填料萃取塔液泛速度的计算

介绍了三种有代表性的填料萃取塔的液泛速度计算公式，并通过它们用于三种典型的液-液实验体系和两种不同填料的计算结果的比较，对这些公式的适用范围进行了讨论。     

Extraction of Anthocyanin Pigments from Purple Sunflower Hulls

The anthocyanin pigments in hulls of purple sunflower seeds were extracted using three solvent systems, 50:1:49 ethanol-acetic acid-water (EAW), 0.01M acetic acid (AAc), or water containing SO₂. Solvent, extraction time, size of ground hulls, pH of extracting solvent, hulls/solvent ratio, and concentration of SO₂ in water, were investigated. All were significant factors affecting yield of extracted anthocyanins. EAW and SO₂ were more effective extractants than AAc. Optimum conditions from response surface optimization for the extraction with sulphurous water were: SO₂ at 200 mg/L, hull size 20 mesh, extraction time 5 min at 22°C, and solvent/hulls ratio = 20.     

潜油螺杆泵采油系统设计与应用技术分析

潜油螺杆泵采油技术在某些方面具有其他人工举升技术不可比拟的优点，特别适合于我国渤海湾一带粘油区、海上平台的采油作业，但这项技术在我国实际开发应用的时间还比较短，人们对这项技术的了解还不够深入，很多单项技术还有待于更多的人去关注和研究.介绍了潜油螺杆泵采油系统的结构，总结了该项采油技术与其他常用采油技术相比较的特点，系统地阐述了国内外的发展状况，分析了以往投入生产试运行时系统失效的原因并提出了相应的解决办法，最后探讨了系统设计技术的发展趋势.     

连续式超临界流体萃取进卸料装置

概括了超临界流体萃取技术和包括连续式操作在内的超临界流体萃取装置的研究现状 ,提出了一种通过球形进、卸料器完成固相物料超临界流体萃取连续化进卸料的装置 ,介绍了该装置的结构和工作原理 ,给出装置中各主要部件的计算方法。     

暖通空调工程设计常见问题

通过对施工图审查工作进行总结，指出了暖通空调和防火防排烟设计中存在的问题及防火规范本身的一些不足。     

New Environment-Friendly Approach for Bastnasite Metallurgic Treatment (I): Extraction of Tetravalent Cerium from Sulphuric Acid Medium with Di(2-ethylhexyl) Phosphoric Acid

Bastnasiteisamainsourceofrareearthproducts inwhichCeO2/REOisabout50%.Atpresent,a cidity leachingcombinedwithalkali conversion method[1]iscommonlyusedinthebastnasitetreat ment.Thismethodisunfriendlytotheenvironment becausetheradioactiveelementofthoriuman…     

离子液体用于燃料油深度脱硫的研究进展

首先介绍了加氢催化脱硫和其他脱硫技术的特点,综述了近年来国内外利用离子液体在萃取脱硫、萃取脱硫与氧化脱硫耦合、萃取脱硫与生物脱硫耦合等方面的研究。认为离子液体萃取脱硫具有操作简便、可循环使用、无需氢气、环境友好、能深度脱硫等特点,是一项具有广阔发展前景的技术。若要实现该技术的工业化应用,还需进一步加强离子液体在合成工艺、脱硫选择性及回收再生等方面的研究。     

Mass transfer kinetics of neodymium(III) extraction by calix[4]arene carboxylic acid using a constant interfacial area cell with laminar flow

BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (K_ao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (E_a) was calculated to be 21·41 kJ mol^?1 or 88·17 kJ mol^?1 (dependent on temperature) from the slope of log K_ao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (C_min) is lower than 4·19 × 10^?4 mol L^?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd³⁺]_(a)/dt = k_f[Nd³⁺]_(a)[H₄A]_(o)^0·727[H⁺]_(a)^?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry     

调节剂对烷基水杨醛肟萃取铜铁的影响

烷基水杨醛肟虽然是一种高选择性的铜萃取剂，但单独使用时，萃取相易出现沉淀；反萃时，再生有机相出现乳化物，而且两相分离时间较长．将月桂醇、仲辛醇、壬基酚三种调节剂分别加入到萃取剂中，研究其对烷基水杨醛肟萃取及反萃行为的影响．结果表明，三种调节剂均可以解决上述问题，只是使萃取能力略有降低；壬基酚加入到烷基水杨醛肟中有助于提高铜铁分离系数，可达647．     

从水淬渣中回收镓的试验研究

对鼓风炉（ISP法）或烟化炉水淬渣中回收镓的工艺进行了研究。结果表明，利用浓硫酸恒温熟化的独特浸出工艺，克服硅对液固分离的影响；以伯胺N9123作为萃取剂在硫酸介质中萃取镓；获得了含镓品位为2.82%的富集物。