Performance data are presented for methane oxidation on alumina-supported Pd, Pt, and Rh catalysts under both fuel-rich and fuel-lean conditions. Catalyst activity was measured in a micro-scale isothermal reactor at temperatures between 300 and 800 °C. Non-isothermal (near adiabatic) temperature and reaction data were obtained in a full-length (non-differential) sub-scale reactor operating at high pressure (0.9 MPa) and constant inlet temperature, simulating actual reactor operation in catalytic combustion applications.
Under fuel-lean conditions, Pd catalyst was the most active, although deactivation occurred above 650 °C, with reactivation upon cooling. Rh catalyst also deactivated above 750 °C, but did not reactivate. Pt catalyst was active above 600 °C. Fuel-lean reaction products were CO2 and H2O for all three catalysts.
The same catalysts tested under fuel-rich conditions demonstrated much higher activity. In addition, a ‘lightoff’ temperature was found (between 450 and 600 °C), where a stepwise increase in reaction rate was observed. Following ‘lightoff’ partial oxidation products (CO, H2) appeared in the mixture, and their concentration increased with increasing temperature. All three catalysts exhibited this behavior.
High-pressure (0.9 MPa) sub-scale reactor and combustor data are shown, demonstrating the benefits of fuel-rich operation over the catalyst for ultra-low emissions combustion. 相似文献
To improve the performance of the Turbofan engine,several measures should be considered during design process.Such measures,relating to aerodynamic characteristic design,include the maximum enthalpy per stage,the shortest axial length,the minimum blade rows and the highest efficient in design and off design condition.To satisfy theses design characters,the meridian geometry of the engine will he excurvature at a high degree transition part between HP and LP turbines.The study is to investigate the effect of blade bowing on flow loss at blade tip and root of the type of turbine.Such turbine,tending towards separation,with severe secondary flow at the tip and strong radial flow at exit,was simulated by the 3D N-S solver Numerea,and there were several different stacking line bowing schemes in all.The results show that tip negative bowing and root positive bowing is able to weaken radial flow,consequently reduce the flow loss at the tip and root. 相似文献