WALL AND PARTICLE-SHAPE EFFECTS ON HEAT TRANSFER IN PACKED BEDS

The effective radial thermal conductivity and apparent heat transfer coefficient for a packed bed were experimentally determined for beds of spheres, full cylinders and hollow cylinders, for flow rates giving particle Reynolds numbers in the range 100-1000, and for tube to particle diameter ratios of 5-12. Over these ranges the radial Peclet number Pe_r showed significant dependence on solid conductivity, gas flow rate and particle shape, while the wall Biot number Bi showed significant dependence on tube to particle diameter ratio, gas flow rate and particle shape. These dependencies were predicted well by equations incorporating the effects of these variables into individual gas and solid phase parameters, which were then combined to give the effective or lumped parameters     

ESTIMATION OF EFFECTIVE SHEAR RATE FOR AERATED NON-NEWTONIAN LIQUIDS IN AIRLIFT BIOREACTOR”“

Effective shear rate is one of the indispensable parameters for the design of aerobic fermentors using a viscous non-Newtonian system. The estimation of effective shear rate in airlift loop bioreactors has been investigated with liquid circulation velocity. An empirical correlation of effective shear rate in airlift loop reactors is proposed.

γ_eπ= 3.26-3.51 ; 10²U_G + 1.48 10⁴U²_G

It is found that the effective shear rate is lower in airlift reactors than in bubble columns. This equation can be used for the cultivation of cells sensitive to shear stress.     

Evaluation of the performance of tight-UF membranes with respect to NOM removal using effective MWCO, molecular weight, and apparent diffusivity of NOM

Concepts for the effective MWCO of tight-UF membranes, and apparent diffusion coefficients for NOM, were introduced to determine the mechanisms influencing NOM removal and to explain the various behaviors of NOM removal by UF membranes with different hydrophobicities, permeability, and surface charges. Colloidal NOM (COM) and non-colloidal hydrophobic NOM (NCD HP) constituents were chosen for the evaluation of two different UF membranes. For a relatively hydrophobic, relatively high permeability, and less negatively charged UF membrane, the hydrophobic fractions of COM were preferentially removed and were also removed by a size exclusion mechanism (i.e., both hydrophobic interaction and size exclusion mechanisms). The NCD HP exhibited no such preferential removal of the hydrophobic fractions, but could be removed by a size exclusion mechanism (i.e., only size exclusion mechanism). With a relatively hydrophilic, relatively low permeability, and more negatively charged UF membrane, COM exhibited no preferential removal of the hydrophobic fractions, but could be removed by a size exclusion mechanism (i.e., only size exclusion mechanism). Whereas the hydrophobic fractions of the NCD HP were preferentially removed, these could not be removed by a size exclusion mechanism (i.e., only hydrophobic interaction mechanism). The apparent diffusion coefficients of NOM, as determined from NOM diffusion experiments using a diffusion cell equipped with a regenerated cellulose membrane, were much lower than those calculated by the Stokes-Einstein relation. The diffusion coefficient of NOM is expected to be used to predict and explain NOM transport behaviors in tight-UF membranes.     

Catalyst pore plugging effects on hydrocracking reactions in an Ebullated bed reactor operation

This paper analyzes the deactivation effects of NiMo/Al₂O₃ catalyst during the operation in an Ebullated bed reactor for Heavy residue hydrocracking. The spent catalysts were characterized by chemical analysis, ¹³C NMR, ESM, DRX, and by using thermal programmed oxidation and diffusion studies in a shallow bed micro-reactor. The deactivations were performed in a 5 l continuously stirred tank reactor, while the spent catalysts were tested in a 0.05 l micro-reactor. The study focused on determining the properties of the external layer of the catalyst and on evaluating the internal coke and metal deposition. The results indicated that initial deactivation is mainly due to coke depositions, while its impact on mass transfer reaction control depends on temperature. In long-term deactivation, the metal deposition plays a more important role in blocking the internal micro- and meso-structures and in building up the external layer of the pellets.     

The voidage function and effective drag force for fluidized beds

Here, an experimental investigation on the effective drag force in a conventional fluidized bed is presented. Two beds of different particle size distribution belonging to group B and group B/D powders were fluidized in air in a diameter column. The drag force on a particle has been calculated based on the measurement of particle velocity and concentration during pulse gas tests, using twin-plane electrical capacitance tomography. The validity of the voidage function “correction function”, (1−ε_s)ⁿ, for the reliable estimation of the effective drag force has been investigated. The parameter n shows substantial dependence on the relative particle Reynolds number , and the spatial variation of the effective static and hydrodynamic forces. It is also illustrated that, a simple correlation for the effective drag coefficient as function of the particle Reynolds number (Re_p), expressed implicitly in terms of the interstitial gas velocity, can serve in estimating the effective drag force in a real fluidization process. Analysis shows that, the calculated drag force is comparable to the particle weight, which enables a better understanding of the particle dynamics, and the degree of spatial segregation in a multi-sized particle bed mixture. The analogy presented in this paper could be extended to obtain a generalized correlation for the effective drag coefficient in a fluidized bed in terms of Re_p and the particle physical properties.     

Heat transfer of gas flow through a packed bed

This paper reports an experimental study of both the transient and steady-state heat transfer behaviour of a gas flowing through a packed bed under the constant wall temperature conditions. Effective thermal conductivities and convective heat transfer coefficient are derived based on the steady-state measurements and the two-dimensional axial dispersion plug flow (2DADPF) model. The results reveal a large temperature drop at the wall region and the temperature drop depends on the axial distance from the inlet. The 2DADPF model predicts the axial temperature distribution fairly well, but the prediction is poor for the radial temperature distribution. Length-dependent behaviour of the effective heat transfer parameters and non-uniform flow behaviour are proposed to be responsible. A comparison with previously published correlations and data in the literature shows that the relationships proposed by Bunnell et al. and Demirel et al. agree well with the measured effective radial thermal conductivity, whereas the wall-fluid heat transfer coefficient is better represented by the Li-Finlayson correlation.     

Deformation transition of intact coal induced by gas injection

Gas migration in coal bed is a multiple-physical process, of which not only includes gas desorption/diffusion through coal matrix and gas Darcy flow through the cleat system, but also results in deform...     

环形刀高度变化刀路轨迹规划方法

为提高汽车覆盖件模具加工效率,将环形刀应用于汽车模具小曲率面的半精及精加工过程.通过对三坐标铣削小曲率面的刀具切触几何分析,确定环形刀最佳进给方向应沿工件高度变化方向,此时可使有效切削带宽达到最大.基于此结论,分别对两类特殊型面进行了刀路轨迹规划.对于单一方向曲率变化面采用垂直截面法,截面方向沿最大主曲率方向,实验表明:垂直截面法与等高线法相比可提高加工效率25%,并且有较好的表面质量;对于圆鼓面采用放射精加工方法,仿真结果表明:此方法与三维偏置方法相比可提高加工效率22.64%,并且避免了周边欠切.     

A global cutter positioning method for multi-axis machining of sculptured surfaces

Traditional cutter positioning methods have defects of global errors and incomplete optimization. Because of using local differential geometry and focusing on the cutting contact point, these defects cannot be avoided and will deteriorate accuracy in precision machining. The authors presented the conception of actual cutting edge of a toroidal mill which was extended from cutting contact point, and pointed out its importance in programming. Instantaneous cutter position error (ICPE) was also investigated. A new global method based on the ICPE curve was presented. Taking the relationship between surface and cutter into consideration thoroughly, this global method shows many advantages which have been verified by simulation and cutting tests.     

一种用微机计算型砂中粘土分布的方法

本文提出了一种用微机研究型砂中粘土分布规律的方法。指出,粘土覆膜率、粘土膜厚度分布标准偏差及成膜粘土量是评价型砂中粘土分布均匀性的主要定量指标;并首次用微机定量地计算和评价了型砂中粘土分布的规律特性。结果表明,型砂中(?)分布规律和型砂性能具有相对应的关系。