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991.
Jing Zhao Weinan Wang Yinping Liu Jinming Ma Xiaowei Li Yu Du Geyu Lu Author vitae 《Sensors and actuators. B, Chemical》2011,160(1):604
Ordered mesoporous SnO2 and mesoporous Pd/SnO2 have been successfully synthesized via nanocasting method using the hexagonal mesoporous SBA-15 as template. Two different procedures, impregnation technique and direct synthesis, were utilized for the doping of Pd in the mesoporous SnO2. The results of small angle X-ray diffraction (SAXD), nitrogen adsorption–desorption and transmission electron microscopy (TEM) demonstrate that the SnO2 and Pd/SnO2 display ordered mesoporous structures and high surface areas. Wide angle X-ray diffraction (WAXD) and X-ray photoelectron spectroscopy (XPS) reveal tetragonal structure of SnO2 and the existence of Pd element. The sensing properties of mesoporous SnO2 and mesoporous Pd/SnO2 for H2 were detected. The sensor utilizing mesoporous Pd/SnO2 via direct synthesis method exhibits excellent response and recovery behavior and much higher sensitivity to H2, compared to those using mesoporous SnO2 and mesoporous Pd/SnO2 via impregnation technique. It is believed that its high gas sensing performance is derived from the large surface area, high activity and well dispersion of Pd additive, as well as high porosity, which lead to highly effective surface interaction between the target gas molecules and the surface active sites. 相似文献
992.
A Chinese liquor classification method based on liquid evaporation with one unmodulated metal oxide gas sensor 总被引:1,自引:0,他引:1
Qiong Zhou Shunping Zhang Yuxiao Li Changsheng Xie Huayao Li Xiaohu DingAuthor vitae 《Sensors and actuators. B, Chemical》2011,160(1):483
Electronic nose has been widely used in the classification of liquid samples, such as vinegars, wines and liquors, which have complex components. The difficulty of these classifications is how to get the information of the trace components in these samples. In this paper a method for liquor recognition based on liquid evaporation was presented. This method makes use of the distinct evaporation characteristics of different components in liquor samples. And during the evaporation process, one metal oxide gas sensor was used to detect the headspace of liquor samples for classification. Due to the distinct evaporation characteristics of different components, volatile compounds in the headspace evaporating from samples would change with the testing time. Meanwhile, the gas sensor would respond to these volatile compounds. Accordingly, more information of liquor samples during evaporation may be acquired with the proposed method. To verify the performance of this method, 8 different Chinese liquors with 50% alcohol for comparison were tested under the method. The results showed that the evaporation characteristics of these liquor samples were quite distinct. The correct classification accuracy of discriminant function analysis was 100%, which indicated this method may be a simple and effective way for complex-component liquid sample analysis. 相似文献
993.
N.M. ShaalanAuthor Vitae T. YamazakiAuthor Vitae T. KikutaAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(2):784-790
Electrodes with micro-gaps are fabricated by using dc-sputtering and FIB techniques. SnO2 nanowires are deposited on the micro-gap (1-30 μm) by suspension dropping method to fabricate a micro-gas sensor. The sensing ability of various SnO2 micro-gap sensors is measured. A comparison between sensors reveals that the short-gap electrode has numerous advantages in terms of reliability, high sensitivity and detection of low concentrations of NO2, while the large-gap electrode is relatively sensitive for high concentrations. Conductance measurements are carried out at different surface temperatures and NO2 concentrations in order to investigate the effects that the gap size has on the overall sensor conductance. The results suggest that the interface between the electrode and sensitive layer has a very important role for the sensing mechanism of tin dioxide gas sensors. 相似文献
994.
Jichao ShiAuthor VitaeGujin HuAuthor Vitae Yan SunAuthor VitaeMing GengAuthor Vitae Jie WuAuthor VitaeYufeng LiuAuthor Vitae Meiying GeAuthor VitaeJunchao TaoAuthor Vitae Meng CaoAuthor VitaeNing DaiAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(2):820-824
WO3 nanocrystals have been prepared by a sol-gel route and characterized by X-ray diffractometry, scanning electron microscopy, and transmission electron microscopy. The experimental results show that WO3 nanocrystals have a high crystallographic quality and a good dispersivity. The particles’ sizes are in the range of 25-100 nm. The fabricated WO3 nanocrystal-based sensors have an excellent sensitivity and selectivity to acetone, and display a rapid response and recovery characteristics. The developed sensors exhibit a detection limit down to 0.05 ppm at 300 °C, rendering a promising application in noninvasive diagnosis of diabetes. The response mechanism of the WO3 nanocrystal sensor to low concentration of acetone has been discussed based on the depletion layer model. 相似文献
995.
Vishal BalouriaAuthor Vitae Arvind KumarAuthor VitaeA. SinghAuthor Vitae S. SamantaAuthor VitaeA.K. DebnathAuthor Vitae Aman MahajanAuthor VitaeR.K. BediAuthor Vitae D.K. AswalAuthor Vitae S.K. GuptaAuthor VitaeJ.V. YakhmiAuthor Vitae 《Sensors and actuators. B, Chemical》2011,157(2):466-472
The conductometric gas sensing characteristics of Cr2O3 thin films - prepared by electron-beam deposition of Cr films on quartz substrate followed by oxygen annealing - have been investigated for a host of gases (CH4, CO, NO2, Cl2, NH3 and H2S) as a function of operating temperature (between 30 and 300 °C) and gas concentration (1-30 ppm). We demonstrate that these films are highly selective to H2S at an operating temperature of 100 °C, while at 220 °C the films become selective to Cl2. This result has been explained on the basis of depletion of chemisorbed oxygen from the surface of films due to temperature and/or interaction with Cl2/H2S, which is supported experimentally by carrying out the work function measurements using Kelvin probe method. The temperature dependent selectivity of Cr2O3 thin films provides a flexibility to use same film for the sensing of Cl2 as well as H2S. 相似文献
996.
Mei ChenAuthor VitaeZhihua WangAuthor Vitae Dongmei HanAuthor VitaeFubo GuAuthor Vitae Guangsheng GuoAuthor Vitae 《Sensors and actuators. B, Chemical》2011,157(2):565-574
Hierarchical flower-like and 1D tube-like ZnO architectures were synthesized by a microemulsion-based solvothermal method. Technologies of XRD, SEM and TEM were used to characterize the morphological and structural properties of the products. The influence of the flower-like and tube-like morphologies on their NO2 sensing properties was investigated. The experimental results showed that high-sensitivity NO2 gas sensors were fabricated. The sensitivity of the tube-like ZnO gas sensor was much higher than that of the flower-like ZnO gas sensor and the tube-like ZnO gas sensor exhibited shorter response time. The in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) technique was employed to investigate the NO2 sensing mechanisms. Free nitrate ions, nitrate and nitrite were the main adsorbed species during the adsorption, and NO also existed in the initial period of surface reoxidation. Furthermore, N2O was formed via NO− and N2O2− stemmed from NO and increased upon rising temperature. Moreover, the PL spectra and the XPS spectra further proved that the intensity of donors (oxygen vacancy (VO) and zinc interstitial (Zni)) and surface oxygen species (O2− and O2) involved in the gas sensing mechanism leaded to the different sensitivities. 相似文献
997.
恒温槽温度的高精度控制和精确液位检测与准确计时是影响重力式毛细管粘度仪测量准确度的关键因素。提出并设计了一种将改进Bang-Bang控制、模糊控制、PID控制与DSP的PWM控制相结合的恒温槽温度复合智能控制方法,构建了一种改进型峰值液位检测方法,实现了恒温槽温度的精确控制和粘度仪的液位自动检测与准确计时。实测结果表明,采用复合智能温度控制和改进型峰值液位检测的重力式毛细管粘度仪各项指标均达到或优于工业粘度计国家标准要求,计时误差0.3%,恒温槽温度控制准确度达0.05℃。 相似文献
998.
The influence of the SnO2 surface modification by the SnO2–Au nanocomposites on conductivity response to such reducing gases as CO and H2 has been analyzed in the present paper. Both initial SnO2 films, subjected for surface modification, and SnO2–Au nanocomposites were deposited by Successive Ionic Layer Deposition (SILD) method. The SnO2–Au nanocomposites with Au/Sn ratio 1 were synthesized using HAuCl4 and SnCl2 precursors. The thickness of the Au-SnO2 nanolayers varied from 0.7–1.0 nm to 10–15 nm. It was established that the increase in the thickness of the SnO2–Au nanocomposite layer formed on the surface of the SnO2 films was accompanied by both the improvement of sensor response and the decrease in response and recovery times. An explanation of the observed effects has been proposed. 相似文献
999.
This paper presents a novel signal processing technique for a square wave temperature modulated carbon black/polymer composite sensor. The technique consists of only two mathematical operations: summing the off- and on-transients of the conductance signals, and subtracting the steady-state conductance signal. The technique has been verified through its application to a carbon black/polyvinylpyrrolidone composite chemoresistor. Identification of water, methanol and ethanol vapours was successfully demonstrated using the peak time of the resultant curves. Furthermore, quantification of those vapours was found to be possible using the height of the peak heights, which was linearly proportional to concentration. The technique does not require zero-gas calibration and thus is superior to previously reported techniques. 相似文献
1000.
Youngmin Ki-Young Jinwoo Jinnil Gwi-Nam Byeong-Kwon 《Sensors and actuators. B, Chemical》2009,140(2):407-411
This study deals with the fabrication of an ozone gas sensor using single-walled carbon nanotubes (SWCNTs) as sensing material. The SWCNTs are dispersed by N,N-dimethylformamide (DMF). The CNT-DMF solution was dropped between interdigitated electrodes’ fingers to fabricate ozone gas sensor. For ozone environment, a commercial ozone generator was introduced. To improve sensor response, the deposited carbon nanotubes network was thermally treated at high temperature in a furnace. The sensor exhibits high sensitivity to ozone gas at concentration as low as 50 ppb, and fast response time, which is promising for future commercialization of carbon nanotubes based ozone gas sensor. 相似文献