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21.
In this paper, we examine, both experimentally and theoretically, the kinetics of formation and microstructure of product
phases in thin film reactions, using the Nb/Al and Ti/Al systems as our prototypes. The results of calorimetry and microscopy
studies are interpreted using simple kinetic and morphology models. In particular, the kinetic models employed here focus
on the nucleation and growth components of the phase formation process and the morphology models provide a starting point
for the classification of product grain structures.
An erratum to this article is available at . 相似文献
22.
Mgidi Donald Dlamini 《Solar Energy Materials & Solar Cells》1996,43(4):353
In this paper results on surface photovoltage (SPV) and electron beam induced conductivity (EBIC) studies of edge-defined film-fed growth (EFG) and floating zone (FZ) silicon solar cell materials (both p-type) are presented. A systematic comparison based on minority carrier diffusion length and carrier recombination is made between: (i) samples contaminated with Ti and/or Fe, (ii) samples gettered by phosphorous diffusion, and (iii) as-received samples. Deep level transient spectroscopy (DLTS) measurements, together with the iron-boron (FeB) pairing kinetics [1] have successfully been used to detect the presence of Fe in the samples. Even though this process is effective in revealing Fe impurities in p-type FZ silicon it is evidently not suitable for Fe identification in p-type EFG silicon. Ti, like Fe, is found to be a prominent lifetime-limiting metallic impurity in both EFG and FZ silicon. Phosphorous diffusion is proven to be an effective external gettering technique for fast-diffusing impurities such as Fe, but not for Ti. 相似文献
23.
Quantitative analyses of flow and stage data, remote sensing and geographic information systems analysis, and field studies were used to assess the impact of dams and diversions on the point bar habitat of the Sacramento Valley Tiger Beetle (Cicindela hirticollis abrupta). The reaches of interest include sites of known historic populations of C. h. abrupta along the Sacramento River from approximately 8 km north of Colusa southward to the confluence with the Feather River and along the Feather River between Yuba City and its confluence with the Sacramento River. The results from this study show that construction of two major dams has altered flows such that prolonged and increased flows during summer, fall, and early winter have most likely disrupted life cycles, flooded larvae, drowned overwintering adults and led to high mortality. Additionally, habitat availability has decreased over time because point bars have decreased in number and area causing increased distances between populations and isolation of populations. Moreover, point bar armouring, channel scouring, altered flows, redirected flows through weirs, and lithologic controls have produced a bimodal distribution of mean grain sizes in the Sacramento River in which the more northern bars contain gravel deposits and more southern bars possess fine sands. These conditions negatively alter moisture retention and sediment compaction and, consequently, burrowing conditions needed by this tiger beetle. Additionally, more stabilized flows (reduced variability) and increased fine‐grained deposition have enabled development and encroachment of vegetation onto the sand bars. Finally, human stresses, such as foot traffic and vehicular traffic may have interfered with burrowing, ovipositing, and foraging. The combination of these stress factors has most likely led to a reduction in source populations and, ultimately, the apparent extirpation of the entire metapopulation. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
24.
本文对激光结晶a-Si∶H SOI结构砷注入和快速退火行为作了研究.a-Si∶H激光结晶有Lp-LCR,OD,FCR-2,FCR-1四个结晶区.用剖面电镜观察了结晶区的结构.扩展电阻测量表明Lp-LCR区中有两种扩散机制,即杂质在晶粒体内扩散和沿缺陷扩散.OD区中有三种扩散形式,除有上述两种以外,还有沿缺陷的扩散.首次比较了沿晶界和缺陷的扩散速度. 相似文献
25.
Yukio Sato Tomohito Tanaka Fumiyasu Oba Takahisa Yamamoto Yuichi Ikuhara Taketo Sakuma 《Science and Technology of Advanced Materials》2003,4(6):137
SrTiO3 and ZnO bicrystals with various types of boundaries were fabricated in order to examine their current–voltage characteristics across single grain boundaries. Their grain boundary structures were also investigated by high-resolution transmission electron microscopy. In Nb-doped SrTiO3, electron transport behaviors depend on the type of boundaries. Random type boundaries exhibit highly non-linear current–voltage characteristics, while low angle boundaries show a slight non-linearity. On the contrary, undoped ZnO does not exhibit non-linear current–voltage characteristics in any type of boundaries including random ones. It is suggested that the differences observed in current–voltage properties between the two systems are mainly due to the difference in the accumulation behavior of acceptor-like native defects at grain boundaries. A clear non-linearity is obtained by means of Co-doping even for the highly coherent Σ1 boundary in a ZnO bicrystal. This is considered to result from the production of acceptor-like native defects by Co-doping. 相似文献
26.
注水开发油田砂砾岩储层含油饱和度解释模型 总被引:2,自引:1,他引:1
本文利用常规测井资料,结合储层岩性、物性、含油性之间的地质规律,解决了储层岩石粒度变化及水淹层混合水电阻率变化对储层电阻率的影响;研究出了一种对电阻率测井资料标准化的校正方法;建立了储层原始、剩余、残余油饱和度解释模型。计算的储层原始、剩余、残余油地质储量,经生产验证相对下误差小于10%;计算产水率,试油验证平均绝对误差小于10%;划分水淹油层等级,试油验证符合率在80%以上。 相似文献
27.
I. W. Hall 《Materials Characterization》1997,39(2-5):419-434
The effects of ion implantation and subsequent annealing on the microstructure of molybdenum have been investigated by transmission electron microscopy. The ions investigated were carbon, nitrogen, and tellurium. The ion-induced damage was found to give rise to grain boundary migration phenomena both during implantation and during subsequent annealing. Precipitation or ordering was found to occur for each ion on annealing. 相似文献
28.
29.
Untextured bulk polycrystals usually possess macroscopically isotropic elastic properties whereas for most thin films transvers isotropy is expected,owing to the limited dimenionlity .The usually applied models for the calculation of elstic constants of polycrystals from single crystal elastic contants(so-called grain interaction models)erroneously predict macroscopic isotropy for an(untextured) thin film.This paper presents a summary of recent work where it has been demonstrated for the first time by X-ray diffraction analysis of stresses in thin films that elastic grain interaction can lead to macroscopically anisotropic behaviour (shown by non-linear sin^2φ plots).A new grain interaction model,predictin the macroscopically anisotropic behaviour of thin films,is proposed. 相似文献
30.
Microstructure evolution during metal forming processes 总被引:8,自引:0,他引:8
Recrystallization and grain growth evolutions during metal forming processes are considered. Coupling between the thermo-mechanical and microstructure processes is realized. Die forging of a rear-axle flange is simulated numerically on the base of the finite element method. Material parameters of the models are obtained experimentally. The influence of interpass and holding times on grain size distributions in the end product is shown. 相似文献