柔性反馈式液压破碎锤配流系统研究与实验

根据工程施工破碎锤实际工况需要,对柔性反馈式液压破碎锤配流系统进行理论研究。设计一套电液联合控制柔性反馈式液压破碎锤实验样机;搭建液压破碎锤实验测试平台,进行可行性与实际工况下实验。实验结果表明:液压破碎锤电液控制系统设计是可行性的,破碎性能符合要求;利用该系统可实现新型液压破碎锤冲击能与冲击频率的实时改变,采集并分析实际工况下的冲击性能参数。     

Nano-SnO_2 Decorated Carbon Cloth as Flexible,Self-supporting and Additive-Free Anode for Sodium/Lithium-Ion Batteries

In this study,nano-sized SnO_2 decorated on carbon cloth(SnO_2/CC) is prepared through a simple and facile solid method.The nano-sized SnO_2 is uniformly distributed on the surface of carbon fibers in carbon cloth,providing sufficient free space to relieve volume expansion and reduce electrode pulverization during cycling.The as-prepared SnO_2/CC as a flexible,self-supporting and additive-free anode electrode for sodium-ion/lithium-ion batteries(SIBs/LIBs) can demonstrate outstanding electrochemical performance.SnO_2/CC after annealing at 350℃(SC-350) as an anode for SIBs can deliver a reversible capacity of 0.587 mA h cm~(-2) at the current density of 0.3 mA cm~(-2) after 100 cycles.In addition,when cycling at 1.5 mA cm~(-2),SC-350 can maintain 1.69 mA h cm~(-2) after 500 cycles when used as LIB anode.These results illustrate that the as-prepared SnO_2/CC can be a promising flexible anode material for flexible SIBs/LIBs and provide a simple and practical method for designing new flexible electrode materials.     

深振荡磁控溅射制备柔性硬质纳米涂层的研究进展

柔性硬质纳米涂层具有高致密性、高表面完整性、高硬度、高韧性和高裂纹抵抗力特性,是新一代高性能纳米涂层的一个重要发展方向,但其制备难度高,难以利用传统涂层制备技术实现。深振荡磁控溅射(deeposcillation magnetron sputtering, DOMS)技术是一种新型的高功率脉冲磁控溅射技术,现已成为国际涂层研究领域的热点。DOMS技术通过一系列调制的电压微脉冲振荡波形,能够实现完全消除电弧放电和靶材近全离化,获得高密度、低离子能量和高束流密度的等离子体,能制备出具有低缺陷、高表面完整性、高致密性的高性能纳米涂层,并且对纳米涂层的成分、结构和性能实现"剪裁化"的可控制备。本文综述了柔性硬质纳米涂层的特征以及DOMS制备柔性硬质纳米涂层的最新进展。     

阻燃聚氨酯软质泡沫塑料中氯含量的测定

叙述了阻燃聚氨酯软质泡沫塑料中氯含量的测定方法:在助燃剂存在下,氧瓶燃烧使聚氨酯软质泡沫塑料中的有机氯转化为HCl,用稀NaOH吸收,使用硫氰酸汞分光光度法测定聚氨酯软质泡沫塑料中阻燃剂的氯含量。该方法简单快捷、精确度高,回收率为99.64%～102.41%。     

聚氨酯软泡叔胺用量与料温的关系

通过对软质聚氨酯泡沫塑料发泡反应中发生的化学反应机理的探讨,运用化学动力学理论,结合实际生产配方数值,推导得不同原料温度下所需叔胺催化剂配方用量的定量计算公式。此公式对不同温度条件下的实用生产配方的拟订有很好的指导作用。     

一种新的卧式加工中心工作台常压系统的研究

介绍了一种卧式加工中心常压工作台结构,卧式加工中心是机床中自动化程度较高、工序较为集中的机床之一。应用传统的夹具在一定程度上限制了卧式加工中心优越性的发挥,采用工作台通油技术,为夹具提供动力,保证夹具动作的完成,从而增加了卧式加工中心的使用范围及自动化程度。实践证明:该技术设计合理、实用性强、可靠性高。     

基于刚柔耦合的转向架构架关键部位疲劳分析

以某型地铁车辆转向架构架为研究对象,根据结构模态综合法基本原理,通过有限元模态分析对构架进行主自由度缩减,得到构架模态中性文件。建立地铁车辆刚柔耦合多体动力学模型,利用多体动力学仿真,得到不同工况下构架关键部位的应力时间历程变化趋势。最后采用惯性释放法对构架关键部位进行准静态应力分析,依据车辆刚柔耦合多体动力学模型得到转向架构架关键部位的边界载荷,结合材料的S-N曲线,最后通过虚拟疲劳仿真的方法预测构架关键部位的疲劳寿命。     

基于混沌优化的数字PID控制器及其应用

为了解决在工业控制中PID参数整定繁琐、控制结果出现大的振荡和超调等问题,提出一种基于混沌变量的数字PID控制器参数优化方案。该方案不仅适用于运动控制中的PID参数整定,还适用于过程控制中的PID参数整定。对柔性机械臂进行运动控制仿真,结果证明：该算法快速有效地实现了PID参数的优化整定;控制结果具有稳定、超调小、响应快、调节时间短的优点,从而实现了对柔性机械臂的PID优化控制。而且在纯滞后系统中也得到了很好的控制效果。     

Controlled Synthesis of Monolayer Graphene Toward Transparent Flexible Conductive Film Application

We demonstrate the synthesis of monolayer graphene using thermal chemical vapor deposition and successive transfer onto arbitrary substrates toward transparent flexible conductive film application. We used electron-beam-deposited Ni thin film as a synthetic catalyst and introduced a gas mixture consisting of methane and hydrogen. To optimize the synthesis condition, we investigated the effects of synthetic temperature and cooling rate in the ranges of 850–1,000°C and 2–8°C/min, respectively. It was found that a cooling rate of 4°C/min after 1,000°C synthesis is the most effective condition for monolayer graphene production. We also successfully transferred as-synthesized graphene films to arbitrary substrates such as silicon-dioxide-coated wafers, glass, and polyethylene terephthalate sheets to develop transparent, flexible, and conductive film application.     

Fabrication of high performance Pt counter electrodes on conductive plastic substrate for flexible dye-sensitized solar cells

Pt counter electrodes (CEs) with different platinum loading have been prepared using chemical reduced method on flexible indium-doped tin oxide coated polyethylene naphthalate (ITO-PEN) for dye-sensitized solar cells (DSSCs). H₂PtCl₆·6H₂O terpineol solutions were screen printed on the transparent ITO-PEN substrates. After drying, H₂PtCl₆ was reduced by treating it in NaBH₄ solution followed by the hydrothermal treatment at 100 °C. The obtained Pt CEs with different Pt-loading (2.4-7.7 μg/cm²) were characterized by SEM, XPS, electrochemical impedance and transmission spectrum measurement. The Pt CEs show high catalytic activity, low charge transfer resistance (0.26-1.38 Ω cm²) and good light transmittance (about 70% at 400-800 nm). The light-to-electricity conversion efficiency of the flexible DSSC fabricated with the prepared Pt CE and the TiO₂ photoanode prepared on Ti substrate by screen printing technique attains 5.41% under the simulated AM 1.5 sunlight, which is almost same as that based on the thermal decomposited Pt CE on FTO-glass. Compared with other methods to prepare Pt CEs, chemical reduced method is simple and suitable for flexible polymer substrates and the large scale preparation of DSSCs.