Oscillating Cup Viscosity Measurements of Aluminum Alloys: A201, A319 and A356

An oscillating cup viscometer was developed to measure the absolute viscosities of molten metals. Previous experiments established the capability of the apparatus to characterize the viscosities of molten nickel-based superalloys. However, modifications to the instrument and its theoretical analysis were required for reliable measurements on molten aluminum alloys, presumably due to their lower densities and lower viscosities. The theoretical literature for the fluid flow inside an oscillating cup is reviewed, and a working equation without any correction factor is developed for the improved viscometer. Some design parameters of the viscometer that directly affect the accuracy of viscosity estimation by using the working equation are discussed. A special vertical furnace was adopted to uniformly heat a longer cylindrical sample (10 mm inner diameter and 120 mm length) with a temperature difference of less than 2°C over the sample length. The measuring procedure was also improved to get more accurate motion parameters. It is estimated that the working equation and improved instrument provide an uncertainty of less than 4%. In addition, applications and experimental data are presented for pure aluminum and three aluminum alloys: A201, A319, and A356.     

降低彩板生产稀释剂消耗的方法探讨

结合彩涂板生产实际，介绍了几种降低稀释剂消耗的方法。     

Characterization of the flow behaviour of sausage emulsions with a simple tube viscometer

A specially designed tube viscometer was used to measure apparent viscosity during flow of Bologna type sausage emulsions moving through a pipe. Emulsions varied in fat content (from 21.8 to 44.3%) and in moisture/protein ratio (from 3.7 to 5.6), and the effects of added sodium chloride, sodium diphosphate, starch and blood plasma were investigated in a 36% fat, 3.7 moisture/protein emulsion.
The shear stresses determined as a function of shear rate were fitted by a power law. Yield stress of the emulsions was negligible relative to the applied stress. However, inspection of the flow profiles indicated that considerable slip of the sausage emulsion occurred at the pipe wall. Both emulsion flow and slip contribute to overall flow behaviour, so a kind of effective viscosity is determined. Intrinsic rheological properties and wall slip will both be affected by the composition of the sausage emulsion.     

顺丁橡胶生产过程"门尼升值"的原因研究

研究了顺丁橡胶生产过程中门尼升值的原因。结果表明，顺丁橡胶生产后处理的膨胀干燥过程存在门尼升值现象。不同内在质量的顺丁橡胶门尼升值不同，正常条件下门尼升值发生于门尼粘度的测试过程。     

Rhizobium trifolii capsular polysaccharide: a novel biopolymer with striking physical properties

The physical properties of the capsular polysaccharide of Rhizobium Trifolii (CPS) were investigated. Viscosity measurements provided information about the hydrodynamic volume of single coils, the perturbation of solvent flow and the shear-thinning behaviour of concentrated solutions. Changes in chain geometry and the development of an intermolecular network as a function of temperature were monitored using the techniques of optical rotation and dynamic oscillation. Finally, analysis of calorimetric thermograms elucidated the type of interactions between CPS and the bacterial levan. Overall, the Rhizobium polysaccharide was found to form thermally-reversible gels at an extremely low 'minimum critical gelling concentration' (c_o∼ 0.35gl^-1). At temperatures above the gel melting point (∼ 48°C), however, the compact polymer coils entangled at comparatively high concentrations (about 60 times higher than c_o). In the presence of a highly branched levan, the thermal stability of ordered CPS structures increased as a consequence of thermodynamic incompatibility between the two polymers.     

Instability due to Viscosity Stratification Downstream of a Centerline Injector

A common injector geometry upstream of a static mixer is the centerline injector. A flow instability can arise due to viscosity differences between the injected core‐flow and the outer co‐flow. This instability can adversely affect the effectiveness of the mixing operation. An experimental investigation of miscible viscosity‐stratified flow in a circular geometry was performed using Laser Induced Fluorescence (LIF) and Particle Image Velocimetry (PIV). The experimental results for the stable region agree with the analytical results. The unstable region exhibits different modes depending on the viscosity ratio, volume flux ratio, and Reynolds number. The modes include wavy core‐flow with fissures and wavy core‐flow with core breakup. The time‐averaged experiment velocity profiles for the unstable core indicate a broadening of the jet at the centerline, which is consistent with the LIF visualization.     

辐射对血液流变效应的研究及动物全身照射后全血粘度的变化规律

本文结果表明经一次大剂量全身照射后的机体血液流变的主要特性为全血表观粘度先高粘后低粘的双向性变化,从照后第一天起即升高。随着放射病病程的发展,在早期有一个高粘峰,其峰均值比照前升高47.80％。但因不同动物、不同剂量、不同均速,不同血源而变化不同。     

Extraction of penicillin G from simulated media by an emulsion liquid membrane process

The extraction of penicillin G from simulated media was performed by water/oil/water (w/o/w) emulsion liquid membranes (ELMs) and studied under various operational conditions in a batch system. The degree of extraction achieved was between 80% and 95% under specific conditions. A concentration of greater than nine times the initial concentration of penicillin G in the external phase was obtained in the internal phase. The pH of the internal aqueous solution, containing a basic salt, was theoretically calculated on the basis of the amount of penicillin G transported into the internal phase. The calculated results agreed with the experimental data well and were used to select a suitable type and concentration of a basic salt in the internal phase to give a pH within the range 5 to 8 where penicillin G was stable after the termination of extraction. The extraction of penicillin G was successfully performed by the ELM process with sodium carbonate in the internal phase.     

VAc—BA／MMA三元共聚物的制备及产品的粘接强度和聚合方法的关系

本文介绍了ＶＡｃ／ＢＡ／ＭＭＡ三元共聚的两种方法，并通过实验证实：聚合方法对三元共聚物的粘接强度有明显的影响。     

影响聚合物段塞流变性因素的研究

本文针对我国表面活性剂/聚合物驱油的实际,研究了石油磺酸盐(PS)、正丁醇(R_4OH)和矿化水对水解聚丙烯酰胺(HPAM)溶液流变性的影响。结果表明,PS对HPAM溶液流变性的影响与介质的矿化度有关:非矿化水介质中,PS对HPAM溶液性质的影响类似于无机盐,能降低HPAM溶液的表现粘度(η_α)和稠度系数(k);当系统中含有一定浓度矿化水时,PS却能升高系统的η_α和k值,降低流型指数(n),使系统的非牛顿性增强。在含有PS和矿化水的HPAM系统中加入R_4OH,系统的η_α和k值会有所增加。