NEOGENE TECTONIC HISTORY OF THE SUB-BIBANIC AND M'SILA BASINS, NORTHERN ALGERIA: IMPLICATIONS FOR HYDROCARBON POTENTIAL

The southern Bibans region in northern Algeria is located in the external zone of the Tell fold‐and‐thrust belt. Field observations in this area together with seismic data integrated with previous studies provide evidence for a number of Tertiary deformation phases. Late Eocene Atlassic deformation was followed by Oligocene (?)‐Aquitanian‐Burdigalian compression, which was associated with the development of a foreland basin in front of a southerly‐propagating thrust system. Gravity‐driven emplacement of the Tellian nappes over the basin margin probably occurred during the Langhian‐Serravallian‐Tortonian. The Hodna Mountains structural culmination developed during the Miocene‐Pliocene. Analysis of brittle structures points to continued north‐south shortening during the Neogene, consistent with convergence between the African and Eurasian Plates. The unconformably underlying Mesozoic‐Cenozoic autochthonous sequence in this area contains two potential source rock intervals: Cenomanian‐Turonian and Eocene. Reservoir rocks include Lower Cretaceous siliciclastics and Upper Cretaceous to Palaeogene carbonates. Structural style has controlled trap types. Thus traps in the Tell fold‐and‐thrust belt are associated with folds, whereas structural traps in the Hodna area are associated with reactivated normal faults. In the latter area, there is also some evidence for base‐Miocene stratigraphic traps.     

砂岩储集层微波加热产生微裂缝的机理及意义

微波加热无需介质传热,具有升温速度快、热惯性小、选择性加热、穿透力强、过程易于控制等优点,已被试验性地应用于石油开采中。但有关微波加热对储集层岩石微观结构影响的研究还很缺乏,限制了该项技术在油气开采领域的广泛应用。通过实验手段研究了微波加热前后砂岩岩样微观结构变化、微裂缝产生机理及特征。结果表明,砂岩在微波加热过程中容易产生微裂缝,且不同岩石的微波加热致裂机理不尽相同,主要包括:矿物失水收缩、颗粒粒间开裂和颗粒内部开裂,低渗透致密砂岩刚性颗粒的粒内开裂作用显著。微波加热产生的微裂缝具非定向特征,即使在应力的作用下有一部分裂缝会发生闭合,但仍有大量微裂缝可以起到增加渗透率的作用。井下微波加热的致裂作用有助于改善近井区域渗流能力,提高低渗透油气藏的开采效率。图4参15     

Gas-phase selective oxidation of toluene on TiO2–sepiolite supported vanadium oxides: Influence of vanadium loading on conversion and product selectivities

Gas-phase selective oxidation of toluene has been carried out on vanadium oxide systems (5–20 wt.% of V₂O₅, equivalent to 0.4–1.7 theoretical monolayers) supported on TiO₂–sepiolite (with titania loading around the theoretical monolayer, 12 wt.%) and on sepiolite. A study has been made on both the influence of vanadia loading and of the support on the catalytic behaviour of the supported vanadium systems. The reducibility by H₂ TPR was also studied as well as the acid and basic/redox sites from the results of conversion of the 2-propanol test reaction of the solids. Benzaldehyde, benzoic acid and several coupling products were the main ones detected, attaining over 50% selectivity towards the benzaldehyde and benzoic acid products at a total conversion around 10%. The activity and selectivity to the selective products exhibited by vanadium systems supported on mixed support were superior to those exhibited by the systems supported on sepiolite and increased notably in both series with the increase in vanadium loading. The best catalytic behaviour exhibited by the vanadium systems supported on mixed support, which also exhibited the highest density of sites capable of being reduced (as well as their reducibility) and of those responsible for propanone formation, could be attributed not only to the different balance of the vanadia species existing in the two supports (monomeric + oligomeric/polymeric), but also to such other factors as the nature of the support and, concretely, its chemical composition.     

同步辐射晶体单色器晶体热应变的模拟与实验结果的比较

报道了同步辐射装置光束线关键部件之一的晶体单色器晶体热应变的ANSYS有限元模拟结果,并与实验结果进行了比对,模拟结果在实验误差范围(约士15%)内与实验数据符合,证明了模拟结果的可靠性.     

Effects of organic farming on minerals contents and aroma composition of Clemenules mandarin juice

Consumers demand organic products because they believe that the organic products are more flavorful and respectful to the environment and human health. The effects of organic farming on the minerals contents and aroma composition of Clemenules mandarin juices were studied. Minerals (Fe, Cu, Mn, Zn, Ca, Mg, K, and Na) were quantified using atomic absorption-emission spectroscopy, while volatile compounds were extracted using the dynamic headspace technique and were identified and quantified by GC–MS. In general, organic farming produced a mandarin juice with a higher quality than that produced by conventional agricultural practices. Higher concentrations of both minerals and positive volatile compounds were found in the organic juice, while the formation of off-flavors was higher in the conventional juice, although threshold values were not reached.     

GC/MS characterization of mate tea leaves extracts obtained from high-pressure CO2 extraction

This work presents a study concerning the chemical characteristics and analytical separation process of the essential oil obtained from high-pressure carbon dioxide extraction of Ilex paraguariensis. The experiments were performed in a laboratory-scale unit in the temperature range of 20–40 °C, from 100 to 250 bar. A blend of the I. paraguariensis extracts was percolated through a preparative chromatographic column, containing silica gel, and successively eluted with 150 mL of each of the following solvents: hexane, toluene, dichloromethane, ethyl acetate, acetone and methanol. The raw extract and its fractions were analyzed by gas chromatography coupled to mass spectrometry detection (GC/MS). The fractionation procedure showed to be a good clean up technique due to the isolation of different classes of compounds in each fraction. Chromatographic analyses allowed the identification of caffeine, fatty acids and esters, phytol, squalene, Vitamin E, stigmasterol derivatives and saturated hydrocarbons.     

Growth and characterization of GaAs films deposited on Ge/Si composite substrates by metalorganic chemical vapor deposition

We report the results of studies which have been made on heteroepitaxial layers of GaAs and AlGaAs grown by metalorganic chemical vapor deposition on composite substrates that consist of four different types of heteroepitaxial layered structures of Ge and Ge-Si grown by molecular beam epitaxy on (100)-oriented Si substrates. It is found that of the four structures studied, the preferred composite substrate is a single layer of Ge ∼1 μm thick grown directly on a Si buffer layer. The double-crystal X-ray rocking curves of 2 μm thick GaAs films grown on such substrates have FWHM values as small as 168 arc sec. Transmission electron micrographs of these Ge/Si composite substrates has shown that the number of dislocations in the Ge heteroepitaxial layer can be greatly reduced by an anneal at about 750° C for 30 min which is simultaneously carried out during the growth of the GaAs layer. The quality of the GaAs layers grown on these composite substrates can be greatly improved by the use of a five-period GaAs-GaAsP strained-layer superlattice (SLS). Using the results of these studies, low-threshold optically pumped AlGaAs-GaAs DH laser structures have been grown by MOCVD on MBE Ge/Si composite substrates.     

济钢350m^3高炉高富氧生产技术

分析了济钢350m^3高炉高富氧对产量,理论燃烧温度,炉况顺行状况,焦比和生产效益的影响,高富氧可提高产量,但升高焦比和高炉理论燃烧温度,一定程度上影响高炉顺行,存在富氧效益最大化的适宜富氧率.高炉生产应低富氧高喷煤,根据钢目前的情况,富氧率经2%-3%为宜.     

不同类型在役抽油机机架受力分析

通过现场测试和检查,对油田特定区域内经过优化后的各种不同类型抽油机在额定载荷下的支架以及连杆受力情况进行了分析和评价。为在油田范围内进行机采设备的选型和推广提供一些参考。     

挠性抗回旋PDC钻头的有限元分析

回旋是导致PDC钻头早期失效的主要原因，介绍了一种基于挠性钻头的构想设计的抗回旋PDC钻头，阐述了其结构和抗回旋原理。对挠性钻头的公、母接头进行了有限元应力分析，说明了模型建立、网格划分以及约束和载荷施加过程中所采用的方法和关键技术。有限元分析结果表明挠性钻头的强度满足要求。