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41.
加入HDPE-g-MAH、CG-8831和KH-550制备HDPE/木粉改性复合材料。研究其长效吸水性,发现吸水率随时间延长先快速增加,浸水35 d后缓慢增至平衡,HDPE-g-MAH改性效果最好,其饱和吸水率仅为1.503%。利用Fick第二扩散定律拟合吸水动力学曲线,得扩散系数D的顺序:HDPE-g-MAH增容HDPE/木粉复合材料HDPE/木粉复合材料KH-550改性HDPE/木粉复合材料CG-8831改性HDPE/木粉复合材料。并证明该吸水过程符合Fick第二扩散定律,相关系数R2值达0.99以上。HDPE/木粉改性复合材料尺寸变化系数CDCWCT。 相似文献
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Mahsa Barzegar Rabi Behrooz Hamid Reza Mansouri Saeed Kazemi Najafi Linda F. Lorenz Charles R. Frihart 《Journal of the American Oil Chemists' Society》2020,97(12):1371-1383
Canola is widely grown in the northern latitudes for its vegetable oil, generating large quantities of residual, low value canola flour used as animal feed. The common wood adhesive poly(diphenylmethylene diisocyanate) (pMDI) should react with the wide variety of functional groups in proteins. Therefore, it would seem that canola flour with added pMDI could be an effective adhesive. Two main questions are addressed in this study: How do the wood adhesive properties of canola flour compare to the better-studied soy flour? How well do proteins, which contain an abundance of functional groups, cure with the very reactive pMDI? These questions were addressed using the small-scale adhesive strength test ASTM D-7998, with various adhesive formulations and bonding conditions for canola flour plus pMDI compared to soy adhesives. The more challenging wet cohesive bond strength was emphasized because the dry strengths were usually very good. Generally, soy adhesives were better than canola ones, as was the polyamidoamine-epichlorohydrin cross-linker compared to pMDI, but these generalizations can be altered by the conditions selected. Three-ply plywood tests supported the small-scale test results. 相似文献
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采用一种操作简便且易于工业推广的方法对木粉进行疏水改性,具体过程为:将3种可热聚合的单体,即甲基丙烯酸甲酯(MMA)、甲基丙烯酸丁酯(BMA)和苯乙烯(St)均匀喷洒在木粉上,经过预热处理后,与配方中其他组分,如高密度聚乙烯(HDPE)和马来酸酐接枝聚乙烯(MAPE)等通过高速混合机混合均匀,采用双螺杆挤出机造粒后,注射制备木塑复合材料(WPC)样条,测试其力学性能。另外,考察了疏水改性对WPC接触角、维卡软化温度、洛氏硬度、吸水性能、热性能的影响规律。结果表明:疏水改性后WPC的接触角增大,木粉和HDPE的界面相容性改善,力学性能得到明显提高。其中,当MMA、BMA和St的添加量为3%时,WPC的力学性能最好,与疏水改性前相比,弯曲强度分别提高了17.3%、26.3%和27.5%,弯曲模量分别提高了24.4%、24.4%和26.0%,冲击强度分别提高了54.7%、57.7%和60.5%。 此外,疏水改性后WPC的维卡软化温度、洛氏硬度、耐水性和耐热性也得到改善。 相似文献
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ABSTRACT: Thermal properties of conventionally and ohmically heated rice starch and rice flours at various frequencies and voltages were studied. There was an increase in gelatinization temperature for conventionally heated rice starches since they were pregelatinized and became more rigid due to starch–chain interactions. In addition, there was a decrease in enthalpy (energy needed) for conventionally and ohmically heated starches during gelatinization; thus, the samples required less energy for gelatinization during DSC analysis. Ohmically heated commercial starch showed the greatest decrease in enthalpy probably because of the greatest extent of pregelatinization through ohmic heating. Brown rice flour showed the greatest gelatinization temperature resulting from the delay of starch granule swelling by lipid and protein. Enthalpy of ohmically heated starches at 20 V/cm was the lowest, which was most likely due to the lower voltage resulting in a more complete pregelatinization from a longer heating time required to reach 100 °C. Ohmic treatment at 70 V/cm decreased onset gelatinization temperature of white flour; therefore, it produced rice flour that swelled faster, whereas the conventionally heated sample showed a better thermal resistance. 相似文献
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