for 23 days significantly (P < 0.05) improved survival of cells desiccated in initial low salt concentrations (0.5%) compared to the survival for non-biofilm cells also desiccated in low salt, indicating the protective effect of the biofilm matrix. Osmoadaptation of cells in 5% NaCl before formation of the static biofilm significantly (P < 0.05) increased long-term desiccation survival (49 days) irrespectively of the initial salt levels (0.5% and 5% NaCl). The efficiency of transfer (EOT) of desiccated biofilm cells was significantly (P < 0.05) lower than EOTs for desiccated non-biofilm bacteria, however, as biofilm formation enhanced desiccation survival more bacteria were still transferred to smoked and fresh salmon. In conclusion, the current work shows the protective effect of biofilm formation, salt and osmoadaptation on the desiccation survival of L. monocytogenes, which in turn increases the potential for cross-contamination during food processing.     

Relaxation nuclear magnetic resonance imaging (R-NMRI) of PDMS/PDPS siloxane copolymer desiccation

Relaxation nuclear magnetic resonance imaging (R-NMRI) was employed to study the effects of desiccation on SiO₂-filled and unfilled polydimethylsiloxane-polydiphenylsiloxane (PDMS/PDPS) copolymers. Uniform NMR spin-spin relaxation time (T₂) profiles were observed across the sample thickness indicating that the drying process is approximately uniform, and that the desiccation of the silicone copolymer is not a H₂O diffusion limited process. In a P₂O₅ desiccation environment, significant reduction of T₂ was observed for the SiO₂-filled and unfilled copolymer material for desiccation up to 225 days. A very small reduction in T₂ was observed for the unfilled copolymer between 225 and 487 days. The increase in relative stiffness with desiccation was found to be higher for the unfilled copolymer.     

真空冷冻干燥人参的物性测量

测定了人参的共晶点温度为-10~-15℃;导热系数为λ=0.041w/m·℃。可供人参冷冻干燥工艺和设备设计的基础物性数据。     

Modeling of Clay Liner Desiccation

The potential for the desiccation of clay liner component of composite liners due to temperature field generated by breakdown of organic matter in municipal solid waste landfills is examined using a model proposed by Zhou and Rowe. In these analyses, a set of fully coupled governing equations expressed in terms of displacement, capillary pressure, air pressure, and temperature increase are used, and numerical results are solved by using finite element method with a mass-conservative numerical scheme. The model results are shown to be in encouraging agreement with experimental data for a problem involving heating of a landfill liner. The fully coupled transient fields (temperature, horizontal stress change, suction head, and volumetric water content) are then examined for two types of composite liner system, one involving a geomembrane over a compacted clay liner (CCL) and the other involving a geomembrane over a geosynthetic clay liner (GCL). It is shown that there can be significant water loss and horizontal stress change in both the CCL and GCL liner even with a temperature increase as small as 20°C. The time to reach steady state decreases as boundary temperature increases. Under a 30°C temperature increase, it takes 5 years to reach the steady state water content with a GCL liner but 50 years with a CCL liner. The effects of various parameters, such as hydraulic conductivity and thickness of the liner, on the performance of the liner are discussed.     

Three-dimensional characterization of cracks in undisturbed Mile expansive soil using X-ray computed tomography

The distribution of cracks strongly affects the hydro-mechanical behavior and strength of soil. In order to characterize the distribution of cracks in undisturbed expansive soil, X-ray computed tomography (X-ray CT) tests were carried out for one type of undisturbed expansive soil from Mile City, China. Seven undisturbed specimens retrieved from depths between 1 and 4.7 m were used to study the evolution of cracks along the drying path. The characteristics of the cracks were quantitatively studied by 3D parameters extracted from CT images by commercial software. The test results suggested that, with an increase in suction, the total volume of the cracks gradually increased, and one large crack formed due to the merging of sub-cracks before the shrinkage limit. When the suction was larger than the suction corresponding to the shrinkage limit, degradation of the cracks caused by the collapse of the soil structure was observed. Meanwhile, due to the development of sub-cracks, the crack anisotropy caused by the typically oriented primary cracks decreased along the drying path. Finally, a conceptual model of crack development for undisturbed Mile clay was proposed based on the evolution of crack volume, number, shape, and orientation.     

Optimum deposition for sub-aerial tailings disposal: concepts and theories

Mineral and energy production produces large volumes of tailings that are generally disposed of on the Earth's surface. How to minimize their environmental impact and reduce the storage volume of the tailings has become a major concern of mining operations. In addition, the pressure on the optimal use of water resources, especially in arid regions, is a critical issue. Therefore, how to maximize recycling of the process water is an important concern for mine operations in these regions. The sub-aerial deposition technique is a promising method for dealing with these problems. Although this technique has existed for decades, its use still involves technical challenges. Among these, an important concern is the selection of the optimum deposition parameters to yield the best desiccation results. A rational method for evaluating the optimum depositional parameter for design of sub-aerial tailings disposal is proposed. In this paper the concepts of sub-aerial tailings disposal are presented. The physical process of sub-aerial deposition and a one-dimensional model of the sedimentation, consolidation and desiccation of sub-aerially deposited tailings are described in detail.     

Effects of leachate infiltration and desiccation cracks on hydraulic conductivity of compacted clay

Both cracks in clay liner and the complex composition of landfill leachate might have effects on the hydraulic conductivity of a compacted clay liner. In this study, the hydraulic conductivities of natural clay and bentonite-modified clay with and without desiccation cracks were measured, respectively, using three types of liquids as permeating liquid: 2 500 mg/L acetic acid solution, 0.5 mol/L Ca Cl2 solution, and tap water. When tap water was adopted as the permeating liquid, desiccation cracks resulted in increases in the average value of hydraulic conductivity: a 25-fold increase for the natural clay and a 5.7-fold increase for the bentonite-modified clay. It was also found out that the strong selfhealing capability of bentonite helped to reduce the adverse impact of cracks on hydraulic performance. In contrast to tap water, simulated leachates(acetic acid and Ca Cl2solutions) show no adverse effect on the hydraulic conductivities of natural and bentonite-modified clays. It is concluded that desiccation cracks and bentonite have more significant effects on hydraulic performance than simulated leachates.